• Journal of the Korean Applied Science and Technology
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• v.25 no.4
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• pp.518-524
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• 2008

In this study, positive plates of lead acid battery of Pb-Ca alloy and Pb-Ca-Sn alloy were fabricated and the mechanical characteristics of positive plates were measured. This study observed how the changes of content of Ca & Sn affect interface corrosion which is located in between grid & active materials and lead acid batteries as well. The mechanical characteristics of grid alloy is better when Ca is 0.05 wt.% then 0.1 wt.%. This study said that the corrosion rate between the active material based on the charge/discharge cycle of lead acid battery and grid interface is much faster than a grid which contains Sn. And furthermore, according to the study the rate 30 of Sn/Ca which is added to grid shows the best performance.

• Journal of the Korean institute of surface engineering
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• v.40 no.5
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• pp.225-233
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• 2007

Effects of alloying elements on the corrosion layer formation of Pb-grid/active materials interface has been researched for improvement of corrosion resistance of Pb-Ca alloy. For this research, various amounts of alloying elements such as Sn, Ag and Ba were added to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test. Overcharge life cycle test was carried out at $75^{\circ}C$, 4.5 A, for 110 hrs. with KS standard (KSC 8504). And then, after keeping the battery with open circuit state for 48 hr, discharge was carried out at 300A for 30 sec. Corrosion morphology and interface between Pb-grid and active materials were investigated by using ICP, SEM, WDX, and LPM. Corrosion layer of Pb-Ca alloy got thicken with increasing Ca content. For Pb-Ca-Sn alloy, thickness of corrosion layer decreased as Sn and Ag content increased gradually. In case of Pb-Ca-Sn-Ba alloy, thickness of corrosion layer decreased up to 0.02 wt% Ba addition, whereas, it was not changed in case of above 0.02 wt% Ba addition.

• Journal of the Korean Applied Science and Technology
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• v.25 no.1
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• pp.41-47
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• 2008

This study was conducted to made a grid alloy (Pb-Ca-Sn-Al) which has a temporary composition ratio in order to improve the efficiency of lead acid batteries. The positive activity material made a 3BS(tri-basic lead sulfate; $3PbO{\cdot}PbSO_4{\cdot}H_2O$) by a low temperature curing and it evaluates the plate efficiency through the life cycle testing. The initial current capacity of low temperature curing plate was excellent but the life cycle was not good (S1). As for the S2 plate, however, the initial current capacity and the life cycle were superior.

• Journal of Welding and Joining
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• v.30 no.1
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• pp.59-63
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• 2012

The spacer grid is one of the main structural components in a fuel assembly. It supports fuel rods, guides cooling water and maintains geometry from external impact load and cyclic stress by the vibration of nuclear fuel rod, it is necessary to have sufficient strength against dynamic external load and fatigue strength. In this study, the mechanical properties and fatigue characteristics of laser beam welded zircaloy thin sheet are examined. The material used in this study is a zirconium alloy with 0.66 mm of thickness. The fatigue strength under cyclic load was evaluated at stress ratio R=0.1. S-N curves are presented with statistical testing method recommend by JSME- S002 and compared with S-N curves at R.T. and $315^{\circ}C$. As a result of the experimental approach, the design guide of fatigue strength is proposed and the results obtained from this study are expected to be useful data for spacer gird design.

• Korean Journal of Materials Research
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• v.32 no.3
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• pp.146-152
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• 2022

One disadvantage of deep cycle flooded lead-acid batteries is increasing water loss caused by use of (+) Pb-Sb / (-) Pb-Sb alloy grid. Water loss is generated by the emission of hydrogen gas from the (-) electrode during battery charging. In this paper, we maintain cycle life aspect through the development of hybrid flooded lead-acid batteries to which a (+) Pb-Sb / (-) Pb-Ca grid is applied and deal with the improvement of water loss. The amount of water loss compared to that of the (-) Pb-Sb grid decreased when Ca was added to the (-) Pb grid. For the (-) Pb-Ca grid, it was confirmed that the time to reach 0.0 V, at which water decomposition occurs, was increased compared to that of the (-) Pb-Sb grid at the NPV (Negative Potential Voltage). In the cycle life test conducted with the BCI (Battery Council International) standard, compared to the (+) Pb-Ca grid, the (+) Pb-Sb grid increased the life cycle of the batteries and the (+) Pb-Ca grid showed an early end of life due to PbO corrosion layer generation, as determined through SEM / EDS and Tear Down analysis. In conclusion, by addition of Sb to (+) Pb grid and Ca to (-) Pb grid, we developed a hybrid flooded lead-acid battery that meets user requirements to improve water loss characteristics and preserve cycle life characteristics.

• Steel and Composite Structures
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• v.33 no.3
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• pp.433-444
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• 2019

Fatigue failure of a grid structure using bolt-sphere joints is liable to occur in a high-strength bolt due to the alternating and reciprocal actions of a suspension crane. In this study, variable amplitude fatigue tests were carried out on 20 40 Cr steel alloy M30 high-strength bolts using an MTS fatigue testing machine, and four cyclic stress amplitude loading patterns, Low-High, High-Low, Low-High-Low, and High-Low-High, were tested. The scanning electron microscope images of bolt fatigue failure due to variable amplitude stress were obtained, and the fractographic analysis of fatigue fractures was performed to investigate the fatigue failure mechanisms. Based on the available data from the constant amplitude fatigue tests, the variable amplitude fatigue life of an M30 high-strength bolt in a bolt-sphere joint was estimated using both Miner's rule and the Corten-Dolan model. Since both cumulative damage models gave similar predictions, Miner's rule is suggested for estimating the variable-amplitude fatigue life of M30 high-strength bolts in a grid structure with bolt-sphere joints; the S-N fatigue curve of the M30 high-strength bolts under variable amplitude loading was derived using equivalent stress amplitude as a design parameter.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.803-808
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• 2002

A computer-aided alloy-designing technique to develop the insert metal for transient liquid phase (TLP) bonding was applied to high aluminum Ni-base superalloys. The main procedure of a mathematical programming method was to obtain the optimal chemical composition through rationally compromising the plural objective performances of insert metal by a grid-search which involved data estimation from the limited experimental data using interpolation method. The objective function Z which was introduced as an index of bonding performance of insert metal involved the melting point, hardness (strength), formability of brittle phases and void ratio (bonding defects) in bond layer as the evaluating factors. The contour maps of objective function Z were also obtained applying the interpolation method. The compositions of Ni-3.0%Cr-4.0%B-0.5%Ce (for ${\gamma}$/${\gamma}$/${\beta}$ type alloy) and Ni3.5%Cr-3.5%B-3%Ti (for ${\gamma}$/${\gamma}$ type alloy) which optimized the objective function were determined as insert metal. SEM observations revealed that the microstructure in bond layers using the newly developed insert metals indicated quite sound morphologies without forming microconstituents and voids. The creep rupture properties of both joints were much improved compared to a commercial insert metal of MBF-80 (Ni-15.5%Cr-3.7%B), and were fairly comparable to those of base metals.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.8
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• pp.3358-3365
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• 2012

This paper presents a scheduling scheme for die casting processes considering power usage. The scheduling problem of a shift-based die casting process is represented by a linear programming (LP) model that maximizes the average efficiency of melting furnaces in regard of the usage of molten alloy, where the product quantities of each shift are used as primary variables. In this research, we propose a novel LP model that considers power usage of foundries. The developed LP model can derive product plans in which the expended power of a casting shift does not exceed a prescribed limit, while optimizing the efficiency of alloy usage. The simulation result of a case study demonstrates the superiority and applicability of the proposed scheme. This paper serves as a basic research on the role of foundries as an intelligent costumer in smart grid environment where the limit of power usage should be fulfilled.

• Nuclear Engineering and Technology
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• v.38 no.4
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• pp.375-382
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• 2006

Characterization tests (load vs. displacement curve) are conducted for the springs of Zirconium alloy spacer grids for an advanced LWR fuel assembly. Twofold testing is employed: strap-based and assembly-based tests. The assembly-based test satisfies the in situ boundary conditions of the spring within the grid assembly. The aim of the characterization test via the aforementioned two methods is to establish an appropriate assembly-based test method that fulfills the actual boundary conditions. A characterization test under the spacer grid assembly boundary condition is also conducted to investigate the actual behavior of the spring in the core. The stiffness of the characteristic curve is smaller than that of the strap-wised boundary condition. This phenomenon may cause the strap slit condition. A spacer grid consists of horizontal and vertical straps. The strap slit positions are differentiated from each other. They affords examination of the variation of the external load distribution in the grid spring. Localized legions of high stress and their values are analyzed, as they may be affected by the spring shape. Through a comparison of the results of the test and FE analysis, it is concluded that the present assembly-based analysis model and procedure are reasonably well conducted and can be used for spring characterization in the core. Guidelines for improving the mechanical integrity of the spring are also discussed.

• Journal of the Korean institute of surface engineering
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• v.39 no.6
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• pp.302-311
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• 2006

Nowadays the open-type lead-acid battery for vehicle use is being replaced with the sealed-type because it needs no maintenance and has a longer cycle life. Thus researches on this battery are being conducted very actively by many advanced battery companies. There is, however, a serious problem with the maintenance free(MF) battery that its cathode electrode has a limited cycle life due to a corrosion of grid. In this study, it was aimed to improve a corrosion resistance of the cathode grid which is commonly made of Pb-Ca alloy for a mechanical strength. For this purpose, various amounts of alloying elements such as Sn, Ag and Ba were added singly or together to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test and their corrosion layers appeared at the interface between the grids and the active materials were carefully observed in order to clarify effects of alloying elements.