• 제목/요약/키워드: halloysite

검색결과 110건 처리시간 0.022초

우리 나라 황토(풍화토)의 구성광물 및 화학성분 (Mineralogy and Chemical Composition of the Residual Soils (Hwangto) from South Korea)

  • 황진연;장명익;김준식;조원모;안병석;강수원
    • 한국광물학회지
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    • 제13권3호
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    • pp.147-163
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    • 2000
  • The mineralogy and chemical composition of reddish to brownish yellow residual soils, so called "Hwangto" have been examined according to representative host rocks. The result of the study indicates that Hwangto consists of 40-80% clay minerals and various minerals such as quartz, feldspar, hornblende, goethite, and gibbsite. Clay minerals include kaolinite, halloysite, illite, hydroxy interlayered vermiculite (HIV), mica/vermiculite interstratifield mineral and chlorite. The mineralogical constituents and contents of Hwangto were different depending on the types of host rocks. Moreover, the Jurassic granitic rocks contain relatively more kaolin minerals, whereas the Cretaceous granitic rocks contain more HIV and illite. In addition, reddish Hwangto contains relatively more kaolinite and HIV, and yellowish Hwangto contains more illite and halloysite. It is suggested that feldspars and micas of host rocks were chemically weathered into illite, halloysite, illite/vermiculite interstratified minerals, and HIV, and finally into kaolinite. Compared with their host rocks, the major chemical compositions of Hwangto tend to contain more $Al_2O_3,\;Fe_2O_3,\;H_2O$ in amount and less Ca, Mg, and Na. Hwangto contains relatively high amount of trace elements, P, S, Zr, Sr, Ba, Rb, and Ce including considerable amount of Li, V, Cr, Zn, Co, Ni, Cu, Y, Nb, La, Nd, Pb, Th in excess of 10 ppm. Relatively high amount of most trace elements were detected in the Hwangto. The major and minor chemical compositions of the Hwangto were different depending on the types of host rocks. However, their difference was in the similar range compared with the compositions of host rocks.

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산청지역 회장암내 단사녹니석의 풍화에 의한 녹니석/버미큘라이트 혼합층 광물 및 할로이사이트의 생성 (Formation of Mixed-layered Chlorite/Vermiculite and Halloysite from Clinochlore by Weathering in Anorthosite in the Sancheong District)

  • 정기영;김수진
    • 한국광물학회지
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    • 제6권2호
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    • pp.145-155
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    • 1993
  • 산청지역 회장암에 함유된 녹니석이 풍화되면서 겪는 광물학적, 조직학적, 화학적 변화를 X선 회절분석, 주사전자현미경 및 전자현미분석을 이용하여 연구하였다. 회장암에 함유된 녹색의 녹니석은 함철단사녹니석으로서 구조상 IIb형에 속한다. 단사녹니석은 $Fe^{2+}$의 산화와 층간 수화물층의 선택적인 용탈에 의해 버미큘라이트화하여 녹니석/버미큘라이트 규칙 혼합층을 형성하며 이 광물은 별개의 버미큘라이트 단계를 거치지 않고 곧바로 할로이사이트로 풍화된다. 녹니석 패킷은 녹니석/버미큘라이트 규칙혼합층으로 변하면서 보다 얇은 패킷들로 갈라지며 할로이사이트화 과정에서는 큰 체적 증가와 함께 특징적인 부채 구조가 형성된다. 녹니석/버미큘라이트 규칙혼합층의 직접적인 할로이사이트화는 이 지역 회장암의 빠른 풍화속도에 기인한다.

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지르코니아를 담지한 할로이사이트 나노튜브를 충진재로 이용한 에폭시 복합체의 기계적 열적 특성 분석 (Analysis of Mechanical and Thermal Properties of Epoxy Complex using Zirconia Supported Halloysite Nanotubes as Filler)

  • 김문일
    • 한국산업융합학회 논문집
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    • 제25권3호
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    • pp.461-466
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    • 2022
  • Epoxy resins are widely used in various industrial fields. However, they suffer from brittleness, an issue that must be addressed for further applications. To solve this problem, additional fillers are needed to improve the mechanical and thermal properties of the resins; zirconia is one such filler. However, it has been reported that aggregation may occur in the epoxy composites as the amount of zirconia increases, preventing enhancement of the mechanical strength of the epoxy composites. Herein, to reduce the aggregation, zirconia was well dispersed on halloysite nanotubes (HNTs), which have high thermal and mechanical strength, by a conventional wet impregnation method using zirconyl chloride octahydrate as a precursor. The mechanical and thermal strengths of the epoxy composites with The zirconia impregnated HNTs (Zr/HNT) were investigated. Zr/HNT were characterized by Scanning electron microscope (SEM), transmittance electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy. The thermal strength of the epoxy composites was studied by thermomechanical analysis (TMA) and the mechanical strength of the epoxy composites (flexural strength) was studied by using a universal testing machine (UTM). The mechanical and thermal strengths of the epoxy complex with Zr/HNT were improved compared to those of the epoxy complex with HNT, and also increased as the content of Zr/HNT increased.

경남 고성의 화강암 적색 풍화층의 특색과 성인에 관한 논의 (Discussion of the Origin and the Properties of Granitic Red Regolith Profile in Goseong, Southern Korea)

  • 김영래
    • 한국지형학회지
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    • 제18권1호
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    • pp.57-71
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    • 2011
  • 남해안의 고성에 위치하는 월치고개 단면은 10m 두께의 화강암 풍화층으로써, 10YR 4/4에 가까운 적색을 띠고 있어서 고온다습했던 고기후의 산물로 판단되기 쉬운 단면이다. 그러나 단면관찰과 박편분석, XRD 동정과 지화학적 분석을 통해 살펴본 결과, 열수변성의 대표광물인 할로이사이트가 단면 전체에서 보편적으로 나타나고 있으며, 한반도의 일반적 화강암 풍화층의 화학적 풍화율인 60~70%보다 훨씬 높은 97%에 달하였다. 이는 기후지형학적 풍화에 의해 형성된 적색풍화층이 아니라, 지열수에 의한 열수변성 가능성이 매우 높게 단면으로 판단된다.

벤토나이트의 풍화에 따른 점토광물의 상전이 및 광물특성 (Characteristics and Phase Transition of Clay Minerals as the Results of Bentonite Weathering)

  • 노진환;이석훈
    • 한국광물학회지
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    • 제15권3호
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    • pp.147-159
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    • 2002
  • 한 구릉상에 자연적으로 노출된 지표면을 따라 대략 50 cm 이내의 두께를 이루며 분포한다. 풍화된 벤토나이트에는 몬모릴로나이트 외에 7 $\AA$형 할로이사이트가 수반되고 그 하부에 인접하는 벤토나이트에 비해서 상대적으로 원암의 광물성분이 거의 잔류되지 않는 점토광물 위주의 광물조성을 보인다. 전자현미경 하에서 몬모릴로나이트와 할로이사이트는 서로 혼재되기보다는 따로 구획되어 분리된 상태로 산출되는 경향이 있다. 몬모릴로나이트의 엽편상 결정형의 테두리가 다소 변형되어 무딘 편상 결정형의 양상을 보인다. 할로이사이트는 0.3 $\mu$m 내외의 폭과 2 $\mu$m 이내의 길이를 갖는 침상 내지 관상의 결정형을 이루고 흔히 다발형태의 집합체를 형성한다. 전자현미경 관찰을 통한 이들의 미시적 조직 및 산출 관계에 대한 해석에 의하면, 몬모릴로나이트에서 할로이사이트로의 상전이는 혼합층상 구조형 (M/H)과 같은 이들의 중간형 점토광물상을 거치지 않는 형식으로 이루어진 것으로 판단된다. 또한 몬모릴로나이트로부터 할로이사이트로의 변질반응은 산화조건에서 용해 및 침전 반응형식으로 진행되었던 것으로 해석된다 이 풍화변질 과정에서 $SiO_2$를 비롯하여 Na, K 및 Ca과 같은 화학성분들이 심하게 용탈되어 많은 용해공극이 형성되었고, 상대적으로 잔류.농집된 $A1_2$$O_3$와 Fe에 의해서 할로이사이트의 생성여건이 조성되었던 것으로 해석된다.

한반도(韓半島) 남부지역(南部地域)의 고령토-납석광상(鑛床) 생성기구(生成機構) (Some Aspects of Kaoline-Pyrophyllite Deposits in Southern Korea)

  • 상기남
    • 자원환경지질
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    • 제19권spc호
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    • pp.43-52
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    • 1986
  • Kaolin-pyrophyllite are locally abundant in the three hydrothermal areas at Yangsan-Tongnae area, Hadong-Sancheong area and Haenam area, deposits are originally composed of acidic volcanic rocks and anorthositic rocks in Hadong-Sancheong area. The clay deposits are formed in the near shallow depths environment through acid hydrothermal alteration. Hadong-Sancheong halloysite deposits are formed by alteration of anorthosite. These differences are mainly on the various country rocks, geological structure and properties of hydrothermal solutions. Country rock is mostly underlain by rhyolitic tuffaceous and anorthositic rocks and a large number of clay deposits were formed during volcanic activity through upper Cretaceous-lower Tertiary. Intrusive rocks is broadly distributed in this area and clay deposits are variable in shapelayer and funnel typed. Zonal pattern of mineral assemblage is as follows, Yangsan-Tongnae deposits-kaolinite, pyrophyllite, dumortierite, andalusite and sericite, Hadong-Sancheong-mostly halloysite, and Haenam-dickite, pyrophyllite, alunite and diaspore. The difference in the zonal pattern of altered rock is considered to depend on differences in the initial acidity of related hydrothermal solution, initial acidity was controlled by the oxygen fugacity.

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제주도 화산회사인의 특성 및 생성에 관한 연구. II. 사, 미사, 점토의 광물학적 특성 (Composition and Genesis of Volcanic Ash Soils in Jeju Island, II. Mineralogy of Sand, Silt and Clay Fractions)

  • 신제성
    • 한국광물학회지
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    • 제1권1호
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    • pp.40-47
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    • 1988
  • Mineralogy of sand, silt and clay fractions from the five chronosequence soils of Jeju Island is studied with the X-ray, TEM and SEM techniques. Soils of Songag and Donghong situated at lower elevations are generally developed on relatively of ash or alluvial deposits and contain mainly ferromagnesian minerals and feldspars, with some quartz, mica and volcanic glass. Crystalline minerals are dominant in the clay fraction; halloysite and vermiculite are abundant but small amounts of allophane are present. Clay migration results in well developed ferrigargillan, Soils of Pyeongdae and Heugag located at higher elevations are developed on relatively young volcanic ash with some contamination of continental aeolian dust probably containing quartz which may be come from acid ash shower. The absence of clay illuivation is due to the dominance of allophane. This clay mineral is associated with some gibbsite, imogolite and halloysite.

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국산카올린의 흡착성에 관한 연구(I) 국산카올린의 물성 (Studies on the Adsorptive Properties of Korean Kaolin(I) Physico-chemical Properties of Korean Kaolin)

  • 이계주;정필조
    • 약학회지
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    • 제29권2호
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    • pp.96-102
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    • 1985
  • Innovated utilization of Korean kaolins as pharmaceuticals is attempted, for which relevant properties including adsorptive behaviours are observed in connection with their mineralogical structures. In practice, physico-chemical properties are assessed by means of IR, XRD and thermal analysis including DTA, TG and DSC. Elemental analysis of the ore specimens under investigation is carried out in conventional manners. It is found that the chemical compositions are varied significantly with sampling sites and primary classifications. The clay ores thus analyzed are mainly composed of halloysite species. Proper benefication of the raw clays is necessary so that authentic requirements for medicinal use may be satisfied. White-colored premium grade halloysite could be utilized as therapeutics with relative ease after purification. Evidence indicates that gibbsite-like impurities are intercalated between the 1 : 1 layered moieties. Thermal behaviours may be characterized in such a fashion that loss of free water occurs near 100.deg. C and further heatings result in liberation of bound water near 500.deg. C, with subsequent transformation into amorphous metastable entities. Through thermal activation, enhanced pharmaceutical effects could be envisaged.

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유기용매 사용 감소를 위한 건식 기계 장치를 이용한 NH2-HNT 제조의 조건 변화와 스케일업 (Production of NH2-HNT Using Organic Solvent Reducing Dry Mechanical Device with Different Conditions and with Scale Up Settings)

  • 김문일
    • 한국산업융합학회 논문집
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    • 제27권2_2호
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    • pp.357-361
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    • 2024
  • Halloysite nanotube (HNT) has a nanotube structure with the chemical formula of Al2Si2O5(OH)4·nH2O and is a natural sediment of aluminosilicate. HNT has been used as additive to improve the mechanical properties of epoxy composites with exchange of amine group as a terminal functional group using huge amount of organic solvents. In order to save time and simplify complicated procedures, a dry coating machine was designed and used for amine group exchange in previous research. For better applications, it was conducted with different parameters and with scale up settings. Best condition was found to reduce usage of solvent, time and man power.