• Title/Summary/Keyword: hBN

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Microstructure and plasma resistance of Y2O3-BN composites (Y2O3-BN 복합체의 미세구조 및 내플라즈마 특성)

  • Lee, Hyun-Kyu;Lee, Seokshin;Kim, Bi-Ryong;Park, Tae-Eon;Yun, Young-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.3
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    • pp.127-132
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    • 2014
  • $Y_2O_3$-BN ceramic composites were fabricated from the slurries of yttria powder with average particle size of 3~10 ${\mu}m$. The slurry was fabricated by mixing PVA binder, NaOH for Ph control, PEG, BN powder and $Y_2O_3$ powder. The mixed $Y_2O_3$ powders were obtained by spray drying process from the slurry. The $Y_2O_3$-BN composite specimen was shaped in size of ${\O}14mm$ and then sintered at $1550^{\circ}C$ and $1600^{\circ}C$, respectively. The characteristics, microstructure, purities, densities, bulk resistance, thermal expansion, hardness and plasma resistance of the $Y_2O_3$-BN composites were investigated with the function of BN contents and sintering temperature.

Characterization and Synthesis of BN Fibers According to the Content of BN Nanopowder by Electrospinning Method (전기방사에 의한 질화붕소 나노분말의 함량에 따른 질화붕소 나노섬유 합성 및 특성 평가)

  • Lee, Jong Hyeok;Chun, Myoung Pyo;Hwang, Jin Ah;Jung, Young Geun;Chu, Jae Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.7
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    • pp.455-461
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    • 2018
  • Boron nitride (BN) nanofibers were fabricated using BN nanoparticles (70 nm) by electrospinning. Morphologies such as the diameter and density of the BN nanofibers are strongly influenced by the viscosity and dispersion state of the precursor solution. In this study, the precursor solution was prepared by ball milling BN nanoparticles and polyvinylpyrrolidone (PVP, Mw~1,300,000) in ethanol, which was electrospun and then calcined to produce BN fibers. High-quality BN nanofibers were well fabricated at a BN concentration of 15 wt% with their diameters in the range of 500 nm to 800 nm; the viscosity of the precursor solution was $400mPa{\cdot}S$. The calcination of the as-electrospun BN fibers seemed to be completed by holding them at $350^{\circ}C$ for 2 h considering the TGA data. The morphologies and phases of the BN fibers were investigated by scanning electron microscopy (SEM) and X-ray diffractometry (XRD), respectively; Fourier transform infrared (FT-IR) was also used for structure analysis.

Effect of MgB6 Addition on Synthesis of Hexagonal Boron Nitride (Hexagonal Boron Nitride의 합성에 있어서 MgB6 첨가의 효과)

  • Lee, Dae-Jin;Jee, Mi-Jung;Choi, Byung-Hyun;Lee, Mi-Jai;Cho, Nam-Hee;Cha, Mi-Sun
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.53-57
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    • 2009
  • The h-BN powder was synthesized by amorphous $B_2O_3$ and activated carbon at $1550^{\circ}C$ in nitrogen atmosphere, whose properties were examined according to $MgB_6$ addition. Amount of $MgB_6$ addition was varied in the range of $0{\sim}$10\;wt% of the initial mixture. It was observed that $MgB_6$ addition led to an increase in the amount and the grain size of h-BN and decrease in the amount of $B_4C$ forming. When $MgB_6$ added 5 wt%, the amount and crystallinity of h-BN increased as the holding time at the synthesis temperature was prolonged. It was also confirmed that the regularity of three-dimensional ordering of h-BN increases.

Surface Properties and Tool Wear of Si3n4-hBN Machinable Ceramics in Endmill Machining using Tungsten Carbide Tool (텅스텐 카바이드 공구를 사용한 앤드밀 가공에서 Si3n4-hBN 머시너블 세라믹스의 표면특성과 공구마멸)

  • Jang, Sung-Min;Cho, Myeong-Woo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.3 no.1
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    • pp.15-21
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    • 2004
  • The machining process of ceramics can be characterized by cracking and brittle fracture. In the machining of ceramics, edge chipping and crack propagation are the principal reasons to cause surface integrity deterioration. Such phenomenon can cause not only poor dimensional and geometric accuracy, but also possible failure of the ceramic parts. Thus, traditional ceramics are very difficult-to-cut materials. To overcome such problems, in this paper, h-BN powder, which gives good cutting property, is added for the fabrication of machinable ceramics by volume of 5, 10, 15, 20, 25 and 30%. The objectives of this paper is to evaluate the fracture phenomenon of the tungsten carbide tool and the variation of surface integrity of the manufactured machinable ceramics under various cutting conditions during end mill machining With CNC machining center.

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Molecular Cloning of Two Genes Encoding Cinnamate 4-Hydroxylase (C4H) from Oilseed Rape (Brassica napus)

  • Chen, An-He;Chai, You-Rong;Li, Jia-Na;Chen, Li
    • BMB Reports
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    • v.40 no.2
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    • pp.247-260
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    • 2007
  • Cinnamate 4-hydroxylase (C4H) is a key enzyme of phenylpropanoid pathway, which synthesizes numerous secondary metabolites to participate in development and adaption. Two C4H isoforms, the 2192-bp BnC4H-1 and 2108-bp BnC4H-2, were cloned from oilseed rape (Brassica napus). They both have two introns and a 1518-bp open reading frame encoding a 505-amino-acid polypeptide. BnC4H-1 is 57.73 kDa with an isoelectric point of 9.11, while 57.75 kDa and 9.13 for BnC4H-2. They share only 80.6% identities on nucleotide level but 96.6% identities and 98.4% positives on protein level. Showing highest homologies to Arabidopsis thaliana C4H, they possess a conserved p450 domain and all P450-featured motifs, and are identical to typical C4Hs at substrate-recognition sites and active site residues. They are most probably associated with endoplasmic reticulum by one or both of the N- and C-terminal transmembrane helices. Phosphorylation may be a necessary post-translational modification. Their secondary structures are dominated by alpha helices and random coils. Most helices locate in the central region, while extended strands mainly distribute before and after this region. Southern blot indicated about 9 or more C4H paralogs in B. napus. In hypocotyl, cotyledon, stem, flower, bud, young- and middle-stage seed, they are co-dominantly expressed. In root and old seed, BnC4H-2 is dominant over BnC4H-1, with a reverse trend in leaf and pericarp. Paralogous C4H numbers in Brassicaceae genomes and possible roles of conserved motifs in 5' UTR and the 2nd intron are discussed.

Analysis of the rate-distortion parameters between inter prediction modes in HEVC (HEVC에서 화면 간 예측 모드들 간의 율-왜곡 파라미터 분석)

  • Baek, Seung-Yong;Lee, Jae-Yong;Cho, Hye-Jeong;Chung, Kwang-Sue;Oh, Seoung-Jun
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2011.07a
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    • pp.177-179
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    • 2011
  • 최근 표준화가 진행되고 있는 HEVC는 H.264/AVC의 기본 구조를 유지하면서 각 부호화기의 성능을 향상시키는 방향으로 진행되고 있다. 기존의 H.264/AVC는 화면 간 예측에서 예측 정보를 보내지 않고 복호화가 가능한 SKIP 모드와 예측 정보를 보내주는 화면 간 예측 모드들을 사용한다. 그런데 SKIP 모드는 율-왜곡 측면에서 극단적인 특성을 갖기 때문에 SKIP 모드와 다른 화면 간 예측 모드들 사이에 넓은 율-왜곡 파라미터 간격이 존재하며, 이는 화질 저하의 원인이 된다. 본 논문에서는 HEVC에서도 동일한 문제점이 존재하는지 분석하기 위해 SKIP 모드와 화면 간 예측 모드들의 율-왜곡 파라미터에 대한 분석을 수행하였다. 분석 결과를 바탕으로 HEVC에서도 부호화 효율을 향상시키기 위하여 새로운 화면 간 예측 모드가 필요함을 보였다.

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Effect of hydrogen addition on the compressive residual stress of cubic boron nitride film (입방정 질화붕소 박막의 압축잔류응력에 미치는 수소첨가 효과)

  • Park, Jong-Geuk;Baek, Yeong-Jun;Lee, Uk-Seong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.46-47
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    • 2013
  • 다이아몬드와 같은 $sp^3$ 결합을 가지며, 다이아몬드 다음으로 경도가 강한 입방정 질화붕소(cBN)는 철계금속가공에의 적합성 및 낮은 증착온도로 인하여 표면 코팅소재로의 응용이 크게 기대되어 왔다. 그러나 증착시 cBN 상의 핵생성 이전에 필연적으로 증착되는 비정질 질화붕소(aBN) 및 육방정 질화붕소(hBN) 층의 대기 하에서의 불안정성 그리고 cBN 상의 증착에 수반되는 높은 압축 잔류응력으로 인해 모재와의 밀착력이 낮아지는 문제점 등으로 인해 응용이 크게 제한되어져 왔다. 본 발표에서는 아르곤(Ar)과 질소($N_2$)를 반응가스로 이용하여 스퍼터링법으로 증착한 질화붕소에서 발생하는 높은 잔류응력의 원인과 이를 낮추기 위해 반응가스에 첨가한 수소의 효과에 대해서 상세히 고찰해 보고자 한다.

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The Spectra Investigation of the Halo Planetary Nebula BoBn 1

  • Hyung, Siek;Otsuka, Masaaki;Tajitsu, Akito;Izumiura, Hideyuki
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.72.2-72.2
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    • 2010
  • The extremely metal-poor halo planetary nebula BoBn 1 has been investigated based on IUE archive data, Subaru/HDS spectra, VLT/UVES archive data, and Spitzer/IRS spectra. We have measured a heliocentric radial velocity of $+191.6\pm1.3\;kms^{-1}$ and expansion velocity 2Vexp of $40.5\pm3.3\;kms^{-1}$ from an average over 300 lines. The estimations of C, N, O, and Ne abundances from the optical recombination lines (ORLs) and Kr, Xe, and Ba from the collisional excitation lines (CELs) are also done. We have detected 5 fluorine and several slow neutron capture elements (the s-process). The amounts of [F/H], [Kr/H], and [Xe/H] suggest that BoBn 1 is the most F-rich among F detected PNe and is a heavy s-process element rich PN. The photo-ionization models built with non-LTE theoretical stellar atmospheres indicate that the progenitor was a 1-1.5 $M_\bigstar$ that would evolve into a white dwarf with an $0.62M_{\odot}$ core mass and $0.09M_{\odot}$ ionized nebula. Careful examination implies that BoBn 1 has evolved from a binary and experienced coalescence during the evolution to become a visible PN. The elemental abundances except N could be explained by a binary model composed of $0.75M_{\odot}+1.5M_{\odot}$ stars.

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