• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.1-7
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• 2014

This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.4
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• pp.492-499
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• 2021

In this study, the benthic environmental and microbial community structure were investigated by mixing granulated coal ash(GCA) and contaminated estuary sediments. Estuary sediments and GCA were mixed in a ratio of 8:2 and allowed to interact for 1 month, then sediment environmental factors were investigated. The pH of the experimental sediment was mixed increased to 11. The concentration of DIP(Dissolved inorganic phosphorus) in the experimental case decreased by 30 % compared to the control case, and this should be due to formation of calcium phosphate through the chemical reaction of DIP and calcium which diluted from GCA. The high abundance of Gammaproteobacteria seen in the experimental sediment compare to the control can af ect the DIP reduction. The DIN(Dissolved inorganic nitrogen) concentration increased over two times in the experimental case than the control, and this should be due to the high pH condition and release of NH₄⁺-N from the GCA. Microorganisms related to nitrogen circulation were not identified in both the control and experimental cases. It was confirmed that the GCA were effective in reducing the DIP concentration in contaminated estuary sediment, and that benthic microbial communities were shown to influenced the phosphorus circulation.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2011.11a
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• pp.31-32
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• 2011

Granulated slag from metal industries and fly ash from the combustion of coal are industrial by-products that have been widely used as mineral admixtures in normal and high strength concrete. Due to the reaction between calcium hydroxide and fly ash or slag, the hydration of concrete containing fly ash or slag is much more complex compared with that of Portland cement. In this paper, the production of calcium hydroxide in cement hydration and its consumption in the reaction of mineral admixtures is considered in order to develop a numerical model that simulates the hydration of concrete containing fly ash or slag. The heat evolution rates of fly ash- or slag-blended concrete is determined by the contribution of both cement hydration and the reaction of the mineral admixtures. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

• Advances in concrete construction
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• v.12 no.6
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• pp.499-505
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• 2021

Geopolymer binders fascinate the attention of researchers as a replacement to cement binder in conventional concrete. One-ton production of cement releases one ton of carbon-dioxide in the atmosphere. In the replacement of cement by geopolymer material, there are two advantages: one is the reduction of CO₂ in the atmosphere, second is the utilization of Fly ash and Ground granulated blast furnace slag (GGBFS) are by-products from coal and steel industries. This paper focuses on the mechanical properties of steel fiber reinforced geopolymer concrete. The framework considered in this research work is geopolymer source (Fly ash, GGBFS and crimped steel fibre) and alkaline activator which consists of NaOH and Na₂SiO₃ of molarity 8M. Here the Na₂SiO₃ / NaOH ratio was taken as 2.5. The variables considered in this experimental work include Binder content (360,420 and 450 kg/m³), the proportion of Fly ash and GGBS (70-30, 60-40 and 50-50) for three different grades of Geopolymer concrete (GPC) GPC 20, GPC 40 and GPC 60. The percentage of crimped steel fibres was varied as 0.1%, 0.2%, 0.3%, 0.4% and 0.5%. Generally, the inclusion of steel fibres increases the flexural and split tensile strength of Geopolymer concrete. The optimum dosage of steel fibres was found to be 0.4% (by volume fraction).

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.914-919
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• 2019

A mesocosm experiment considering water exchange was conducted to evaluate the change in the properties of contaminated coastal sediment. The contaminated coastal sediment sample was prepared by mixing with granulated coal ash(GCA), which is an alkaline industrial by-product. During one month of observation time, the phosphate concentration of the GCA sample case was measured to be 19.0 and 0.4 mg/L lower than that of the control sample at the pore water and overlying water, respectively. The hydrogen sulfide concentration of the GCA sample case was 5.0 mg/L, which is significantly lower than that of the control sample(112.5 mg/L). Further addition of GCA in the sediment reduced the concentrations of phosphate and hydrogen sulfide, and could enhance the adsorption reaction, when compared to the sediment without GCA. The dissolved oxygen concentration in the overlying water of the GCA sample was measured to be 3.47 mg/L higher than the control sample. From the above results, we confirmed that GCA is an effective material for reducing pollutants in coastal sediment.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.2
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• pp.95-106
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• 1998

To reduce the environmental contamination and to utilize fly ash massively produced from the coal power plant every year, we synthesized the artificial zeolite using fly ash treated with alkaline, and then analyzed the mineralogical and morphological properties by X-ray, IR, and SEM. The amount of $NH_4{^+}$, $K^+$, and $H_2PO_4{^-}$ adsorbed by the fly ash and the artificial zeolite were determined with reaction time, amount of adsorbate used, ion concentrations. The results obtained from the pot experiments packed with the top soil, amended with granulated artificial zeolite which was made by treatment of 4% polyvinylalcohol, showed that CEC of the artificial zeolite was $257.7cmol^+kg^{-1}$, that was almost 36 times greater than that of fly ash. The ratio of $SiO_2/Al_2O_3$ decreased but the amount of Na increased. The physico-chemical properties analyzed by X-ray, IT, and SEM represented that the artificial zeolite synthesized had a similar morphological structure to that of the natural zeolite. The structures of the artificial zeolite had a significantly enlarged surface having a lot of pores, while the fly ash looked like spherical smooth shape with having not pores on the surface. Thus, the artificial zeolite was successfully synthesized. The results of adsorption isotherms of fly ash and artificial zeolite showed that the amount of $NH_4{^+}$, $K^+$, and $H_2PO_4{^-}$ adsorbed increased as the equilibrium concentration increased, while $NH_4{^+}$ was strongly adsorbed on the surface of fly ash and artificial zeolite than that of $K^+$. The most distinctive growth of Chinese cabbage was found from the top soil(NPK + soils + 20% of granulated artificial zeolite + 5% of compost). Therefore, we concluded that one of the most effective methods to effectively recycle a fly ash was to make the artificial zeolite as we did in this experiment.

• Resources Recycling
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• v.27 no.3
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• pp.39-47
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• 2018

According to Vietnam government establishes additional coal-fired power plants to secure generation capacity, emission of ashes is accelerating and processing them is urgent issue. This study targeted utilize fly ashes that occurred in circulating fluidized bed combusion (CFBC) power plant to use ground solidification materials. CFBC fly ashes are used to make solidification with ground granulated blast furnace slag (GGBFS), gypsum and cement. Then produced specimens by mixing with soft ground soil to confirm mixing effect of fly ash in solidification. As a result it was possible to find mixture design that is satisfied 3 MPa compressive strength in age 28 days and reduce weight loss rate over 50% in acid immersion test than plain specimens that using only ordinary portland cement.