• 제목/요약/키워드: growth morphology

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승화법으로 성장된 AlN 결정의 성장 양상에 관한 연구 (A study on the growth morphology of AlN crystals grown by a sublimation process)

  • 강승민
    • 한국결정성장학회지
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    • 제19권5호
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    • pp.242-245
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    • 2009
  • 종자결정을 사용하지 않고 AlN 결정을 승화법으로 성장하였으며, 결정이 성장되는 양상을 고찰하였다. AlN 결정으로 성장된 상은 다결정 상이었으며, 약 $60\sim160\;{\mu}m$의 크기를 가졌으며, $0.2\sim0.5\;{\mu}m/hr$의 성장 속도로 성장되었다. 성장된 결정구조는 AlN 결정의 결정 구조가 반영된 육방정계의 결정상으로 성장되었음을 관찰하였으며, 주상 구조(columnar structure)로 성장된 후 횡적 성장(lateral growth)하는 양상을 보이면서 대형화됨을 알 수 있었다. 성장된 결정의 표면에서는 다량의 pinhole이 관찰되었으며, 광학현미경과 SEM을 이용하여 성장 morphology의 변화과정을 고찰하였다.

안모수직 부조화에 따른 하악이부 형태에 관한 연구 (A STUDY OiM THE MORPHOLOGY OF CHIN IN RELATION TO VERTICAL DYSPLASIA OF CRANIOFACIAL COMPLEX)

  • 차봉근;서정훈
    • 대한치과교정학회지
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    • 제20권1호
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    • pp.135-156
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    • 1990
  • This study was undertaken to investigate the difference of chin morphology and mandibular form in relation to different mandibular growth direction. The subject was divided into three group i.e., control group, vertical group, and horizontal group, according to the criteria of $Bj{\ddot{o}}rk$ sum, and each group was composed of 15 females and 15 males. Medial axis analysis in addition to the routine cephalometric analysis using P.I.A.S. (personal image analysing system) was carried out to find out the differences of mandibular morphology on each group. The results were as follows: 1. The area of symphysis was larger in horizontal growth group than that of vertical growth group. 2. Protruding chin area was also larger in horizontal growth group than that of vertical growth group. 3. There was a close correlationship between protruding chin area and other form of mandible. 4. Antegonial notch depth and ramus posterior contour depth was deeper in vertical growth group than in horizontal growth group, and antegonial notch depth was more influenced by anterior part of notch than posterior part of notch. 5. Mental medial axis and incisal medial axis length, in relation to corpus medial axis length was larger in vertical growth group than in horizontal growth group.

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Investigation of carbon nanotube growth termination mechanism by in-situ transmission electron microscopy approaches

  • Kim, Seung Min;Jeong, Seojeong;Kim, Hwan Chul
    • Carbon letters
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    • 제14권4호
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    • pp.228-233
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    • 2013
  • In this work, we report in-situ observations of changes in catalyst morphology, and of growth termination of individual carbon nanotubes (CNTs), by complete loss of the catalyst particle attached to it. The observations strongly support the growth-termination mechanism of CNT forests or carpets by dynamic morphological evolution of catalyst particles induced by Ostwald ripening, and sub-surface diffusion. We show that in the tip-growth mode, as well as in the base-growth mode, the growth termination of CNT by dissolution of catalyst particles is plausible. This may allow the growth termination mechanism by evolution of catalyst morphology to be applicable to not only CNT forest growth, but also to other growth methods (for example, floating-catalyst chemical vapor deposition), which do not use any supporting layer or substrate beneath a catalyst layer.

Nucleation and Growth of Diamond in High Pressure

  • Choi, Jun-Youp;Park, Jong-Ku;Kang, Suk-Joong L.;Kwang, Yong-Eun
    • The Korean Journal of Ceramics
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    • 제2권4호
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    • pp.221-225
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    • 1996
  • In diamond synthesis by metal film growth method under high pressure and high temperature, the nucleation and growth of diamond was observed dependent on the carbon source variation from graphite powder to the heat treated powders of lamp black carbon. At the low driving force condition near equilibrium pressure and temperature line, nucleation of diamond did not occur but growth of seed diamond appeared in the synthesis from lamp black carbon while both nucleation and growth of diamond took place in the synthesis from graphite. Growth morphology change of diamond occurred from cubo-octahedron to octahedron in the synthesis from graphite but very irregular growth of seed diamond occurred in the synthesis from lamp block carbon. Lamp black carbon transformed to recrystallized graphite first and very nucleation of diamond was observed on the recrystallized graphite surface. Growth morphology of diamond on the recrystallized graphite was clear cubo-octahedron even at higher pressure departure condition from equilibrium pressure and temperature line.

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Shape Control of Gold Nanocrystal: Synthesis of Faceted Gold Nanoparticles and Construction of Morphology Diagram

  • Ahn, Hyo-Yong;Lee, Hye-Eun;Nam, Ki Tae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.281.1-281.1
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    • 2013
  • Shape control of gold nanocrystal is still one of the most important challenges remaining to achieve geometry dependent properties. Thus far, several strategies have been developed to control the shape of nanoparticles, such as adding capping agents and diverse additives or adjusting the temperature and pH. Here, we used an already established seed-mediated method that allowed us to focus on controlling the growth stage. Cetyltrimethylammonium bromide (CTAB) and ascorbic acid (AA) were used as the ligand and the reducing agent, respectively, without using any additional additives during the growth stage. We investigated how the relative ratio of CTAB and AA concentrations could be a major determinant of nanoparticle shape over a wide concentration range of CTAB and AA. As a result, a morphology diagram was constructed experimentally that covered the growth conditions of rods, cuboctahedra, cubes, and rhombic dodecahedra. The trends in the morphology diagram emphasize the importance of the interplay between CTAB and AA. Furthermore, high-index faceted gold nanocrystal was obtained by two step seeded growth. Already synthesized cubic particles developed into hexoctahedral nanocrystal consisting of 48 identical {321} facets, which indicates that the growth of gold nanocrystal is affected by initial morphology of seed particles. The hexoctahedral gold nanoparticles can be used in catalysis and optical applications which exploiting their unique geometry. Our research can provide useful guidelines for designing various facetted geometries.

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용액성장된 ZnS 박막의 표면형상 및 양자사이즈효과 (Surface Morphology and Quantum Size Effect of ZnS Thin Film Grown by Solution Growth Technique)

  • 이종원;이상욱;조성룡;김선태;박인용
    • 한국재료학회지
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    • 제12권1호
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    • pp.36-43
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    • 2002
  • In this study, the nanosized ZnS thin films that can be used for fabrication of blue light-emitting diodes, electro-optic modulators, and n-window layers of solar cells were grown by the solution growth technique (SGT), and their surface morphology and film thickness and grain size dependence on the growth conditions were examined. Based on these results, the quantum size effects of ZnS were systematically investigated. Governing factors related to the growth condition were the concentration of precursor solution, growth temperature, concentration of aq. ammonia, and growth duration. X-ray diffraction patterns showed that the ZnS thin film obtained in this study had the cubic structure ($\beta$-ZnS). With decreasing growth temperature and decreasing concentration of precursor solution, the surface morphology of film was found to be improved. Also, the film thickness depends largely on the ammonia concentration. In particular, this is the first time that the surface morphology dependence of ZnS film grown by SGT on the ammonia concentration is reported. The energy band gaps of samples were determined from the optical transmittance values, and were shown to vary from 3.69 eV to 3.91 eV. These values were substantially higher than 3.65 eV of bulk ZnS. It was also shown that the quantum size effect of SGT grown ZnS is larger than that of the ZnS films grown by most other growth techniques.

NYAB 결정육성시 종자정의 방향이 성장외형 및 표면형상에 미치는 영향 (The Effect of Seed Orientation on Growth Form and Surface Morphology in Growing NYAB Crystal)

  • 정선태;최덕용
    • 한국결정학회지
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    • 제5권2호
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    • pp.93-99
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    • 1994
  • K2O/3MOOS/0.SBB03 융제를 사용하여 TSSG 법으로 육성한 Md:Yal3(BO3)4 (NYAB) 단결정의 결정외형 및 표면형상을 연구하였다. <100>과 <120> 종자정을 사용한 경우는 서로 다른 크기의 프리즘 면들과 (101) 면들이 발달하였고 <001> 종자정을 사용하였을 때는 (001) 면이 함께 발달하였다. 종자정의 방향이 <100>또는 <120> 일때 프리즘 면 위에 성장구룽이 많이 형성되었으나, <001> 일때는 이웃하는 (101) 면에 평행한 줄무늬가 형성 되었다. (101) 면은 이차원 핵생성에 의한 성장이 지배적이고, <001> 종지정을 사용할 때 발달하는 (001) 면은 나선형 전위에 의한 성장이 지배적이었다. 종자정의 방향은 성장외형을 변화시키고 성장외형과 결정의 질을 결정하는 중요한 성장변수로 작용하였다.

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악안면 성장양상에 따른 하악이부 헝태에 관한 연구 (A STUDY ON CORRELATIONSHIP BETWEEN CRANIOFACIAL GROWTH PATTERN AND SYMPHYSIS MORPHOLOGY)

  • 남현진;유영규
    • 대한치과교정학회지
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    • 제26권5호
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    • pp.601-611
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    • 1996
  • 교정치료에 있어서 악안면 성장의 양상은 진단과 치료계획 수립에 있어서 매우 유용한 자료이며 교합의 달성 및 안모의 형태, 발육에 많은 영향을 미친다. 따라서 성장유형의 분류에 대한 많은 연구가 있었으며 성장예측을 위한 많은 시도가 있었다. 이에 본 연구에서는 성인 120명을 대상으로 치료전 측모두부계측 방사선사진을 이용하여 전안면고경에 대한 후안면고경의 비를 측정하여 $56\%-62\%$는 시계방향 성장군(36명), $65\%-80\%$는 반시계방향 성장군(43명)으로, 그리고 $62\%-65\%$는 정상군(41명)으로 분류하고 이에 따른 하악이부의 형태와 돌출정도 평가를 시행한 결과 다음과 같은 결과를 얻었다. 1. 남녀 하악이부 형태비교에 있어서는 남자가 여자보다 이부의 높이와 돌출정도가 크게 나타났다. 2. 시계방향 성장군이 반시계방향 성장군에 비해 하악이부의 Height, H/D ratio, Actual length는 크게 나타났고, Depth, Angle, effective length, E/A ratio는 작은 값을 나타냈다. 3. 악안면 성장양상에 있어 이부의 돌출정도가 작을수록 시계방향성장 경향을 나타내며, 돌출정도가 클수록 반시계방향성장 경향을 나타냈다.

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