• 한국추진공학회지
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• 제19권2호
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• pp.46-54
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• 2015

아산화질소는 친환경적이고 비교적 안전하며 자발가압으로 공급될 수 있어서 다수의 액체로켓엔진 관련 연구기관 및 학교에서 산화제로 사용하고 있다. 그러나 본 연구실에서 에탄올 및 기체 아산화질소 추진제 조합을 이용한 연소시험 중 원인을 알 수 없는 폭발 현상이 다수 발생하였고, 본 논문에서는 분사기 내부에서의 아산화질소 분해 반응, 아산화질소 공급압력을 높이기 위한 탱크 가열에 따른 배관 내 아산화질소 재응축을 폭발현상의 원인으로 지목하고 해결책 및 안전한 아산화질소 산화제 사용방안을 제시하였다.

• 한국추진공학회지
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• 제17권6호
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• pp.97-104
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• 2013

Guanylurea-dinitramide(GUDN)는 낮은 감도와 좋은 성능을 가진 에너지 물질로서 추진제 및 둔감 탄약에 사용할 수 있다. 고에너지 고밀도 화약인 GUDN의 효과적인 합성과 특성분석을 이화학적 분석 및 원소분석을 통하여 수행하였다. Gaussian 09 프로그램을 사용하여 생성열을 계산하였다. 화약의 안전한 취급을 위해서 충격 및 마찰 감도를 BAM 방법으로 측정하였다.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.153-160
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• 2018

An environmentally favorable (chlorine-free) solid oxidizer, guanidinium dinitramide [GDN; $NH_2C(NH_2)NH_2N(NO_2)_2$], was newly synthesized from guanidine carbonate [$NH_2C(=NH)NH_2{\cdot}1/2H_2CO_3$]. Two different crystalline forms (${\alpha}-type$ and ${\beta}-type$) appeared according to the applied solvents and synthesis conditions. Moisture, during extraction, might become trapped in a crystal between inner molecules. Therefore, despite having the same chemical composition, Raman-IR and TGA-DSC revealed different physical characteristics of the two forms. Peaks of Raman shift near $1000cm^{-1}$ implied different chemical structures. Thermal analysis revealed an exothermic temperature $155.7^{\circ}C$ for ${\alpha}-type$ but one of $191.6^{\circ}C$ for ${\beta}-type$. The caloric value of ${\alpha}-type$ was 536.4 J/g, which was 2.5 times larger than that of the ${\beta}-type$, which was 1310 J/g. While the synthesized GDN of ${\alpha}-type$ showed a steep exothermic decomposition, the ${\beta}-type$ was slowly decomposed after melting through an endothermic process. This work implied that despite of the same molecular formula some different core thermal properties would appear depending on synthesis conditions.

• Transactions on Electrical and Electronic Materials
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• 제15권5호
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• pp.249-252
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• 2014

The aim of this work is to investigate the effect of $Ca_xSr_{2-x}$ and activator on the structural and luminescent properties of green-emitting $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ nano phosphor. Using urea as fuel and ammonium nitrate as oxidizer, $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ has been successfully synthesized, using a combustion method. The particles were found to be small, spherical and of round surface. SEM imagery showed that the phosphors particles are of nanosize. The $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ emission spectrum for 360 nm excitation showed a single band, with a peak at 490 nm, which is a green emission. The highest luminous intensity was at $1,000^{\circ}C$, which was obtained when the $Eu^{2+}$ content (y) was 0.05. The results support the application of $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ phosphor as a fluorescent material for ultraviolet light-emitting diodes (UV-LEDs). Characteristics of the synthesized $Ca_xSr_{2-x}SiO_4:Eu^{2+}$ phosphor were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and photoluminescence (PL) detection.

• 공업화학
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• 제27권4호
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• pp.397-401
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• 2016

새로운 고체산화제 화합물인 pyridinium dinitramide (Py-DN)는 환경 및 인체에 독성이 적은 비염소계의 에너지물질로서 고체 추진제 뿐만 아니라 단일계 추진제로 활용이 가능한 high performance green propellant (HPGP) 물질이다. 합성반응은 술팜산칼륨(potassium sulfamate, $NH_2SO_3K$)을 출발물질로 시작하였으며, 합성된 Py-DN의 화학적인 구조특성을 적외선분광법과 가시광선-자외선분광법으로 관찰하였다. 또한, 유사한 물성의 친환경 고체산화제인 ammonium dinitramide[ADN, $NH_4N(NO_2)_2$]와 guanidine dinitramide[GDN, $NH_2C(NH_2)NH_2N(NO_2)_2$]의 열특성을 TG/DSC로 분석하여 상대 비교하였다. 본 연구에서 합성한 Py-DN염의 흡열온도는 $77.4^{\circ}C$, 분해온도는 $144.7^{\circ}C$, 발열에너지는 1739 J/g으로 기존의 DN계열 물질보다 열적 반응이 빠르므로 분해온도가 상대적으로 낮아 단일계 추진제의 촉매 분해 시 촉매의 예열온도를 낮출 수 있어 로켓추력기의 연료로 활용할 경우, 낮은 분해온도 적용성에 장점이 있다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제23권4호
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• pp.42-47
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• 2018

E. coli TG1 pBS TOM Green was cultured to produce toluene-o-monooxygenase (TOM). A biosensor system was successfully constructed using purified TOM to effectively detect trichloroethene (TCE) and tetrachloroethene (PCE), which represent some of the major contaminants in groundwater and soil. In order to utilize TOM as a sensor, NADH, a biological oxidizer, was replaced with hydrogen peroxide which is a chemical oxidizing agent. A three-layered sandwich-type sensing tip was fabricated on the outside of the hydrophilic polyvinylidene fluoride membrane. TCE and PCE were applied to the sensor and the hydrogen ions were measured by a fiber optic fluorometer using fluoresceinamine. Calibration curves were obtained for TCE and PCE in the concentration range of 0.2-100 mg/l, and the detection limit of the system was $10{\mu}g/l$ for TCE and PCE.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.112-117
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• 2001

An experiment using high preheated and swirled air in the coaxial diffusion flame burner was carried out in order to decrease NOx emission and improve the thermal efficiency. $N_2$ gas was used for diluent and propane was utilized for fuel. Combustion using high preheated air has two remarkable characteristics ; (1) low NOx emission with increasing dilution level, (2) high thermal efficiency in the furnace. Also, swirled air can mix fuel and oxidizer well in condition of diffusion flme and maintain the stable combustion. The color of flame changes from yellow to blue green according to increasing the dilution level of mixture gas. NO emission decreased with increasing dilution level and the swirl number.

• 항공우주시스템공학회지
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• 제17권1호
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• pp.51-58
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• 2023

별도의 점화원 없이 스스로 점화가 가능한 접촉점화 추진제는 부식성과 독성으로 인하여 취급의 어려움이 있다. 따라서 독성이 적거나 없는 친환경 접촉점화 추진제의 개발이 필요하며, 본 연구에는 친환경 접촉점화 추진제의 기초 연구를 수행하였다. 산화제로 95%의 과산화수소, 연료로 CNU_HGFv1를 사용하였으며 액적 낙하 시험, 점화 시험 및 연소 시험을 통하여 추진제의 점화 및 연소 특성을 확인하였다. 액적 낙하 시험 결과 점화지연 시간은 9.7ms 이며, 점화시험에서는 약 27ms로 추진제로 사용하기에 충분히 빠른 것을 확인하였다. 연소시험 결과 약 11.7bar에서 연소 효율 95.4~98.1%를 달성하였으며, 하드스타트 및 연소 불안정 없이 빠르고 안정적인 연소가 가능함을 확인하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.93-101
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• 2006

This research makes a new attempt to apply the activated seawater by electrolysis in the development of two-stage wet scrubber system to control the exhaust gas of large marine diesel engines. First, with using only seawater that is naturally alkaline (pH typically around 8.1). the $SO_2\;and\;SO_3$ are absorbed by relatively high solubility compared to other components of exhaust pollutants, and PM (Particulate Matter) is removed through direct contact with sprayed seawater droplets. Besides, the electrolyzed alkaline seawater by electrolysis, which contains mainly NaOH together with alkali metal ions $(i.e.\;Na^+,\;Mg^{2+},\;Ca^{2+})$, is used as the absorption medium of NOx and $CO_2$. Especially, to increase NOx absorption rate into the alkaline seawater. nitric oxide (NO) is adequately oxidized to nitrogen dioxide $(NO_2)$ in the acidic seawater, which means both volume fractions are adjusted to identical proportion. The results found that the strong acidic seawater was a valid oxidizer from NO to $NO_2$ and the strong alkaline seawater was effective in $CO_2$ absorption In the scrubber test, the SOx reduction of nearly $100\%$ could be achieved and also led to a sufficientPM reduction. Hence, the author believes that applying seawater and its electrolyte would bring the marine air pollution control system to an economical measure. Additionally it is well known that NOx and SOx concentration has a considerable influence on the $N_2O$ emission of green house gas. Although the $N_2O$ concentration exhausted from diesel engines is not as high, the green house gas effect is around 300 times greater than an equivalent volume of $CO_2$. Therefore, we investigated the $N_2O$ removal efficiency with using the electrolyzed seawater too. Finally this research would also plan to treat the effluent by applying electro-dialysis and electro-flotation technique s in the future.

• 한국항공우주학회지
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• 제36권5호
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• pp.491-496
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• 2008

본 연구에서는 RBCC (Rocket Based Combined Cycle)엔진이나 기존 램제트 추진기관의 초기 추력 제공에 과산화수소 가스발생기를 이용하는 새로운 추진시스템을 제안하였고, 기초 연구 수행으로서 촉매 분해된 과산화수소 제트에 케로신을 분사하여 자연발화 및 연소 특성을 연구하였다. 과산화수소는 촉매 베드를 통하여 분해된 후 축소노즐을 통해 연소실로 분사됐으며 이 제트에 인젝터를 통하여 수직으로 케로신을 액상으로 분무하였다. 연소실내에서의 온도와 압력을 측정하여 점화를 확인하고 자연발화 특성을 조사하였다. 400°C의 연소실 온도와 연료와 산화제 혼합비 0.6이상에서 자연발화와 안정적인 연소가 가능하였다. 이 결과를 통하여 램제트의 새로운 초기 가속장치의 가능성을 확인할 수 있었다.