• Journal of Korea Water Resources Association
• /
• v.54 no.11
• /
• pp.875-889
• /
• 2021

This study compares and analyzes the Soil and Water Assessment Tool (SWAT) and Terra MODIS (Moderate Resolution Imaging Spectroradiometer) as coniferous, deciduous and mixed forest with Yongdam Dam upstream (904.4 km²). The hydrologic evaluation period was set to 10 years from 2010 to 2019, and the applicability of the 8-day MOD15A2 Leaf Area Index (LAI) data, 3 TDR (Time Domain Reflectometry) (GB, JC, CC), and 1 Flux Tower (DU) evaporation volume (YDD) data was simulated. As a result, the R² of coniferous forest, deciduous forest and mixed forest are 0.95, 0.89, 0.90, soil moisture and evaportranspiration stations R² were analyzed at 0.50 to 0.55 and 0.51, respectively, with R² at 0.74, RMSE 2.75 mm/day, NSE 0.70 and PBIAS 14.3% for Yongdam inflow. Based on the calibrated and validated watersheds, the annual average evaportranspiration was calculated as coniferous 469.7 mm, deciduous 501. mm and 511.5 mm mixed forest, total runoff were estimated at coniferous 909.8 mm, deciduous 860.6 mm and 864.2 mm mixed forest. In the case of annual average evaportranspiration, it was evaluated that deciduous were high, but in the case of streamflow, it was evaluated that coniferous were high. Unlike other hydrologic with similar patterns throughout the year, the average annual evapotranspiration was about 7% higher than coniferous due to the higher evapotranspiration of deciduous with high leaf area index in summer and fall. In addition, deciduous were 9% and 6% higher for surface runoff and lateral flow, but the groundwater of coniferous was 77% higher. Therefore, it was confirmed that the total runoff was in order of coniferous, mixed forest, and deciduous.

• Economic and Environmental Geology
• /
• v.41 no.1
• /
• pp.63-79
• /
• 2008

Physicochemical characteristics of stream water, leachate, mine water and groundwater were investigated to estimate the influences of the tailing and waste rock from the abandoned Uljin mine area. Total extraction analysis and mineralogical studies were carried out to understand sulfide weathering and to determine the distributions of trace elements in the soil affected by mine waste (tailing, waste rock and leachate). The pH and EC value of the leachate from the tailing disposal ranged 2.9-6.0, $99{\sim}3,990{\mu}S/cm$, respectively, and the concentrations of dissolved major (up to 492 mg/l Ca; 83.8 mg/l Mg; 45.2 mg/l Na; 44.7 mg/l K, 50.8 mg/l Si) and trace elements (up to $826,060{\mu}g/l$ Fe; $131,230{\mu}g/l$ Mn; $333,600{\mu}g/l$ Al; $61,340{\mu}g/l$ Zn; $2,530{\mu}g/l$ Cu; $573{\mu}g/l$ Cd; $476{\mu}g/l$ Pb) were relatively high. The stream water showed the variation of dissolved metal concentrations in seasonally and spatially. The dissolved metal contents of the stream water increased by influx the leachate from the tailing disposal, but these of the down stream have been considerably decreased by mixing of dilute tributaries. The dissolved metal concentrations of the stream water at dry season (as February) were lower than these at rainy season (as May and July). These represent that the amounts of the leachate varied with season. However, stream water could not be effectively diluted by confluence with uncontaminated tributaries, because the flux of tributaries and streams reduced at dry season. Thus attenuations by dilution had been dominantly happened in rainy seasons. The order of accumulations of trace element in soils compared with background values revealed Mn>Fe>Pb>Cu>Zn. Sulfide minerals were mainly pyrrhotite, sphalerite and galena and chalcopyrite. Pyrrhotite was rapidly weathered along the edge and fractures, and results in the formation of Fe-(oxy)hydroxides, which absorbed a little amount of Zn.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.1
• /
• pp.33-42
• /
• 2000

Adsorption onto the surfaces of solid particles is a well known phenomenon that causes the retardation effect of heavy metals in soils. For adequate remediation of soil and groundwater contamination, it is important to investigate the mobility of heavy metals that largely depends on pH conditions in the soil water since adsorption of heavy metals is pH-dependent. In this study, we investigated the transport of Zn ion under various pH conditions in a sandy soil by conducting batch and column tests. The batch test was performed using the standard procedure of equilibrating fine fractions collected from the soil with eleven different initial $ZnCl_2$ concentrations, and analysis of Zn ion in the equilibrated solutions using ICP-AES. The column test consisted of monitoring the concentrations of soil solutions exiting the soil column with time known as a breakthrough curve (BTC). We injected respectively $ZnCl_2$ and KCl solutions with the concentration of 10 g/L as a tracer in a square pulse type under three different pH conditions (7.7, 5.8, 4.1) and monitored the flux concentration at the exit boundary using an EC meter and ICP-AES. The resident concentration was also monitored at the 10cm-depth by Time Domain Reflectometry (TDR). The results of batch test showed that ion exchange process between Zn and other cations (Ca, Mg) was predominant. The retardation coefficients obtained from adsorption isotherms (Linear, Freundlich, Langmuir) resulted in the various values ranging from 1.2 to 614.1. No retardation effect but ion exchange was found for the BTCs under all pH conditions. This can be explained by the absence of other cations to desorb Zn ion from soil exchange sites under the conditions of ETC experiment imposing blank water as leachate in steady-state flow. As pH decreased, the peak concentration of Zn increased due to the competition of Zn with hydrogen ions ($H^+$) and the concentrations of other cations decreased. The peak concentration of Zn was increased by 12.7 times as pH decreased from 7.7 to 4.1.