• Title/Summary/Keyword: halide

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Efficiency Improvement of an Electronic Ballast for HID Lamps (HID 램프용 전자식 안정기의 효율 개선)

  • 이성희;이치환;권우현
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.2
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    • pp.9-17
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    • 2002
  • A high-efficiency electronic ballast for HID lamps is presented. The ballast consists of a PFC and a resonant inverter. To reduce losses of the ballast, DC link voltage should be determined by taking into account the peak voltage of lamp and the maximum flux density should be kept 0.2[T] on all of inductors. AR inductor at bridge diode is employed in order to remove currant harmonics from PFC. An inductor is connected in series with an electrolytic capacitor at DC link to reject high-frequency current. The acoustic resonance is eliminated using the stead spectrum technique. The electronic ballast for 250[W] metal-halide discharge lamp is implemented and 96[%] efficiency, no acoustic resonance and low conducted EMI level are accomplished.

Changes in the Growth and Biochemical Composition of Nannochloropsis sp. Cultures Using Light-Emitting Diodes (LED (Light Emitting Diode)를 이용한 Nannochloropsis sp.의 성장 및 생화학적 조성 변화)

  • Park, Jin-Chul;Kwon, O-Nam;Hong, Sung-Eic;An, Heui-Chun;Bae, Jea-Hyun;Park, Mi-Sun;Park, Heum-Gi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.3
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    • pp.259-265
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    • 2013
  • The marine microalgae Nannochloropsis sp. was cultured under a metal halide lamp (MH) or light-emitting diodes (LEDs) of various wavelengths (blue, LB; red, LR; yellow, LY; green, LG; white, LW); changes in growth, total carotenoid, chlorophyll a, amino acid and fatty acid profiles were investigated. LB-exposed cultures exhibited the highest specific growth rate (SGR) (0.32), whereas LY-exposed cultures showed the lowest SGR (0.18). After cultivation for 9 days, the maximum dry cell weight (g/L) of LB-exposed cultures was significantly higher than that of those exposed to other light conditions (LB>MH>LW$${\geq_-}LG{\geq_-}$$LR>LY). The essential amino acid (EAA, %) contents of cultures exposed to LG, LB, LR and MH were higher than those exposed to LY and LW (P<0.05). Eicosapentaenoic acid and n-3 highly unsaturated fatty acid levels were significantly higher in MH-exposed cultures compared to those exposed to LY (P<0.05), with no marked difference compared to those exposed to LB, LG, LR and LW (P>0.05). The total carotenoid content was highest in LR-exposed cultures (18.0 mg/L), whereas MH showed the lowest (11.8 mg/L; P<0.05). Chlorophyll a content was highest in cultures exposed to LR compared to other light sources. These results suggest consistent differences in growth and biochemical composition after exposure to light of different wavelengths.

Synthesis and Structure of Tetrahomodioxa p-phenylcalix(4)arene dihexylether (Tetrahomodioxa p-phenylcalix(4) arene dihexylether의 합성 및 구조에 관한 연구)

  • 노광현;박영자
    • Korean Journal of Crystallography
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    • v.13 no.3_4
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    • pp.158-164
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    • 2002
  • Tetrahomodioxa p-phenylcalix(4)arene dihexylether(C/sub66/H/sub68/O/sub6/) has been synthesized and structurally characterized by X-ray diffraction. Reaction of tetrahomodioxa p-phenylcalix(4)arene with hexyl halide and NaH in DMF leads to the dihexyl derivatives, 7,13,21,27-tetraphenyl-29,31-dihexyloxy- 2,3,16,17-tetrahomo-3,17-dioxacalit(4)arenes. The crystal is orthorhombic, P2₁2₁2₁, a= 9.764(2), b=16.167(2), c=32.994(3) Å, V=5208(1) Å, Z= 4, Dc = 1.221 gcm/sup -3/. The structure was solved by direct methods and refined by full-matrix least squares. Refinement converged at R = 0.070 for 2009 observed reflections. This molecule has a C-1,2-alternate conformation with pseudo-centrosymmetry and has two pairs of opposite phenyl rings, which are approximately parallel to each other. The benzene rings A and B are up, and the rings C and D rings are down with respect to the plane of the macrocyclic ring.

Lewis Acid Degradation Characteristics of Perfluoropolyethers Derivatives (퍼프로로폴리에테르 유도체의 루이스 산 분해특성)

  • Chun, Sang-Wook;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.650-655
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    • 2014
  • The degradation characteristics of perfluoropolyether (PFPE) derivatives currently being used as computer hard disk lubricants have been investigated. Especially, we considered the effects of end group on degradation behavior of PFPE derivatives. It was found that the degradation of PFPE derivatives in the presence of $Al_2O_3$ involves two degradation mechanisms such as thermal degradation and Lewis acid disproportionation by $AlF_3$ which was mainly formed by oxide-to-halide reaction between $Al_2O_3$ and the degraded PFPE. The end groups were strongly related to Lewis acid disproportionation of PFPE derivatives, and it is due to the difference of electron donating ability in the each end groups. Even if PFPE derivatives have same repeating unit in the main chain, Lewis acid disproportionation was prohibited by higher electron donating ability by the end group which caused the high electron density at the acetal group in the repeating unit.

Studies on Chromatographic Behaviors of the Metal Complexes by Various Eluents (용리제의 종류에 따른 금속착물의 크로마토그래피적인 거동에 관한 연구)

  • Chang Eon Oh;Doo Cheon Yoon
    • Journal of the Korean Chemical Society
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    • v.31 no.1
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    • pp.31-36
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    • 1987
  • We examined eluting behaviors for cationic complexes with the eluting cations. Retention volumes of hydrophilic complexes when eluted by the high concentration of aqueous KCl, NaCl and $NH_4Cl solutions, have been increased in the order NH_4^+ > Na^+ > K^+$, but in the low concentration, retention volumes of hydrophilic complexes bave been increased in the order $Na^+ > NH4^+ > K^+$. On the order hand, retention volumes of hydrophobic complexes when eluted by aqueous KCl, NaCl and $NH_4Cl solutions, have been increased in the order NH_4^+ > Na^+ > K^+$ in the whole concentration range. And we examined eluting behaviors for cationic complexes with the eluting anions. Hydrophilic complexes were associated more strongly with chloride ion among halide ions. However, hydrophobic complexes were associated more strongly with iodide ion. Sulfate ion, a highly hydrated anion, was associated more strongly with hydrophilic complexes than with hydrophobic complexes.

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육지초인용 고광도 LED 대형등명기 연구 개발

  • Song, Sang-Bin;Ju, Jae-Yeong;Sin, Gyeong-Ho;Lee, Dong-Hui;Kim, Sang-Yu;Yu, Seong-Hwan
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2015.10a
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    • pp.322-323
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    • 2015
  • Traditional rotation type large beacon was characterized by frequent failure, long repair time and high cost etc. These problems are caused by traditional light sources(metal halide lamps or tungsten halogen lamps). In order to solve these problems, IALA standards-based(efficiency and reliability) large LED beacon technologies are needed. we developed by applying a LED. The object of the this project, to design a reflective optics and the high power LED lighting engine module. And to develop a rotational speed control system for controlling flash pattern of beacon. As a result, to develop of LED beacon for landfall mark that distance to reach the light 20NM to 27NM.

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A Study on High Efficiency of Phase Grating (은염에 형성된 위상형 회절격자의 고효율에 관한 연구)

  • Kim, Nam;Gil, Sang-Keun;Park, Han-Kyu
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.3
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    • pp.145-152
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    • 1989
  • Volume phase diffraction grating is formed in 5${mu}m$ Agfa 8E75 photographic emulsion film using He-Ne laser. It is dependent on the chemical processing rather than materials themselves that high diffraction efficiency can obtained in silver halide emulsions. With potassium dichromate bleach and alcohol drying, overall efficiency of 71% (81% after allowing for reflection at the two surfaces) has been achieved at an exposure of 180${mu}J/cm^2.$ Dichromate cross-linkage and air void by rapid dehydration increase refractive index modulation depth. The grating is swollen, which is newly identified by Scanning Electronic Microscope(SEM) photography, and it causes on-Bragg at larger angle than the recording angle. It is pointed out that controlling the emulsion thickness has an important role as a potential source for high diffraction efficiency.

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Irradiance Distribution in East Sea by Using Measured Optical Properties for Squid Jigging Vessels

  • Bae, JaeHyun;Kim, SangWoo;Park, TaeYang;Cho, HyunWoo;An, YoungDuk;Kim, SangHyun;Ra, HyunWoon;Cho, YoungSil;Koh, JaeSeok;Jung, MeeSuk
    • Journal of the Optical Society of Korea
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    • v.20 no.5
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    • pp.547-556
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    • 2016
  • A fishing lamp is the instrument for attracting distributed fish to a certain place, and is the lighting system mainly used in fishery. In the inshore fishing, most fishing lamps are used for squid and hairtail jigging fishing, and the light source of the fishing lamps mainly used is metal halide with 1.5 KW in electric power consumption. We will analyze the irradiance distribution according to depth because squid is attracted towards light. To analyze irradiance distribution by such fishing lamps, data for seawater Type-II among the seawater types defined in 1976 are applied to East Sea. However, the Type-II data have limitations in analyzing precise seawater transmission characteristics, due to insufficient information on deep seawater. This paper analyzed the irradiance distribution of fishing lamps using the measurement of transmission characteristics in the seawater in East Sea up to 100 m underwater instead of Type-II data, which is not sufficient for transmission. A compensation factor was drawn between the actual measurement data and Type-II data through seawater transmission characteristics simulation.

Synthesis of Conjugated Dienals by Palladium-Catalyzed Vinyl Substitution Reaction (팔라듐 촉매화 비닐 치환 반응을 이용한 Conjugated Dienals의 합성)

  • Jong-Tae Lee;Jin Il Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.5
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    • pp.335-341
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    • 1984
  • Acetals of ${\alpha},{\beta}$-unsaturated aldehydes reacted readily with aryl bromides in the presence of palladium catalyst and triethylamine to form aryl conjugated enals. Acrolein diethyl acetal and methacrolein diethyl acetal were reacted with phenyl bromides with substituents such as methyl and isopropyl groups at $100^{\circ}C$. The reaction products yields except the reaction of o-bromotoluene with methacrolein diethyl acetal. The products were identified by proton nuclear magnetic resonance and infrared spectroscopy. In the reverse combination of reactants to prepare aliphatic 2,4-dienals in good yield of above 50%, 3-bromopropenal dimethyl acetal and (E)-3-bromo-2-methylpropenal diethyl acetal were used as vinylic halide reactants and 1-alkenes and ethyl acrylate as olefin reactants.

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The Development of Buck Type Electronic Ballast for 250W MHL and Dimming System (250W MHL용 Buck Type 전자식 안정기 및 Dimming 시스템 개발)

  • 박종연;박영길;정동열;김한수
    • The Transactions of the Korean Institute of Power Electronics
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    • v.7 no.1
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    • pp.30-40
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    • 2002
  • This paper studies the electronic ballast development for 250w MH lamps. We have improved the input power factor using a PFC IC. To provide the rating voltage required In the lamps, we have used the buck type dc-dc converter By this method, the stress of switching devices in inverter can be reduced. The inverter is the Full-Bridge type. To eliminate the acoustic resonance phenomena of MH lamps, we have added the high frequency sinewave voltage to the low frequency square-wave voltage to the lamp. We hove developed the igniter circuit using the L, C devices. We could control dimming of the lamp by varying the output voltage of the buck converter. The time of illuminating lamps and luminous intensity could be adjusted by season and time band. The buck converter output voltage can be controlled and the no load and over current situation were Protected by the development of the microprocessor Program.