• Composites Research
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• v.28 no.4
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• pp.168-175
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• 2015

Recently, the applications of carbon fiber reinforced plastics (CFRPs) have become broader than ever when it comes to such industries as automotive, ships, aerospace and military because of their lightweight-ness and high mechanical properties. Thermosetting plastics like epoxy are frequently used as the binding matrix in CFRPs due to their high hardness, wetting characteristics and low viscosity. However, they cannot melted and remolded. For this reason, thermosetting plastic wastes have caused serious environmental problems with the production of fiber reinforced plastics. Thus, many studies have focused on the carbon fiber reinforced thermoplastics (CFRTPs) and recycling carbon fiber. In this study, recycled carbon fiber (RCF) was prepared from CFRPs using a pyrolysis method, which was employed to separate resin and carbon fiber. The degree of decomposition for epoxy resin was confirmed from thermal gravimetric analysis (TGA) and scanning electron microscope (SEM). The RCF was cut and ground to prepare a carbon fiber composite sheet (CFCS). CFCS was manufactured by applying recycled carbon fibers and various thermoplastic fibers. Various characterizations were performed, including morphological analyses of surface and cross-section, mechanical properties, and crystallization enthalpy of CFCS at different cooling conditions.

• Journal of the Korean Chemical Society
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• v.55 no.6
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• pp.919-925
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• 2011

A new series of manganese(II), iron(III) and cobalt(III) complexes of 14-membered macrocyclic ligand, (3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane-1,8-diamine) have been prepared and characterized by elemental analyses, IR, UV-VIS, $^1H$- and $^{13}C$- NMR spectra, magnetic susceptibilities, conductivities, and ESR measurements. Molar conductance measurements in DMF solution indicate that the complexes are electrolytes. The ESR spectrum for cobalt(III) complex in $CD_3OD+10%D_2O$ after exposure to $^{60}Co-{\gamma}$-rays at 77 K using a 0.2217 M rad $h^{-1}$ vicrad source showed $g_{\perp}$ > $g_{\parallel}$ > $g_e$, indicating that, the unpaired electron site is mainly present in the $d_z2$ orbital with covalent bond character. In this case, the ligand hyperfine tensors are nearly collinear with ${\gamma}$-tensors, so there is no major tendency to bend. Therefore, little extra delocalization via the ring lobe of the $dz^2$ orbital occurs. However, the ESR spectrum in solid state after exposure to $^{60}Co-{\gamma}$-rays at 77 K showed $g_{\parallel}$ > $g_{\perp}$ > $g_e$, indicating that, the unpaired electron site is mainly present in the $d_x2_{-y}2$ ground state as the resulting spectrum contains a large number of randomly oriented molecules provided that, the principle directions of g and A tensors. Manganese (II) complex 2, $[H_{12}LMn]Cl_4.2H_2O$, showed six isotropic lines characteristic to an unpaired electron interacting with a nucleus of spin 5/2, however, iron(III) complex 3, $[H_{12}LFe]Cl_5.H_2O$, showed spectrum of a high spin $^{57}Fe$ (I=1/2), $d^5$ configuration. The geometry of these complexes was supported by elemental analyses, IR, electronic and ESR spectral studies. Complex 1 showed exploitation in reducing the amount of electron adducts formed in DNA during irradiation with low radiation products.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.111-125
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• 2022

Since landslide can cause huge damages to many facilities, close characterization of slopes is needed for appropriate reinforcements for the unstable ones in order to prevent the damages. Geophysical surveys, which can characterize a large area at a relatively low cost without disturbing slopes, have been widely employed for the assessment of slope stability in other countries. However, only conventional direct investigation methods are mainly used in Korea. In this paper, we analyzed various cases, which evaluated slope stabilities by characterizing slopes using geophysical exploration. First, we introduced changes in geophysical properties due to unstable media of slope like fracture location, fracture connectivity and distribution of groundwater level, and subsequently discussed the applicability of geophysical methods to the detection of the changes; the methods include electrical resistivity survey, seismic survey, self-potential survey, induced polarization survey and ground penetrating radar. Based on this description, we analyzed how geophysical surveys were performed on various slopes.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.2C
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• pp.109-120
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• 2006

SPT-Uphole test is a seismic field test using receivers on ground surface and a SPT (Standard penetration test) source in depth. Even though this method is simple and economic, it makes hesitate to apply in real field that it is difficult to obtain reliable travel time information of shear wave because of the characteristics of SPT impact source. To overcome this shortcoming, in this paper, modified SPT-Uphole method using two component surface geophones was suggested. Numerical analysis was performed using finite element method for understanding the characteristics of surface motion induced by in-depth vertical source, and comparison study of the various methods which determine the travel time information in SPT-Uphole method was performed. In result, it is thought that the most reasonable method is using the first local maximum point of the root mean square value signals of vertical and horizontal component in time domain. Finally, modified SPT-Uphole method using two component surface geophones was performed at the site, and the applicability in field was verified by comparing wave velocity profiles determined by the SPT-Uphole method with the profiles determined by SASW method and SPT-N values.

• Journal of the Korean Geotechnical Society
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• v.39 no.12
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• pp.115-125
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• 2023

In this study, we evaluated the behavior of frozen soil using an electrical resistivity survey method-a nondestructive technique-and examined its characteristics through field experiments. Frozen soil was artificially prepared by injecting fluid to accelerate the freezing process, and naturally frozen soil was selected in a nearby area for comparison. A dynamic cone penetration test (DCPT) was performed to compare the reliability of the electrical resistivity survey, and time-domain reflectometry surveys were performed to assess the moisture content of the ground. Field experiments were conducted in February-when the atmosphere temperature was below freezing-and May-when the temperature was above freezing. This temperature-compensated method was used to determine reliability because the behavior of frozen soil depends on the underlying temperature. In the resistivity survey method, a section of high electrical resistivity was observed under freezing conditions due to the frozen water and converted into porosity. The converted porosity was compared with the porosity inferred from the DCPT, and the results showed that the measured electrical resistivity was valid.

• Journal of the Korean Geotechnical Society
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• v.40 no.3
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• pp.55-63
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• 2024

Xanthan gum biopolymer is an ecofriendly ground stabilizer that maintains stability in a wide range of temperatures and pH values. The binding effect of sandy soil particles realized by injecting xanthan gum biopolymer is dependent on the xanthan gum matrix, which is formed during the drying process; thus a study on the effects of the drying process of the xanthan gum solution on the changes in stiffness characteristics of sandy soil is required. In this study, shear wave velocity and electrical resistivity were monitored in sandy soil specimens saturated with biopolymer solutions of different gravimetric concentrations to investigate the improvement effects of biopolymer-treated sandy soils with the drying process. The experimental results reveal that both shear wave velocity and electrical resistivity increase during drying process. The results demonstrate the stiffness improvement effects of biopolymer-treated sandy soils. In addition, a higher stiffness improvement effect was monitored in the biopolymer-treated sandy soils with a higher gravimetric concentration. The results of this study may be used to estimate the stiffness improvement effects of sandy soils treated with biopolymer solutions with the drying process.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.27-35
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• 2003

The study site located in an industrial complex has a Precambrian age gneiss as a bedrock. The poorly-developed, disturbed soils in the study site have loamy-textured surface soil (1 to 2 m) and gravelly sand alluvium subsurface (2 to 6 m) on the top of weathered gneiss bedrock. The depth of the groundwater table was about 3.5 m below ground surface and increased toward down-gradient of the site. The hydraulic conductivity of transmitted zone (gravelly coarse sand) was in the range of 5.0${\times}$10$\^$-2/∼1.85${\times}$10$\^$-1/ cm/sec. The fine sand layer was in the range of 1.5${\times}$10$\^$-3/ to 7.6${\times}$10$\^$-3/ cm/sec. and the reclaimed upper soil layer was less than 10$\^$-4/ cm/sec. Toluene, ethylbenzene, and xylene (TEX) was the major contaminant in the soil and groundwater. The average depth of the soil contamination was about 1.5 m in the gravelly sand alluvium layer. At the depth interval 2.4∼4.8 m, the highest contamination in the soil is located approximately 50 to 70 m from the suspected source areas. The concentration of TEX in the groundwater was highest in the suspected source area and a lesser concentration in the center and southwest parts of the site. The TEX distribution in the groundwater is associated with their distribution in the soil. Microbial isolation showed that Pseudomonas flurescence, Burkholderia cepacia, and Acinetobactor lwoffi were the dominant aerobic bacteria in the contaminated soils. The analytical results of the groundwater indicated that the concentrations of dissolved oxygen (DO), nitrate, and sulfate in the contaminated area were significantly lower than their concentrations in the none-contaminated control area. The results also indicated that groundwater at the contaminated area is under anaerobic condition and sulfate reduction is the predominant terminal electron accepting process. The total attenuation rate was 0.0017 day$\^$-1/ and the estimated first-order degradation rate constant (λ) was 0.0008 day$\^$-1/.

• Korean Chemical Engineering Research
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• v.53 no.5
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• pp.620-626
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• 2015

$Ho^{3+}$ doped $SrAl_2O_4$ upconversion phosphor powders were synthesized by spray pyrolysis, and the crystallographic properties and luminescence characteristics were examined by varying activator concentrations and heattreatment temperatures. The effect of organic additives on the crystal structure and luminescent properties was also investigated. $SrAl_2O_4:Ho^{3+}$ powders showed intensive green emission due to the $^5F_4/^5S_2{\rightarrow}^5I_8$ transition of $Ho^{3+}$. The optimal $Ho^{3+}$ concentration in order to achieve the highest luminescence was 0.1%. Over this concentration, emission intensities were largely diminished via a concentration quenching due to dipole-dipole interaction between activator ions. According to the dependence of emission intensity on the pumping power of a laser diode, it was clear that the upconversion of $SrAl_2O_4:Ho^{3+}$ occurred via the ground state absorption-excited state absorption processes involving two near-IR photons. Synthesized powders were monoclinic as a major phase, having some hexagonal phase. The increase of heat-treatment temperatures from $1000^{\circ}C$ to $1350^{\circ}C$ led to crystallinity enhancement of monoclinic phase, reducing hexagonal phase. The hexagonal phase, however, did not disappear even at $1350^{\circ}C$. When both citric acid (CA) and ethylene glycol (EG) were added to the spray solution, the resulting powders had pure monoclinic phase without forming hexagonal phase, and led to largely enhancement of crystallinity. Also, N,N-Dimethylformamide (DMF) addition to the spray solution containing both CA and EG made it possible to effectively reduce the surface area of $SrAl_2O_4:Ho^{3+}$ powders. Consequently, the $SrAl_2O_4:Ho^{3+}$ powders prepared by using the spray solution containing CA/EG/DMF mixture as the organic additives showed about 168% improved luminescence compared to the phosphor prepared without organic additives. It was concluded that both the increased crystallinity of high-purity monoclinic phase and the decrease of surface area were attributed to the large enhancement of upconversion luminescence.

• Journal of Bio-Environment Control
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• v.18 no.4
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• pp.309-315
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• 2009

Maintenance of adequate soil water content during the period of crop growth is necessary to support optimum plant growth and yields. A better understanding of soil water movement for precision irrigation would allow efficient supply of water to crops, thereby resulting in minimization of water drainage and contamination of ground water. This research reports on the characterization of spatial and temporal variations in water contents through three different textured soils, such as loam, sandy loam, and loamy sand, when water is applied on the soil surface using an one-line drip irrigation system and the soils are dried after the irrigation stops, respectively. Water contents through each soil profile were continuously monitored using three Sentek probes, each consisting of three capacitance sensors at 10, 20, and 30cm depths. Spatial variability in water content for each soil type was strongly influenced by soil textural class. There were big differences in wetting pattern and the rate of downward movement between loam and sandy loam soils, showing that the loam soil had a wider wetting pattern and a slower rate of downward movement than did the sandy loam soil. The wetting pattern in loamy sand soil was not apparent due to a low variability in water content (< 10%) by a lower-water holding capacity as compared to those measured in the loam and sandy loam soils, implying that the rate of water drainage below a depth of 30cm was high. When soils were dried, there were highly exponential relationships between water content and time elapsed after irrigation stops ($r^2$${\geq}$0.98). It was estimated that equilibrium moisture contents for loam, sandy loam, and loamy sand soils would be 17.6%, 6.2%, and 4.2%, respectively.

• Journal of Bio-Environment Control
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• v.17 no.3
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• pp.231-237
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• 2008

Objective of this research was to investigate the effect of calcium concentrations in the fertilizer solution on growth and development of Ca deficiency in 'Maehyang' strawberry (Fragaria $\times$ ananassa Duch.). The margins of the youngest leaves were scorched and they developed a cupped shape as they were expanded in Ca deficient plants. The vein area of the youngest leaves became brown when the deficiency became severe. The quadratic responses were observed in dry weight production to elevated Ca concentrations in fertilizer solutions with the highest growth in 4.5 mM treatment. The regression equation was y=2.4026+1.0209x-$0.098x^2$ $(R^2=0.3546^{***})$. However, tissue Ca contents increased lineally as the Ca concentrations in fertilizer solutions were elevated (y=1.2108+0.1333x, $R^2=0.9189^{***}$). In changes of the fresh weight and Ca concentrations in petiole sap, fresh weight production showed quadratic responses to elevated Ca concentrations in fertilizer solution, but Ca concentration increased lineally. The equations in changes of fresh weight and Ca concentrations were y=9.273+4.882x-$0.4245x^2$ $(R^2=0.4935^{***})$ and y=52.311+3.2917x $(R^2=0.6918^{***})$, respectively. When the concentration of calcium at which plant growth was retarded by 10% is regarded as critical concentration level, the calcium contents based on dry weight of above ground plant tissue and in petiole sap should be in the range between 1.6 to 2.25% and 63 to $79mg{\cdot}kg^{-1}$, respectively.