• Journal of Soil and Groundwater Environment
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• v.20 no.6
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• pp.95-102
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• 2015

The purpose of this study is to compare the degradation characteristics by subcritical water of RDX contaminated soil using batch mode and dynamic mode devices. First, upon application of RDX contaminated soil, RDX treatment efficiency was increased with increasing the temperature in both modes. At 150℃, the treatment efficiency was 99.9%. RDX degradation efficiency got higher with lower ratio of solid to liquid. However, the treatment efficiency in the dynamic mode tended to be decreased at a certain ratio of solid to liquid or lower. The treatment efficiency was increased when it took longer time for the reactions in both modes. As the results of analysis on concentration of treated water after subcritical water degradation, the RDX recovery rate of dynamic and batch modes at 150℃ was 10.5% and 1.5%, respectively. However, both modes showed very similar recovery rates at 175℃ or higher. RDX degradation products were analyzed in treated water after it was treated with subcritical water. According to the results, RDX degradation mechanism was mostly oxidation reaction and reduction reaction was partially involved. Therefore, it suggested that most of RDX in soil was degraded by oxidation of subcritical water upon extraction. According to this result, it was found that both batch and dynamic modes were very effectively applied in the treatment of explosive contaminated soil.

• Journal of Soil and Groundwater Environment
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• v.20 no.5
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• pp.47-51
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• 2015

Biocatalytic degradation of total petroleum hydrocarbons (TPHs) in contaminated soil by hemoglobin and hydrogen peroxide is an effective soil remediation method. This study used a laboratory soil reactor experiment to evaluate the effectiveness of a nonspecific biocatalytic reaction with hemoglobin and H₂O₂ for treating TPH-contaminated soil. We also quantified changes in the soil microbial community using real-time PCR analysis during the experimental treatment. The results show that the measured rate constant for the reaction with added hemoglobin was 0.051/day, about 3.5 times higher than the constant for the reaction with only H₂O₂ (0.014/day). After four weeks of treatment, 76% of the initial soil TPH concentration was removed with hemoglobin and hydrogen peroxide treatment. The removal of initial soil TPH concentration was 26% when only hydrogen peroxide was used. The soil microbial community, based on 16S rRNA gene copy number, was higher (7.1 × 10⁶ copy number/g of bacteria, and 7.4 × 10⁵ copy number/g of Archaea, respectively) in the hemoglobin catalyzed treatment. Our results show that TPH treatment in contaminated soil using hemoglobin catalyzed oxidation led to the enhanced removal effectiveness and was non-toxic to the native soil microbial community in the initial soil.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.5
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• pp.788-793
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• 2011

To evaluate fertilizer value of animal cadavers for agricultural recycling, fertilizer components of animal cadavers by pig and poultry were investigated using rendering and alkali (KOH) treatment methods. Total nitrogen concentrations in meat waste by pig and poultry using rendering treatment method were 7.80% and 9.30%, respectively. Total nitrogen concentration in meat waste of pig by KOH treatment method was lower than that by rendering treatment method. Organic matter concentrations in meat waste of pig and poultry ranged 87.8~97.4%. Total phosphorus concentrations in bone waste of pig using rendering and KOH treatment methods ranged 5.59~11.18%. Animal cadavers contains nitrogen, phosphorus, potassium and other nutrients essential to plant growth. The results of this study suggest that animal cadavers can supply some of the nutrient requirements of crops and is a valuable fertilizer as well.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2019.05a
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• pp.349-350
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• 2019

• Economic and Environmental Geology
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• v.34 no.3
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• pp.307-313
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• 2001

Reactive medium including zero-valent metals such as zero-valent iron ($Fe^0$) degrades chlorinated solvents as a contaminant plume flows through the treatment medium. Although the Feo based reactive barrier has been demonstnlted to be a cost effective for trichloroethenc (TCE)-contaminaled plume remediation, current approach is limited by low process eftlciency and uncertain, effective life of the medium. The objective of this study is to develop an enhanced treatment method of TeE-contaminated groundwater using Feo and direct current. The bench-scale test using flow-through $Fe^0$ reactor column confirmed that the application of direct current with $Fe^0$ is highly effective in enhancing the rate of TeE dechlorination. The dechlorination mechanism appears to be reductive, with the electrons supplied by the iron oxidation and external power supply serving as the additional source of electrons.

• Journal of Soil and Groundwater Environment
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• v.18 no.7
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• pp.25-31
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• 2013

Hydrogen peroxide takes much of the cost for Fenton reaction applied for treatment of organic contaminants. Therefore, the effective use of hydrogen peroxide makes the technology more cost effective. The effective use of hydrogen peroxide is especially needed in the soil and groundwater remediation where complete mixing is not possible and it takes a long time for reactive species to transport to the fixed target compounds. Stabilization ability for hydrogen peroxide of malonic acid was evaluated in Fenton and Fenton-like reactions in this study. Malonic acid contributes on the stabilization of hydrogen peroxide by weak interaction between iron and the stabilizer and inhibiting the catalytic role of iron. The stabilization effect increased as the solution pH decrease below the $pK_{a1}$. The stabilization effect increased as the concentration of malonic acid increased and the effect was maximized at the malonic acid concentration of about ten times higher than the iron concentration. The model organic contaminant was successfully oxidized in the presence of the stabilizer but the degradation rate was slower than the system without the stabilizer. The stabilization effect was also proved in a Fenton-like reaction where magnetite and hematite were used instead of soluble iron species.

• Journal of Environmental Impact Assessment
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• v.16 no.6
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• pp.407-419
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• 2007

This study investigated the predicted and abserved outflow of groundwater which occurred during tunnel constructions. Among the 586 road construction projects from 1986 to 2006, 4 route 25 tunnel construction areas and 26 waste water treatment facilities under construction were studied. Most of the tunnel outflow prediction in EIA (Environmental Impact Assessment) process have been classified into the 17 types of units depending on the assessor's options, which have not conformed to the request of the residents and non government organizations. The investigation results showed that the outflow of underground water in tunnel construction areas averaged about $0.133m^3/km{\cdot}min$ with the maximum $0.386m^3/km{\cdot}min$, and that the outflow mostly occurred in the early stage of tunnel excavation and diminished gradually. The prediction of outflow of underground water in the EIA process showed excessive results compared to observed outflow, the even 51.7 times. Consequently for more realistic prediction, current EIA method for prediction of outflow of underground water in tunnel construction areas has to adopt numerical methods coupled with hydraulics and geologic informations from unit methods of present time.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.347-350
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• 2002

The petrochemical products can cause soil and groundwater contamination during their transportation and the use of the products, and while being contained in underground storage tanks(USTs) throughout the leakage. To treat the contaminated soil, the bioventing method is suitable for the remediation of semi-volatile compounds, such as diesel and kerosene. Biofiltration is one of possible method to treat the off-gas produced in the process of the bioventing. This study is related to the usage, effectiveness of treatment, and feasibility of two types of biofilter system made of ceramic-compost and polymer respectively to treat diesel VOCs at constant retention time of 20 sec. Compost biofilter showed the average removal efficiency of 73 % when the inlet concentration increased to 20 ppmv. Increased the inlet concentration decreased the microbial activities as well as the removal efficiency. On the contrary, the removal efficiency of the polyurethane biofilter was maintained at 88 % at the inlet concentration of 13 ppmv during ten days and was obtained to 80 % at the inlet concentration of 30 ppmv in spite of the drop of the efficiency in the sudden increase of the inlet concentration. At the beginning of the experiment it showed low removal efficiency at low inlet concentration due to the low microbial activity, however, as experiments proceed the removal efficiency could be obtained more than 80% at high inlet concentration.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.394-397
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• 2006

Hydrogeologic and hydrochemlcat conditions of two uncontrolled landfills without reliable underlying liners, leachate collection and treatment systems were compared. With similar weather conditions, spatial distribution and temporal variations of contaminants of concern and redox parameters were different for the two landfills. These differences are highly associated with ages and hydrogeologic settings of the landfills. Groundwater flow diverges from the Cheonan landfill while it converges to downgradient area in the Wonju landfill. Less permeable clayey silt layer or silty soil in the subsurface limited dispersion of leachate plume in the former landfill but highly permeable sandy soil with good lateral extent facilitated rapid plume dispersion in the latter landfill. In addition, hydraulic properties of the cover soil played a role in the different development of redox conditions, which resulted in significantly different concentrations of nitrates. Most problematic contaminants at downgradient wells of the landfills are ammonia and nitrate.

• Journal of Soil and Groundwater Environment
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• v.27 no.6
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• pp.37-46
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• 2022

As the amount of livestock wastewater increases, ammonia contamination in surface water and groundwater is also increasing, and its treatment is urgently needed. In this study, indigenous soil bacteria was utilized for ammonia removal in artificial wastewater and associated removal mechanisms and efficiencies were evaluated. Two batch reactors were configurated to contain natural soil and artificial wastewater at 1:10 mass ratio, and incubated for 84 and 168 hours, respectively. The results showed that ammonia was completely removed within 48 and 72 hours in the first and second reactors, respectively. There were no significant changes in ammonia concentrations in the control groups without soil. Nitrate was formed in the reactors, indicating that the main removal mechanism of ammonia was nitrification by nitrifying bacteria. Nitrate was further converted to nitrogen gas by denitrification in the anaerobic environment, which was caused by consumption of oxygen during the nitrification process.