• 제목/요약/키워드: hard Coating

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사회적 규제가 대체재 간 경쟁과 혁신에 미치는 영향에 관한 연구 : 국내 철강 구조물용 내화 피복재 산업의 사례연구 (A Study on the Influence of Social Regulation on Competition and Innovation: A Case of Fire-retardant Coating Material for Steel Structure Sector in Korea)

  • 장철권;지일용
    • 기술혁신학회지
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    • 제20권4호
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    • pp.939-969
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    • 2017
  • 환경과 안전에 대한 관심이 증가함에 따라 사회적 규제 및 이의 혁신에 대한 영향성에 대한 관심 또한 증대되고 있다. 포터가설을 중심으로 한 기존의 사회적 규제 관련 문헌들은 주로 혁신으로 인한 비용, 기대이익, R&D 투자 등 내적 요소에 초점을 두어 왔다. 최근에는 환경규제 등 사회적 규제로 인한 산업구조의 변화에 관심을 두는 연구가 증가하고 있는 상황이나, 사회적 규제에 따른 외부환경의 변화와 그로 인한 혁신에 대한 영향에 대해서는 연구가 많이 이루어지지 못한 상황이다. 이에 본 연구에서는 기존 문헌이 제시하는 바와 같이 준수 기대이익 등 내적 요인은 물론, 산업구조 변화와 같은 변화를 통해 사회적 규제가 혁신에 영향을 미칠 수 있음을 보여주고자 하였다. 이를 위해 본 연구에서는 국내 철강 구조물용 내화 피복재 산업의 사례연구를 실시하였다. 연구 결과 내화 피복재 산업은 1990년대 3번에 걸친 규제완화를 경험하였으며, 이들 규제 완화들이 시장 기회 및 기대이익을 제공함으로써 신규 시장진입을 유도하였고, 시장구조 변화와 경쟁 심화에 따라 기업들의 혁신이 발생하였음을 확인할 수 있었다.

Fabrication of Superhydrophobic Aluminum Alloy Surface with Hierarchical Pore Nanostructure for Anti-Corrosion

  • Ji, Hyejeong;Jeong, Chanyoung
    • Corrosion Science and Technology
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    • 제18권6호
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    • pp.228-231
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    • 2019
  • Aluminum and its alloys have been widely used in various fields because of low weight, high strength, good conductivity, and low price. It is well known that aluminum alloys that cause natural oxide film can inhibit corrosion in wet, salty environments. However, these oxides are so thin that corrosion occurs in a variety of environments. To prevent this problem, an electrochemical anodizing technique was applied to the aluminum alloy surface to form a thick layer of oxide and a unique oxide shape, such as a hierarchical pore structure simultaneously combining large and small pores. The shape of the structures was implemented using stepwise anodization voltages such as 40 V for mild anodizing and 80 V for hard anodizing, respectively. To maximize water repellency, it is crucial to the role of surface structures shape. And a hydrophobic thin film was coated by 1H, 1H, 2H, 2H-Perfluorodecyltrichlorosilane (FDTS) to minimize surface energy of the structure surface. Thus, such nanoengineered superhydrophobic surface exhibited a high water contact angle and excellent corrosion resistance such as low corrosion current density and inhibition efficiency.

LIGA-like 공정을 이용한 마이크로 부품 복제용 Ni과 Ni-W 금형 제조 및 특성 (Fabrication and Properties of Ni and Ni-W Electroplated Molds Using LIGA-like Process for Replication of Micro Components)

  • 황완식;박준식;강영철;조진우;박순섭;이인규;강성군
    • 한국재료학회지
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    • 제13권1호
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    • pp.6-10
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    • 2003
  • Electroplated Ni and Ni-W micro-molds using LIGA-like process for replication of micro-components such as microfluidic parts and micro optical parts have been investigated. In general, it is hard to produce micro-parts using conventional mechanical processes. Micro-mold formed by LIGA-like process could fabricate micro-parts with high aspect ratio. In this paper, fabrication and properties of electroplated Ni molds with varying applied current types as well as those of Ni-W molds were investigated. Ni molds fabricated under pulse-reverse current showed the highest hardness value of about 160 Hv. Ni-W molds showed the hardness of about 500 Hv which was much harder than that of Ni electroplated molds. The above results suggested that high quality micro-molds could be fabricated by using Ni electroplating of pulse-reverse type for core molds and sequential Ni-W alloys coating.

선체블록 론지 이면부 자동 도장 장비 개발 (Development of Automatic Painting Unit for Back-side of Longitudinal Stiffeners in Double Hull Blocks)

  • 김은태;이동훈;김호경
    • 대한조선학회 특별논문집
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    • 대한조선학회 2009년도 특별논문집
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    • pp.123-129
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    • 2009
  • Ship painting procedures can be divided into two categories; Out-shell plate painting of the hull and the interior painting of each double gull blocks. It is really hard to apply standardized and automated operations to the latter because the double hull blocks contains a variety of complicated supportive materials and pipes to strengthen the ship structure. In addition their poor working conditions cause painting workers to avoid working in them, resulting in the waste of paints and additional pollution issues. So this research, successfully focused on overcoming the difficulties in working in the complicated blocks and the tough working conditions introduces the main details of automatic equipment systems and their transfer algorism which show how the equipment paints the inner sides of a longitudinal stiffener and moves to another automatically.

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Ti(Al,O)/$Al_2O_3$ 플라즈마 코팅한 SS41의 고온산화 거동 (High Temperature Oxidation Behavior of Plasma-sprayed Ti(Al,O)/$Al_2O_3$ Coatings on SS41 Steel)

  • 최갑송;우기도;이현범;전재열
    • 열처리공학회지
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    • 제20권5호
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    • pp.231-236
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    • 2007
  • High velocity oxy-fuel (HVOF) spraying was used to coat Ti(Al,O)/$Al_2O_3$ powder onto the SS41 steel plate. Macrostructure of the coated specimen has been investigated by scanning electron micrograph (SEM). High temperature oxidation behavior of the coated specimen and SS41 steel have been studied. From the results of SEM observation, Ti(Al,O)/$Al_2O_3$ powder was coated well onto the substrate SS41 steel. Porosity onto the coated layer was only 0.38%. The oxidation results showed that Ti(Al,O)/$Al_2O_3$ powder coated SS41 steel have improved little oxidation resistance at $900^{\circ}C$ in air, but improved remarkably oxidation resistance at $800^{\circ}C $ in air compare to the substrate SS41 steel.

SU-8 PR을 이용한 마이크로 구조물 제작 공정 개발 (A development of fabrication processes of microstructure using SU-8 PR)

  • 김창교;장석원;노일호
    • 한국결정성장학회지
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    • 제13권2호
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    • pp.68-72
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    • 2003
  • 본 논문에서는 3차원 마이크로구조물을 위한 새로운 UV-LIGA 공정을 개발하였다. 일반적으로 photoresist는 얇은 두께로 코팅이 되지만, SU-8은 수십 $\mu\textrm{m}$ 이상의 두께를 가질 수 있으며, 높은 형상비를 갖는다. SU-8과 같은 Thick photoresist는 기존의 baking 공정과 같이 급격한 cool down을 할 경우 stress에 의한 crack이 발생한다. 이와 같은 경우 도금을 위한 마이크로구조물이 구현이 되지 않는다. SU-8의 코팅, bake에서의 시간 조절, 그리고 PEB의 시간 조절 및 cool down조절을 통하여 stress에 의한 crack이 발생하지 않도록 3차원 마이크로구조물을 제작 할 수 있도록 하였다.

Rheo-compocasting법에 의한 SiC입자분산 복합재료의 마모특성에 관한 연구 (A Study on the Wear Characteristics of SiC Particle Dispersed Composites by Rheo-Compocasting Method)

  • 곽현만;최창옥
    • 한국주조공학회지
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    • 제13권3호
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    • pp.238-247
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    • 1993
  • Microstructure, hardness and wear characteristics of $SiC_p/Al-6.5wt%Si-1.7wt%Mg$ alloy composites fabricated by the method of rheo-compocasting and hot pressing are investigated in this study. The dispersion of SiC particles in the composites is homogeneous and the hardness improves as additional amount increases. The wear amount of the matrix metal increases highly as wear rates increase, for the wear mechanism changes from adhesive wear to melt wear, and the matrix metal was coated on the surface of revolving disc and its weight increases. In the 5vol% composites, Fe is adhered on the surface of specimen by the projection of the dispersed hard SiC particles which have net-work structure and the coating layer is about $300{\mu}m$. But in the composite more than 20vol%, the wear amount of composite decreases because the SiC particles which have superior hardness, wear resistance and heat resistance properties resist wear, the abrasive wear turn out predominant wear mechanism and so the wear amount of revolving disc increases.

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직류 및 고주파 마그네트론 스퍼터링법으로 증착한 Ti-Al-V-N 박막의 특성 (Characterizations of Ti-Al-V-N Films Deposited by DC and RF Reactive Magnetron Sputtering)

  • 손용운;정인화;이영기
    • 열처리공학회지
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    • 제13권6호
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    • pp.398-404
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    • 2000
  • The Ti-Al-V-N films have been deposited on various substrates by d.c and r.f reactive magnetron sputtering from a Ti-6Al-4V alloy target in mixed $Ar-N_2$ discharges. The films were investigated by means of XRD, AES, SEM/EDX, microhardness, TG and scratch test. The XRD and SEM results indicated that the films were of single B1 NaCl phase having dense columnar structure with the (111) preferred orientation. The composition of Ti-Al-V-N film was the Ti-7.1Al-4.3V-N(wt%) films. Adhesion and microhardness of Ti-Al-V-N films deposited by r.f magnetron sputtering method were better than those deposited by d.c magnetron sputtering method. The anti-oxidation properties of Ti-Al-V-N films were also superior to that of Ti-N film deposited by the same deposition conditions.

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Hydroxy Apatite가 피복된 치과매식체의 주위골조직 반응에 관한 조직학적 연구 (A HISTOLOGICAL STUDY OF SURROUNDING BONE TISSUE REACTION TO HYDROXY APATITE COATED DENTAL IMPLANT)

  • 송준기;허성주;조인호
    • 대한치과보철학회지
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    • 제29권2호
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    • pp.23-34
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    • 1991
  • Even if we can recover the function of mastication, pronunciation and esthetic using the fixed or removable prosthesis in the loss of teeth or hard tissue in the oral cavity, we use several kinds of implants in order to solve the problem which can be occured when we can't install the denture because of excessive bone resolution or psychlogical affairs. At present Titanium implant plays a major role in this field and has osseointegrated. And the study on the modern material is going on, that result in developing and using the implant which is coated with HA, bone induced material. In this, I studied histologically the change of the bone tissue which is occured when three kinds of HA coated implants. Such as Integral, Sustain, Biovent implanted into mandible of dog and got a 8-weeks healing period. I got the conclusion as follows: 1. Most of the implant which is covered with serveral kinds of HA coating implant in bone after 8 weeks being implanted and has osseointegrated, partially converted into the connective tissue. 2. Biovent formed the connective tissue in the perforated area of inferior alveolar canal and has osseointegrated.

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STD61 강의 내열특성향상을 위한 표면경화에 관한 연구 (A Study in the Heat Resistance Properties of STD61 Steel using the Surface Hardening Method)

  • 이구현
    • 연구논문집
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    • 통권26호
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    • pp.121-132
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    • 1996
  • The carburising surface modification treatment of the die steel has been used for improving wear resistance and heat cycle strength of the die and preventing a pitting on the surface because the carbides are forming in the matrix during carburising. Generally, the hot forging die was used after quenching-tempering treatment or nitriding after quenching-tempering treatment. The nitriding after carburising on the surface of a hot die steel and a wear resistance die steels was suggested by SOUCHARD, JACQUOT. and BUVRON. This surface modification treatment improved the adhesive and abrasive wear resistance and friction coefficient. The process was introduced to the forging die of stainless steel, titanium alloy steel, alloy and medium carbon steel and the physical properties of the die after the treatment were improved. The surface hardening treatment of the nitriding, the carburising, the boriding, and TD process were used to improved the life time of the forging die. Also, the coating process of PVD, CVD and PCVD were used and the hard chromium plating was occasionally used. Therefore, this study analyzed the effects of the carburising time and the conditions of nitriding on STD61 steel. The case depth, the surface hardness, the forming carbide size and shape during overcarburising process on the die steel were also examined.

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