• Title/Summary/Keyword: grain composition

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Regulation of Fat and Fatty Acid Composition in Beef Cattle

  • Smith, Stephen B.;Gill, Clare A.;Lunt, David K.;Brooks, Matthew A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.9
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    • pp.1225-1233
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    • 2009
  • Fat composition of beef, taken here to mean marbling, can be manipulated by time on feed, finishing diet, and breed type. These three factors also strongly influence the fatty acid composition of beef. Both the amount of marbling and the concentration of monounsaturated fatty acids (MUFA) increase with time on feed in grain-fed and pasture-fed cattle, but much more dramatically in grain-fed cattle. High-concentrate diets stimulate the activity of adipose tissue stearoyl-CoA desaturase (SCD), which is responsible for the conversion of saturated fatty acids (SFA) to their $\Delta{9}$ desaturated counterparts. Also, grain feeding causes a depression in ruminal pH, which decreases those populations of ruminal microorganisms responsible for the isomerization and hydrogenation of polyunsaturated fatty acids (PUFA). The net result of elevated SCD activity in marbling adipose tissue and depressed ruminal isomerization/hydrogenation of dietary PUFA is a large increase in MUFA in beef over time. Conversely, pasture depresses both the accumulation of marbling and SCD activity, so that even though pasture feeding increases the relative concentration of PUFA in beef, it also increases SFA at the expense of MUFA. Wagyu and Hanwoo cattle accumulate large amounts of marbling and MUFA, and Wagyu cattle appear to be less sensitive to the effects of pastures in depressing overall rates of adipogenesis and the synthesis of MUFA in adipose tissues. There are small differences in fatty acid composition of beef from Bos indicus and Bos taurus cattle, but diet and time on feed are much more important determinants of beef fat content and fatty acid composition than breed type.

Fracture Behavior and Degradation of Piezoelectric Properties in PZT (PZT의 파괴거동 및 압전 열화특성)

  • 태원필;김송희;조상희
    • Journal of the Korean Ceramic Society
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    • v.29 no.10
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    • pp.806-814
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    • 1992
  • The aim of this study was to investigate the change in compressive strength, freacture behavior and degradation of piezoelectric properties with compressive cyclic loading in Pb(Zr, Ti)O3 of tetragonal, morphotropic phase boundary and rhombohedral composition. The highest compressive strength was found in rhombohedral composition. After poling treatment the strength increased by 8.4% and 6.5% in tetragonal and morphotropic phase boundary compositions respectively while changed little in rhombohedral. The increase of compressive strength after poling treatment is believed to be due to the internal stress around grain boundary by domain alginment toward electric field direction in the microstructures having tetragonality and the occurrence of domain switching to the direction perpendicular to electrical field during fracture. Fracture mode relatively change from transgranular to intergranular was observed in the large grain sized tetragonal and morphotropic phase boundary compositions before and after poling but the transgranular fracture mode always remained in the rhombohedral composition. From the X-ray diffractometer analysis the domains parallel to the electric field direction is known to undergo rearrangement during the cyclic loading into random direction that is responsible for the degradation of piezoelectric property.

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A Study of Structure & Composition Characteristics of the(Ti, Al) N Coating on the STS 304 by D.C. Magnetron Sputtering (D.C. Magnetron Sputter를 이용한 (Ti, Al) N 피막의 조성 및 조직특성연구)

  • 최장현;이상래
    • Journal of the Korean institute of surface engineering
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    • v.25 no.5
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    • pp.223-233
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    • 1992
  • (Ti, Al)N films were deposited on 304 stainless steel by D.C. magnetron sputtering using Al target and Ti plate. The properties of (Ti, Al)N films such as composition, microhardness, grain size, crystal structure were investigated. The chemical composition of (Ti, Al)N films was similar to the sputter area ratio of titanium to aluminum target by means of EDS and AES survey. The higher bias voltage to substrate and the smaller input of N2 gas showedthe increased microhardness and the finer grain size of the films. The results obtained from this study show, it is belived, that the (Ti, Al)N film by D.C.magne-tron sputtering is promising in the wear resistance use.

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A study on the Poly-$Si_{1-x}Ge_x$ thin film deposition(II) Variation of surface roughness, grain size and electrical property with deposition parameters (다결정 $Si_{1-x}Ge_x$박막 증착에 관한 연구(II) 증착변수에 따른 표면거칠기, 결정립크기 및 전기적성질 변화)

  • 이승호;어경훈;소명기
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.64-72
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    • 1998
  • In this work, we have investigated the change of surface roughness, grain size and crystallinity of Poly-$Si_{1-x}Ge_x$ films deposited with the variation of deposition parameters (temperature, pressure, Ge composition ) and the effect of these results on the electrical resistivity. The crystallinity and the grain size were increased with increasing deposition temperature and Ge composition. Also, the electrical resistivity was decreased by enhanced grain size, while the surface roughness was increased. With increasing deposition pressure, the crystallinity was increased, but the grain size and the cluster size were decreased, by which the surface roughness was decreased. And the electrical resistivity was increased. Based on the effect of the crystallinity and the grain size on the electrical resistivity, it was founded that the electrical resistivity was depend on the grain size rather than the crystallinity.

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Analysis of Toughening Mechanism of Ceramic Composites by Acoustic Emission (AE(Acoustic Emission)에 의한 세라믹 복합재료의 고인성화 기구 분석)

  • 장병국
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1129-1138
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    • 1997
  • Al2O3/20 vol%YAG composite containing equiaxed grains and Al2O3/20 vol%LaAl11O18 composite containing elongated grains were fabricated using Al2O3-Y2O3 composition and Al2O3-La2O3 composition, respectively, by hot-pressing. In order to investigate the influence of microstructural control of second phase on toughening effect of toughened ceramic composites, AE (acoustic emission) measurements have been coupled with fracture toughness experiments(SENB and SEPB method). A separation of the fracture toughness and analysis of toughening mechanism was possible using the AE technique. The fracture toughness of hot-pressed materials was estimated to be 3.2 MPam0.5 for monolithic alumina, 4.7 MPam0.5 for Al2O3/20 vol%YAG composite and 6.2 MPam0.5 for Al2O3/20 vol%LaAl11O18 composite. In monolithic Al2O3, toughening does not occur as a result of either microcracking or grain bridging, whereas, composites exhibit toughening effects by both microcracking in the frontal zone and gain bridging in the wake zone, resulting in an improvement of fracture toughness as compared with monolithic Al2O3. The fracture toughness of Al2O3/20 vol%LaAl11O18 composite is higher than that of Al2O3/20 vol%YAG composite. It may be attributed to the elongated microstructure of Al2O3/20 vol%LaAl11O18 composite, resulting relatively greater bridging effect.

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Inference Models for Tidal Flat Elevation and Sediment Grain Size: A Preliminary Approach on Tidal Flat Macrobenthic Community

  • Yoo, Jae-Won;Hwang, In-Seo;Hong, Jae-Sang
    • Ocean Science Journal
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    • v.42 no.2
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    • pp.69-79
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    • 2007
  • A vertical transect with 4 km length was established for the macrofaunal survey on the Chokchon macrotidal flat in Kyeonggi Bay, Incheon, Korea, 1994. Tidal elevation (m) and sediment mean grain size $(\phi)$ were inversely predicted by the transfer functions from the faunal assemblages. Three methods: weighted average using optimum value (WA), tolerance weighted version of the weighted average (WAT) and maximum likelihood calibration (MLC) were employed. Estimates of tidal elevation and mean grain size obtained by using the three different methods showed positively corresponding trends with the observations. The estimates of MLC were found to have the minimum value of sum of squares due to errors (SSE). When applied to the previous data $(1990\sim1992)$, each of three inference models exhibited high predictive power. This result implied there are visible relationships between species composition and faunas' critical environmental factors. Although a potential significance of the two major abiotic factors was re-affirmed, a weak tendency of biological interaction was detected from faunal distribution patterns across the flat. In comparison to the spatial and temporal patterns of the estimates, it was suggested that sediment characteristics were the primary factors regulating the distribution of macrofaunal assemblages, rather than tidal elevation, and the species composition may be sensitively determined by minute changes in substratum properties on a tidal flat.

Directional Effect of Applied Pressure during the Sintering on the Microstructures and Fracture Toughness of Heat-treated Silicon Nitride Ceramics (소결시의 가압방식이 열처리 후 질화규소의 미세조직과 파괴인성에 미치는 영향)

  • 이상훈;박희동;이재도
    • Journal of the Korean Ceramic Society
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    • v.32 no.6
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    • pp.653-658
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    • 1995
  • Directional effect of applied pressure during sintering on the microstructure and fracture toughness of the heat-treated silicon nitride ceramics has been investigated. The specimens with a composition of 92Si3N4-8Y2O3(in wt%) were sintered at 172$0^{\circ}C$ by a hot press (HP ) and a hot isostatic press (HIP) and heat-treated for grain growth at 1800~20$0^{\circ}C$. The fracture toughness of the HP samples increased with the grain size while the fracture toughness of the HIP treated samples remained the same even though the grain growth occurred. This discrepancy was explained by a bimodal grain size distribution and large aspect ratio of the HPed samples and a monomodal grain size distributjion and samll aspect ratio of the HIP treated samples.

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Effect of Impurities in Grain Boundary Phases on Wear Behavior of $Si_3N_4$ (질화규소의 입계상에 존재하는 불순물이 마모에 미치는 영향)

  • 오윤석;임대순;이경호
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.277-284
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    • 1996
  • The water test results indicated that the impurities had detrimetal effect on the wear resistance of silicon nitride and the effects were getting severe as the temperature increased. Especially when Ca existed as an impurity the detrimental effects was the most severe. These results were resulted from the fact that impurities lowered the mechanical properties of the grain boundary phase of silicon nitride. The wear test results of glass/glass-ceramic specimens having a similar composition to the grain boundary phase of silicon nitride revea-led that the specimen containing CaO showed the lowest wear resistance. The existence of Fe and Ca at the grain boundary phase assisted forming a grain boundary phase with relatively low refractoriness. Therefore at a given wear condition the removal of deformed layer would be easier. The results showed that the glass phases could be modified by heat-treatment and this modification improved tribological characteristics of the silicon nitride.

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Effect of Material Degradation and Austenite Grain Coarsening on the Creep life Prediction in 3.5 Ni-Cr-Mo-V Steel (3.5Ni-Cr-Mo-V 강의 크리프 수명예측에 재질열화 및 오스테나이트 결정립 조대화가 미치는 영향)

  • 홍성호;조현춘
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.11
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    • pp.2837-2845
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    • 1994
  • Several methods have been developed to predict on the remaining life of the old power plants. However, Larson-Miller parameter, one of existing creep life prediction methods, has not reflected the effect of material degradatioin and grain size. So this study has been carried out to research the effects of material degradation and austenite grain coarsening on the life prediction of 3.5Ni-Cr-Mo-V steel. An experimental result shows that carbide coarsening has no significant effects on the creep rupture life and the Larson-Miller parameter, but grain coarsening has an important influence on the creep ruptrure life and the Larson-Miller parameter. Therefore Larson-Miller constant, K should be determined to consider on the chemical composition and the grain size of materials.

Effects of Yttria and Calcia Co-Doping on the Electrical Conductivity of Zirconia Ceramics

  • Lee, Jong-Sook;Shin, Dong-Kyu;Choi, Byung-Yun;Jeon, Jung-Kwang;Jin, Sung-Hwan;Jung, Kwon-Hee;An, Pyung-An;Song, Sun-Ju
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.655-659
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    • 2007
  • Zirconia polycrystals co-doped with x mol% CaO and (10-x) mol% $Y_2O_3$ were prepared by solid state reaction method. The compositions were chosen for nominally the same oxygen vacancy concentration of 5 mol%. X-ray diffraction patterns indicated the formation of cubic zirconia by heat treatment at $1600^{\circ}C$. Impedance spectroscopy was applied to deconvolute the bulk and grain boundary response. Electrical conductivity was measured using the complex impedance technique from 516 to 874 K in air. Maximum conductivity was exhibited by the composition with equal amounts of CaO and $Y_2O_3$, which may be ascribed to the smaller degree of defect-interactions in that composition due to the competition of different ordering schemes between the two systems. When compared to the composition containing $Y_2O_3$ only, co-doping of CaO increases the grain boundary resistance considerably. The activation energy of grain and grain boundary conductivity was 1.1 eV and 1.2 eV, respectively, with no appreciable dependence on dopant compositions.