• Title/Summary/Keyword: green phosphorescent OLED

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Green Phosphorescent OLED Without a Hole/Exciton Blocking Layer Using Intermixed Double Host and Selective Doping

  • Kim, Won-Ki;Kim, Hyung-Seok;Shin, Hyun-Kwan;Jang, Ji-Geun
    • Korean Journal of Materials Research
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    • v.19 no.5
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    • pp.240-244
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    • 2009
  • Simple and high efficiency green phosphorescent devices using an intermixed double host of 4, 4', 4"-tris(N-carbazolyl) triphenylamine [TCTA], 1, 3, 5-tris (N-phenylbenzimiazole-2-yl) benzene [TPBI], phosphorescent dye of tris(2-phenylpyridine)iridium(III) [$Ir(ppy)_3$], and selective doping in the TPBI region were fabricated, and their electro luminescent characteristics were evaluated. In the device fabrication, layers of $70{\AA}$-TCTA/$90{\AA}$-$TCTA_[0.5}TPBI_{0.5}$/$90{\AA}$-TPBI doped with $Ir(ppy)_3$ of 8% and an undoped layer of $50{\AA}$-TPBI were successively deposited to form an emission region, and SFC137 [proprietary electron transporting material] with three different thicknesses of $300{\AA}$, $500{\AA}$, and $700{\AA}$ were used as an electron transport layer. The device with $500{\AA}$-SFC137 showed the luminance of $48,300\;cd/m^2$ at an applied voltage of 10 V, and a maximum current efficiency of 57 cd/A under a luminance of $230\;cd/m^2$. The peak wavelength in the electroluminescent spectral and color coordinates on the Commission Internationale de I'Eclairage [CIE] chart were 512 nm and (0.31, 0.62), respectively.

New Green Phosphorescent Organic Light Emitting Devices with the (TCTA/$TCTA_{0.5}TPBI_{0.5}$/TPBI):$Ir(ppy)_3$ Emission Layer

  • Jang, Ji-Geun;Shin, Sang-Baie;Shin, Hyun-Kwan;Kim, Won-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.465-468
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    • 2008
  • New green light emitting phosphorescent devices with host structure of TCTA[4,4',4"-tris(N-carbazolyl)-triphenylamine]/$TCTA_{0.5}TPBi_{0.5}$/TPBI[1,3,5-tris(N-phenylbenzimiazole-2-yl)benzene] were proposed and investigated according to the thickness combination of host layers and the doping level of $Ir(ppy)_3$[tris(2-phenylpyridine) iridium(III)].

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Novel host and electron blocking materials for efficient and long lifetime phosphorescent OLEDs

  • Vestweber, Horst;Gerhard, Anja;Kaiser, Joachim;Heil, Holger;Kroeber, Jonas;Pflumm, Christof;Stoessel, Philipp;Joosten, Dominik;Buesing, Arne;Fortte, Rocco;Parham, Amir;Boehm, Edgar
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.925-927
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    • 2008
  • In order to improve the performance in green phosphorescent OLED devices, Merck has developed novel host and electron blocking materials. The newly developed host materials improve the device lifetime by a factor of 3. The newly developed electron blocking materials having not only electron but also exciton barrier properties increase the efficiency of the device by a factor of 1.4. Comparable results were achieved in phosphorescent red systems with further host materials.

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Highly efficient phosphorescent polymer OLEDs fabricated by screen printing

  • Lee, D.H.;Choi, J.S.;Cho, S.M.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.694-697
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    • 2007
  • We demonstrate the use of screen printing in the fabrication of highly efficient phosphorescent polymer organic-light-emitting devices (OLEDs) based on a green-emitting $Ir(ppy)_3$ and a host polymer PVK. We incorporate PBD in the polymer host as an electron-transporting dopant and ${\alpha}-NPD$ as a hole transporting dopant. The best screen printed single-layer device exhibits very high peak luminous efficiency of 63 cd/A at a relatively high operating voltage of 17.1 V at the luminance of $650\;cd/m^2$. We observed the highest luminance of $21,000\;Cd/m^2$ at 35V. Due to the high operating voltage, despite of the high peak luminous efficiency the peak power efficiency was found to be 12.2 lm/W at the luminance of $470\;cd/m^2$ (15.9 V).

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The prospects of highly power efficient OLEDs using molecular dopants for display and lighting applications

  • Werner, Ansgar;Blochwitz-Nimoth, Jan;Birnstock, Jan;Wellmann, Philipp;Romainczyk, Tilmann;Lux, Andrea;Limmert, Michael;Zeika, Olaf
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1692-1696
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    • 2006
  • Dopant and host molecules for charge transport layer in OLED have been developed. They enable implementation of the PIN OLED technology in mass production. We review the status of PIN OLED with main focus on top-emission structures and operation stability at elevated temperatures. A green phosphorescent top-emission device with 2.5 V operating voltage and 90 lm/W at 1000 $cd/m^2$ is presented. For a red top-emission device, lifetime exceeding 100,000 h at 500 $cd/m^2$ initial brightness is reported. Operational stability at $80^{\circ}C$ has been investigated. A lifetime of 17,000 h at 500 $cd/m^2$ has been achieved. Finally, we comment on further reduction of the operating voltage in OLED.

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White OLED and Dual-plate OLED Display

  • Han, Chang-Wook;Pieh, Sung-Hoon;Sung, Chang-Jae;Kim, Hwa-Kyung;Pang, Hee-Suk;Choi, Hong-Seok;Lee, Nam-Yang;Ahn, Byung-Chul
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.411-414
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    • 2009
  • We report single and two-stacked WOLED. Two-stacked WOLED structure adopts fluorescent blue EML and phosphorescent (red+green) EML. Current efficiency, EQE and color coordinate of two-stacked WOLED are 54.5cd/A, 28.8% and CIExy (0.322, 0.345), respectively. Those of single WOLED are also 20cd/A, 10% and CIExy (0.29, 0.37), respectively. Dual-plate OLED Display (DOD) employing the single WOLED shows high aperture ratio up to 67% in 2-inch panel of which pixel size is equivalent to that of 32 inch Full HD.

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Treatments of Electron Transport Layer in the Fabrication of High Luminous Green Phosphoresent OLED (고휘도 녹색 인광 OLED 제작에서 전자수송층 처리)

  • Jang, Ji-Geun;Kim, Won-Ki;Shin, Sang-Baie;Shin, Hyun-Kwan
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.3
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    • pp.5-9
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    • 2008
  • New devices with structure of ITO/2TNATA/NPB/TCTA/CBP:7%Ir(ppy)$_3$/BCP/ETL/LiF/Al were proposed to develop high luminous green phosphorescent organic light emitting diodes and their electroluminescent properties were evaluated. The experimental devices were divided into two kinds according to the material ($Alq_3$ or SFC137) used as an electron transport layer (ETL). Luminous intensities of the devices using $Alq_3$ and SFC137 as electron transport layers were 27,500 cd/$m^2$ and 51,500 cd/$m^2$ at an applied voltage of 9V, respectively. The current efficiencies of both devices were similar as 12.6 cd/A under a luminance of 10,000 cd/$m^2$, while showed slower decay in the device with SFC137 as an ETL according to the further increase of luminance. Current density and luminance of the device with SFC137 as an electron transport layer were higher at the same voltage than those of the device with $Alq_3$ as an ETL.

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High-Performance Flexible Organic Light-Emitting Devices using Amorphous Indium Zinc Oxide Anode

  • Kang, Jae-Wook;Jeong, Won-Ik;Kim, Han-Ki;Kim, Do-Geun;Lee, Gun-Hwan;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1425-1428
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    • 2007
  • The amorphous IZO on flexible substrate (PC) shows similar electrical conductivity and optical transmittance with commercial ITO glass even though it was prepared at $<50\;^{\circ}C$. Moreover, it exhibits little resistance change during 5000 bending cycles, demonstrating good mechanical robustness. A green phosphorescent OLED fabricated on amorphous IZO on flexible PC shows maximum external quantum efficiency of ${\eta}_{ext}=13.7\;%$ and power efficiency of ${\eta}_p=32.7\;lm/W$, which are higher than a device fabricated on a commercial ITO on glass (${\eta}_{ext}=12.4%$ and ${\eta}_p=30.1\;lm/W$) and ITO on flexible PC (${\eta}_{ext}=8.5%$ and ${\eta}_p=14.1\;lm/W$).

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A Study on the Highly Efficient Green Organic Light-Emitting Diodes Using Phosphorescent materials (인광물질을 사용한 고효율 녹색 유기 발광 소자에 관한 연구)

  • Jung, Jin-Ha;Shim, Ju-Yong;Kang, Myung-Goo;Oh, Hwan-Sool
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.276-277
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    • 2006
  • 본 연구에서는 인광 발광 물질인 host재료, CBP에 guest로 인광색소인 $Ir(ppy)_3$을 첨가하여 광학적, 전기적 특성을 보았다. $Ir(ppy)_3$ 색소를 서로 다른 중량비로 첨가할 때의 소자들의 특성을 평가하였다.$ Ir(pppy)_3$을 3.125%의 중량비로 하였을 때 가장 좋은 휘도특성을 보였다. 소자의 기본구조는 glass/ITO/${\alpha}-NPD(300{\AA})$/CBP:$Ir(ppy)_3(300{\AA})$/$BCP(80{\AA})$/$Alq_3(200{\AA})$)/$Al(1000{\AA})$로 하였다.

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Novel Bipolar Host Materials for Phosphorescent OLEDs

  • Yu, Eun-Sun;Kim, Nam-Soo;Kim, Young-Hoon;Chae, Mi-Young;Chang, Tu-Won
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.636-639
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    • 2007
  • We have developed novel bipolar host materials, designed to have both electron transporting and hole transporting abilities, which show significant increase in luminance efficiency and decrease in driving voltage of green phosphorescent OLEDs. In case of the best host material, CheilGH-3, the driving voltage was decreased 27 % at a given constant luminance of $1000cd/m^2$. Also the luminance efficiency was enhanced 44 % and the power efficiency was almost doubled compared to the reference device using CBP as a host.

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