• Title/Summary/Keyword: grain-connectivity

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A Study on Unsaturated Zone Characterization and Feasibility of Soil Vapor Extraction at a DNAPL-contaminated Site in Korea

  • Lee, Man Na Mi;Yeo, In Wook
    • Journal of Soil and Groundwater Environment
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    • v.18 no.6
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    • pp.48-55
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    • 2013
  • This study aimed at characterizing unsaturated zone at the source zone area contaminated by DNAPL and investigating feasibility of soil vapor extraction (SVE). Five boreholes with three multi-level screens at the depth of 3.0~4.5 m, 5.5~7.0 m, and 8.0~12.0 m were installed at the source zone. Pneumatic tests were performed to determine the permeability of porous medium. Permeability was estimated to be 81.6 to 203.7 darcy, depending on the applied solutions, which was contradicted by grain size analysis of cored soil samples leading to 3.51 darcy. This is due to air flow through gravel pack during the early stage of pneumatic test. Pressure-drawdown curve in the late stage also well showed the leaky aquifer type, indicating air leakage to the ground. Air flow tests were also carried out to investigate air flow connectivity between multi-level wells, indicating that the horizontal air flow was well developed between the lower screens of the wells, not between the upper and middle screens due to the leakage to the surface. For the SVE test, there was no noticeable variation in TCE vapor concentration between three different test runs: 1. 8 hours daily for 5 days, 2. 24 hours together with air blowing at another well (BH1), 3. five consecutive days. Even for five-day consecutive test, total amount of removed TCE was estimated only to be as low as 46.5 g.

The Effect of Stacking Fault on Thermoelectric Property for n-type SiC Semiconductor (N형 SiC 반도체의 열전 물성에 미치는 적층 결함의 영향)

  • Pai, Chul-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.13-19
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    • 2021
  • This study examined the effects of stacking faults on the thermoelectric properties for n-type SiC semiconductors. Porous SiC semiconductors with 30~42 % porosity were fabricated by the heat treatment of pressed ��-SiC powder compacts at 1600~2100 ℃ for 20~120 min in an N2 atmosphere. XRD was performed to examine the stacking faults, lattice strain, and precise lattice parameters of the specimens. The porosity and surface area were analyzed, and SEM, TEM, and HRTEM were carried out to examine the microstructure. The electrical conductivity and the Seebeck coefficient were measured at 550~900 ℃ in an Ar atmosphere. The electrical conductivity increased with increasing heat treatment temperature and time, which might be due to an increase in carrier concentration and improvement in grain-to-grain connectivity. The Seebeck coefficients were negative due to nitrogen behaving as a donor, and their absolute values also increased with increasing heat treatment temperature and time. This might be due to a decrease in stacking fault density, i.e., a decrease in stacking fault density accompanied by grain growth and crystallite growth must have increased the phonon mean free path, enhancing the phonon-drag effect, leading to a larger Seebeck coefficient.

The Effect of Particle Size and Additives on the Thermoelectric Properties of P-type FeSi2 (P형 FeSi2의 열전물성에 미치는 입자크기 및 첨가물 영향)

  • Pai, Chul-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.4
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    • pp.1883-1889
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    • 2013
  • Although Fe-Si based alloy has lower figure of merit than Si-Ge alloy applied for space probe, its low cost related to abundant raw material, rather simple processing, high temperature resistance and reliability up to $800^{\circ}C$ made it one of the most promising middle temperature thermoelectric generation materials. The effect of particle size and additive on the thermoelectric properties of p-$FeSi_2$ prepared by a RF inductive furnace was investigated. The electrical conductivity increased slightly with decreasing particle size and hence better grain-to-grain connectivity due to the increase of density. The Seebeck coefficient exhibited the maximum value at about 600~800K and decreased slightly with increasing particle size. This must be due to the amount of residual metallic phase ${\varepsilon}$-FeSi. $Fe_2O_3$ and/or $Fe_3O_4$-doped specimens showed the higher electrical conductivity and the lower Seebeck coefficient due to increase of the metallic phase and Si-vacancy. On the other hand, $SiO_2$-doped specimen showed the higher electrical conductivity and the higher Seebeck coefficients.

Fabrication of high-$J_c$ $YBa_2Cu_3O_{7-{\delta}}$ thin films on (100) $SrTiO_3$ single crystal substrates by a modified TFA-MOD method (수정된 TFA-MOD법에 의한 (100) $SrTiO_3$ 단결정 기판 위 고 임계전류 밀도 $YBa_2Cu_3O_{7-{\delta}}$ 박막 제조)

  • Wee, Sung-Hun;Shin, Keo-Myung;Song, Kyu-Jung;Hong, Gye-Won;Moon, Seung-Hyun;Park, Chan;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.6 no.1
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    • pp.12-17
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    • 2004
  • High critical current density. $J_c$ over $1MA/cm^2$ at 77 K in a self field was successfully achieved from the YBCO film prepared on (100) $SrTiO_3$ single-crystal substrates by the TFA-MOD process. Unlike a normal TFA-MOD process, we prepared the TFA precursor solution by dissolving YBCO powder into the trifluoroacetic acid. A significant amount of the second phases, including $BaF_2$, was observed in the films fired at $700-725^{\circ}C$ for 2 h under $P(O_2)=10^{-3}$ atm and $P(H_2O)=4.2%$, most probably due to an insufficient reaction time, and hence $T_c$ was greatly degraded. However the films fired at $750-800^{\circ}C$ for 2 h were composed of strongly c-axis oriented YBCO grams without any second phases. and exhibited the $T_c$ values of 89.5 ~ 91 K with a sharp transition. With increasing the firing temperature from 750 to $800^{\circ}C$ average grain size of YBCO was increased and grain connectivity was enhanced. The highest $J_c$ value of $1.1MA/cm^2$ was obtained from the YBCO film fired at $800^{\circ}C$.

The Theoretical and Experimental Value on the Stress-Strain Behavior of Dual Phase Steels (복합조직강의 응력-변형 거동에 관한 이론치와 실험치)

  • 오택열;김석환;유용석
    • Journal of the Korean institute of surface engineering
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    • v.26 no.2
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    • pp.63-70
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    • 1993
  • The mechanical properties of ferrite-martensited dual phases steels are affected by the microstructural factors, such as martensited volume fractions, ferrite grain size, strength ratio, connectivity, etc. Two phase alloys are technologically important. However, there is a lack of understanding as to stress-strain behavior of dual phase alloy in terms of stress-strain behavior of each component phases. The lack of the understanding stems from the complex deformation behavior of two phase alloys. The aim of this study is to rationalize stress-strain behavior of dual phase alloy in terms of the stress-strain behavior of component phase by systematically considering all the factors listed above. It was found that for a given martensite volume fraction, the calculated stress-strain curve was higher for a finer particles size than for a coarse particle sized within the range of the strains considered, and this behavior was seen for all the different volume fraction alloys considered. The calculated stress-strain curves were compared with corresponding experimental curves, and in general, good agreement was found. The maximum difference in flow stress between the calculated and the experimental results occurs at the nearly beginning of the plastic deformation.

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Effect of Mg content on the density and critical properties of in-situ reacted MgB2 bulk superconductor

  • Jun, Byung-Hyuk;Kim, Dan-Bi;Park, Soon-Dong;Kim, Chan-Joong
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.19-22
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    • 2014
  • The effects of Mg content on the pore formation, density and critical properties were investigated in in-situ reacted $MgB_2$ superconductors. The $Mg_{1+x}B_2$, (x=-0.2, 0.0, 0.05, 0.3, 1.0) bulk samples with different Mg contents were heat-treated at $900^{\circ}C$ for 1 h in an Ar atmosphere. The dimensional changes of a pellet's mass and volume after heat-treatment were measured. After heat-treatment process, the sample mass was decreased by Mg evaporation, but the sample volume was expanded by pore formation at the Mg site; therefore, the apparent density was decreased. Spherical pores the same as Mg particles were developed after heat-treatment in all samples, and the pore density was increased with increasing Mg content. As the x of Mg content was increased to 1.0, the apparent density of $Mg_{1+x}B_2$ samples was decreased due to a relatively larger reduction in a mass change. The critical current density of Mg excessive sample of x=0.05 showed the highest values over the applied magnetic fields because the excessive Mg may compensate Mg loss and enhance grain connectivity.

Fabrication of $MgB_2$ tape with metal powder addition (금속분말이 첨가된 $MgB_2$ 선재의 제조 및 특성)

  • Ko, Jae-Woong;Yoo, Jai-Moo;Kim, Young-Kuk;Chung, Kook-Chae;Yoo, Sang-Im;Wang, Xio Lin;Dou, Shi Xue
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.1
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    • pp.1-4
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    • 2006
  • The $MgB_2$ tapes with several metal powder addition were fabricated by PIT method with or without heat treatment. The $J_c$ value of $5.600A/cm^2$ and $16.000A/cm^2$ at 4.2 K and 5 T were obtained for the $MgB_2$ tape and 10 vol % of Cu added $MgB_2$ tape without heat treatment respectively. The $J_c$ value of $8.000A/cm^2$ and $35,000A/cm^2$ at 4.2 K and 5 T were obtained for the $MgB_2$ tape and 10 vol. % of Al added $MgB_2$ tape with heat treatment, respectively. The $J_c-B$ curve shows enhancement in $J_c$ under magnetic field. which suggests enhancement in workability and grain connectivity with several metal powder addition.

Thermoelectric properties of SiC prepared by refined diatomite (정제 규조토로 합성한 탄화규소의 열전특성)

  • Pai, Chul-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.596-601
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    • 2020
  • Silicon carbide is considered a potentially useful material for high-temperature electronic devices because of its large band gap energy and p-type or n-type conduction that can be controlled by impurity doping. Accordingly, the thermoelectric properties of -SiC powder prepared by refined diatomite were investigated for high value-added applications of natural diatomite. -SiC powder was synthesized by a carbothermal reduction of the SiO2 in refined diatomite using carbon black. An acid-treatment process was then performed to eliminate the remaining impurities (Fe, Ca, etc.). n-Type semiconductors were fabricated by sintering the pressed powder at 2000℃ for 1~5h in an N2 atmosphere. The electrical conductivity increased with increasing sintering time, which might be due to an increase in carrier concentration and improvement in grain-to-grain connectivity. The carrier compensation effect caused by the remaining acceptor impurities (Al, etc.) in the obtained -SiC had a deleterious influence on the electrical conductivity. The absolute value of the Seebeck coefficient increased with increasing sintering time, which might be due to a decrease in the stacking fault density accompanied by grain or crystallite growth. On the other hand, the power factor, which reflects the thermoelectric conversion efficiency of the present work, was slightly lower than that of the porous SiC semiconductors fabricated by conventional high-purity -SiC powder, it can be stated that the thermoelectric properties could be improved further by precise control of an acid-treatment process.

Analysis of Scale Sensitivity of Landscape Indices for the Assessment of Urban Green Areas (도시녹지 평가를 위한 경관지수의 스케일 민감성 분석)

  • Lee, In-Sung;Yoon, Eun-Joo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.36 no.2
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    • pp.69-79
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    • 2008
  • Landscape indices are effective tools to explain the spatial structure and patterns of ecological landscape including area/density, shape, core area, isolation/proximity, contagion/interspersion, and connectivity. More than 100 indices have been developed and an increasing amount of research explains changes in urban spaces using the indices. However, landscape indices have a high level of sensitivity to the scale of analysis - grain size and extent. If the scale sensitivity of indices is not considered, the research may produce inaccurate results. This study examines the scale sensitivity of landscape indices to find relatively stable indices in the complex geographical features of Korea. The scale sensitivity was analyzed using 20 categories of grain size and 41 categories of extent change. Landsat TM and ETM+ images of five years - 1985, 1991, 1996, 2000 and 2003 - were used, and 54 class level indices mounted on the FRAGSTATS program were examined. The results are as follows: First, according to the analysis of the scale sensitivity, 19 out of 54 class level indices were found to be stable to scale change. Second, the scale sensitivity was closely related to the green area ratio, and the typical threshold of change was $40{\sim}50%$. Third, among the 16 indices which were frequently used in the research in Korea, only 6 indices were relatively stable to the scale change. These results can be an effective basis for the selection of indices in the landscape ecology research in Korea.

The use of JIP test to evaluate drought-tolerance of transgenic rice overexpressing OsNAC10

  • Redillas, Mark C.F.R.;Strasser, Reto J.;Jeong, Jin-Seo;Kim, Youn-Shic;Kim, Ju-Kon
    • Plant Biotechnology Reports
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    • v.5 no.2
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    • pp.169-175
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    • 2011
  • In this study, the JIP test was exploited to assess drought-tolerance of transgenic rice overexpressing OsNAC10. Two types of promoters, RCc3 (root-specific) and GOS2 (constitutive), were used to drive the transcription factor OsNAC10, a gene involved in diverse functions including stress responses. Three-month-old plants were exposed to drought for 1 week and their fluorescence kinetics was evaluated. Our results showed that drought-treated non-transgenic plants (NT) have higher fluorescence intensity at the J phase (2 ms) compared to transgenic plants, indicating a decline in electron transport beyond the reduced plastoquinone ($Q_A^-$). As manifested by negative L bands, transgenic plants also showed higher energetic connectivity and stability over NT plants under drought conditions. Also, the pool size of the end electron acceptor at the photosystem I was reduced more in NT than in transgenic plants under drought conditions. Furthermore, the transgenic plants had higher $PI_{total}$, a combined parameter that reflects all the driving forces considered in JIP test, than NT plants under drought conditions. In particular, the $PI_{total}$ of the RCc3:OsNAC10 plants was higher than that of NT plants, which was in good agreement with their differences in grain yield. Thus, the JIP test proved to be practical for evaluating drought-tolerance of transgenic plants.