• Bulletin of the Korean Chemical Society
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• v.19 no.7
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• pp.747-753
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• 1998

The phoisomerization process of symmetric carbocyanine dyes such as 3,3'-diethyloxadicarbocyanine iodide (DODCI), 3,3'-diethylthiadicarbocyanine iodide (DfDCI), 1,1'-diethyl-2,2'-dicarbocyanine iodide (DDI), 1,1'-diethyl-2,2'-carbocyanine iodide (DCI), and cryptocyanine (1,1'-diethyl-4,4'-carbocyanine) iodide (CCI) have been studied by measuring the steady state and time resolved fluorescence spectra and the ground-state recovery profiles. The steady-state fluorescence spectrum of photoisomer as a function of concentration and excitation wavelength provides the evidence that the fluorescence of photoisomer is formed by the radiative energy transfer from the normal form and the quantum yield for the formation of photoisomer is increased by decreasing the excitation wavelength. The fluorescence decay profiles have been measured by using the time correlated single photon counting (TCSPC) technique, showing a strong dependence on the concentration and the detection wavelength, which is due to the formation of excited photoisomers produced either by the radiative energy transfer from the non-nal form or by absorbing the 590 nm laser pulse. We first report the fluorescence decay time of photoisomers for these cyanine dyes. The experimental results are explained by introducing the semiempirical calculations. The ground state recovery profiles of DTDCI, DDI, and CCI normal forms have been measured, showing that the recovery time from the singlet excited state is similar with the fluorescence decay time.

• Bulletin of the Korean Chemical Society
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• v.16 no.6
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• pp.547-552
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• 1995

As an extension to the Kramers' restricted Hartree-Fock (KRHF) method [J. Comp. Chem., 13, 595 (1992)], we have implemented the Kramers' restricted configuration interaction (KRCI) program in order to calculate excited states as well as the ground state of polyatomic molecules containing heavy atoms. This KRCI is based on determinants composed of the two-component molecular spinors which are generated from KRHF calculations. The Hamiltonian employed in the KRHF and KRCI methods contains most of all the important relativistic effects including spin-orbit terms through the use of relativistic effective core potentials (REP). The present program which is limited to a small configuration space has been tested for a few atoms and molecules. Excitation energies of the group 14 and 16 elements calculated using the present KRCI program are in good accordance with the spectroscopic data. Calculated excitation energies for many Rydberg states of K and Cs indicate that spin-orbit terms in the REP, which are derived for the ground state, are also reliable for the description of highly excited states. The electronic states of the polyatomic molecule CH3I are probed from the molecular region to the dissociation limit. Test calculations demonstrate that the present KRCI is a useful method for the description of potential energy surface of polyatomic molecules containing heavy atoms.

• Structural Engineering and Mechanics
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• v.59 no.4
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• pp.653-669
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• 2016

Recent earthquakes worldwide show that a significant portion of the earthquake shaking happens in the vertical direction. This phenomenon has raised significant interests to consider the vertical ground motion during the seismic design and assessment of the structures. Strong vertical ground motions can alter the axial forces in the columns, which might affect the shear capacity of reinforced concrete (RC) members. This is particularly important for non-ductile RC frames, which are very vulnerable to earthquake-induced collapse. This paper presents the detailed nonlinear dynamic analysis to quantify the collapse risk of non-ductile RC frame structures with varying heights. An array of non-ductile RC frame architype buildings located in Los Angeles, California were designed according to the 1967 uniform building code. The seismic responses of the architype buildings subjected to concurrent horizontal and vertical ground motions were analyzed. A comprehensive array of ground motions was selected from the PEER NGA-WEST2 and Iran Strong Motions Network database. Detailed nonlinear dynamic analyses were performed to quantify the collapse fragility curves and collapse margin ratios (CMRs) of the architype buildings. The results show that the vertical ground motions have significant impact on both the local and global responses of non-ductile RC moment frames. Hence, it is crucial to include the combined vertical and horizontal shaking during the seismic design and assessment of non-ductile RC moment frames.

• Journal of IKEEE
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• v.23 no.2
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• pp.474-478
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• 2019

In this paper, we analyze the degradation of receiving sensitivity due to the coupling between digital noise and mobile handset antenna using characteristic mode. First, we analyze the coupling mechanism between the antenna and digital noise, and analyze the role of the decoupling capacitor of the ground signal line, which is one of the ways to improve the antenna receiving sensitivity degradation due to camera noise. For the analysis, the digital signal line and the ground line of the FPCB of the camera module are modeled as a loop type feeder that excites the characteristic mode of the PCB ground, and improved model which has a ground line with a capacitor are analyzed.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.5
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• pp.493-499
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• 2010

In the sea-floating logistics port called mobile harbor a crane system with the different structure from the conventional above-ground container crane is installed. And, the dynamic stability of whole mobile harbor by the wave excitation is definitely affected by the crane positioned at the top. This paper is concerned with the dynamic rolling analysis of the mobile harbor subject to sea state 3 wave excitation, for which two-step analysis procedure composed of theoretical and numerical approaches is employed. First, the rigid rolling of mobile harbor is obtained according to the linear wave theory. And then, the dynamic rolling response of the flexible crane system caused by the rolling excitation of mobile harbor is analyzed by finite element analysis. The coupled interaction effect between the sea wave and the mobile harbor is taken into consideration by the added mass technique.

• Earthquakes and Structures
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• v.9 no.4
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• pp.875-891
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• 2015

Earthquake can occur anywhere in the world and it is essential to design important members in special structures based on maximum possible forces that can be produced in them under severe earthquake. In addition, since the earthquake is an accidental phenomena and there are no similar earthquakes, therefore the possibility of strong earthquakes should be taken into account in earthquake-resistant design of important structures. Based on this viewpoint, finding the critical acceleration which maximizes internal forces is an essential factor in structural design. This paper proposes critical excitation method to compute the critical acceleration in design of important members in special structures. These critical accelerations are computed so that the columns' internal shear force at the base of the structure at each time step is maximized under constraints on ground motion. Among computed critical accelerations (of each time step), the one which produces maximum internal shear force is selected. A numerical example presents to show the efficiency of critical excitation method in determining the maximum internal shear force and base moment under variety of constraints. The results show that these method can be used to compute the resonant earthquake which have large enough effective duration of earthquake strong motion (between 12.86 sec to 13.38 sec) and produce the internal shear force and base moment for specific column greater than the same value for selected earthquakes in constructing the critical excitation (for different cases about 2.78 to 1.29 times the San Fernando earthquake). Therefore, a group of them can be utilized in developing the response spectrum for design of special structures.

• Proceedings of the KSR Conference
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• 2004.10a
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• pp.1095-1100
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• 2004

When the walls and floor of a tunnel are excited by a train, a ground vibration energy is transmitted to the surface and to footing of a nearby buildings. Excessive vibration affected to a building structures causes undesirable effect to the structural safety and the perception on residents in building. In this paper, a simple approach is introduced to predict how much vibration, in terms of level and spectra, is transmitted through the ground from the tunnel vibration excitation. A high rise building on a tunnel is selected as an application example of this case study.

• Journal of the Earthquake Engineering Society of Korea
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• v.20 no.7_spc
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• pp.495-502
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• 2016

In this paper, time and frequency domain characteristics of Gyeong-ju earthquakes were investigated, and nonlinear time history analyses were conducted for bi-linear hysteretic structures excited by short-duration ground accelerations. Previous studies showed that larger inelastic displacements than the peak displacement of the corresponding elastic system were observed especially for the structures with structural period shorter than 0.3s, and the similar results could be obtained when long-duration ground accelerations were used as excitation loads. For the short-duration earthquakes, however, the inelastic displacements were not so large and almost identical to the peak elastic displacements.

• Steel and Composite Structures
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• v.9 no.2
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• pp.119-130
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• 2009

This paper reports results of the structural response of empty steel tanks under vertical ground motions. The tanks are modeled using a finite element discretization using shell elements, and the vertical motion is applied and analyzed using nonlinear dynamics. Several excitation frequencies are considered, with emphasis on those that may lead to resonance of the roof. The computational results illustrate that as the base motion frequency is tuned with the frequency of the first roof-mode of the tank, the system displays large-amplitude displacements. For frequencies away from such mode, small amplitude displacements are obtained. The effect of the height of the cylinder on the dynamic response of the tank to vertical ground motion has also been investigated. The vertical acceleration of the ground motion that induces significant changes in the stiffness of the tank was found to be almost constant regardless of the height of the cylinder.

• Bulletin of the Korean Chemical Society
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• v.22 no.6
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• pp.605-610
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• 2001

The molecular geometries and harmonic vibrational frequencies of dibenzofuran in the ground and lowest triplet state have been calculated using the Hartree-Fock and Becke-3-Lee-Yang-Parr(B3LYP)density functional methods with the 6-31G basis set. Upon the excitation to the lowest triplet state, the molecular structure retains the planar form but distorts from a benzene-like to a quinone-like form in skeleton. Scaled vibrational frequencies for the ground and lowest triplet state obtained from the B3LYP calculation show excellent agreement with the available experimental data. A few vibrational fundamentals for both states are newly assigned based on the B3LYP results.