• 한국재료학회지
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• 제10권9호
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• pp.612-618
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• 2000

WC-Co와 WC-Co 초경합금중 WC/WC 입계의 구조와 입계 편석상태를 알아볼 목적으로 HRTEM과 EDS를 이용하여 연구하였다. 일부의 입계들은 액상에 의하여 분리된 상태로 관찰되었으나, 상당수는 원자적 상태의 연소계면이었다. 또 연속계면 중 WC-Co 합금에서는 Co 상이 편석되어 있었으며, WC-VC-Co 합금에서는 Co와 V이 동시에 편석되어 있음을 알 수 있었다. 그 편석의 폭은 약6nm이었다. 연속 계면 중 V의 편석은 소결 또는 열처리 시에 일어나는 입계 이동을 억제하는 데 효과적인 역할을 할 것으로 여겨졌다. 동시에 이것은 WC-Co 초경합금에서 VC 첨가에 의한 입성상 억제기구를 설명할 수 있는 것으로 사료되었다.

• Corrosion Science and Technology
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• 제14권6호
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• pp.313-324
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• 2015

Austenitic stainless steels have been widely used in many engineering fields because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion, stress corrosion cracking, pitting, etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled using methods such as lowering the carbon content, solution heat treatment, alloying of stabilization elements, and grain boundary engineering. This work focused on the effects of aging and UNSM (Ultrasonic Nano-crystal Surface Modification) on the intergranular corrosion of commercial 316L stainless steel and the results are discussed on the basis of the sensitization by chromium carbide formation and carbon segregation, residual stress, grain refinement, and grain boundary engineering.

• 한국세라믹학회지
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• 제39권9호
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• pp.818-821
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• 2002

The grain boundary resistivity of a 1-mol%-$Al_2O_3$-dopedd CaO-Stabilized Zirconia(CSZ) specimen was determined by impedance spectroscopy using sub-millimeter-scale electrodes. At the initial stage of sintering, the grain-boundary resistivity of the specimen interior was observed to be higher than that of the surface. However, upon further sintering the boundary resistivity of the specimen interior became lower than that of the surface. The results were explained in terms of a redistribution of the intergranular liquid phase. The liquid phase was predicted to initially coagulate at the interior of the specimen then spread outward during sintering.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2008년도 High Temperature Superconductivity Vol.XVIII
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• pp.39-39
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• 2008

• 한국세라믹학회지
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• 제36권4호
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• pp.354-359
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• 1999

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1998년도 춘계학술대회논문집
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• pp.65-71
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• 1998

The superplastic deformation behaviors of 7075Al alloy have been characterized experimentally and analyzed by the internal variable theory of inelastic deformation. A simple rheological model including the grain boundary sliding has been used to interpret the superplastic deformation behaviors. A series of load relaxation and tensile tests have been carried out for 7075Al alloy at the various temperatures. The superplastic deformation of 7075Al alloy is confirmed to consist of the grain boundary sliding and accommodating grain matrix defprmation.

• 한국세라믹학회지
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• 제25권4호
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• pp.390-398
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• 1988

Effects of atmospheres and adidtives on the grain growth of TiO2 ceramics were investigated. In the range of 1300~140$0^{\circ}C$, grain growth was increased in CO2 as compared with O2 atmosphere and the grain boundary migration activation energy was lower than the diffusion activation energy of oxygen ion in TiO2. Also, in the case of addition of oxides, the grain growth was increased by oxides acting as a acceptor andinhibited by oxides acting as a donor. From the above results, when the oxygen vacancy concentration was increased, the intrinsic grain boundary mobility was increased and the pore drag force was decreased due to the rapid densification. Also it seems that the pore was migrated by the surface diffusion rather than lattice diffusion.

• Journal of Magnetics
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• 제8권4호
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• pp.157-159
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• 2003

The strengths of the inter-grain exchange interaction were evaluated for nanocrystalline $Nd_{2.33}Fe_{14}B_{1.06}Si_{0.21}$ magnets of different grain size by comparing the $_{i}H_{c}$ calculated by micromagnetics with the experiments. With increase of the grain boundary thickness to that of the magnet of grain diameter 12.4, 24.8, 37.2 and 49.6 nm, the strengh of the interaction in reference to that without the grain boundary phase decreases to 83％, 69％, 54％ and 42％.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.348-349
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• 2006

The plastic deformation behavior of cemented carbides is related to the WC grain boundary strength. Ab initio calculations predict that Co and Mn segregate to WC/WC grain boundaries. To experimentally study the effect of Mn, a WC-Co-Mn material was manufactured and compared to a WC-Co material. The microstructure was studied using scanning electron microscopy (SEM), including electron backscatter diffraction (EBSD). Special attention was paid to the WC grain size and the frequency of special low-energy grain boundaries. Mn was found to have negligible effect on both the WC grain growth and the fraction of $\sum2$ WC/WC boundaries in the as-sintered material.

• 한국표면공학회지
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• 제47권6호
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• pp.303-310
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• 2014

In this study, the average in-situ stress in metallic thin film was measured during deposition of the Cu thin films on the Si(111) wafer and then the phenomenon of stress shift by the interruption of deposition was measured using Cu thin films. We have observed the stress shift in accordance with changing amount of atom's movement between the surface and grain boundary through altering the grain size of the Cu thin film with variety of parameters. The grain size is known to be affected on the deposition rate, film thickness and deposition temperature. As a experimental results, the these parameters was not adequate to explain stress shift because these parameters affect directly on the amount of atom's movement between the surface and grain boundary as well as the grain size. Thus, we have observed the stress shift toward tensile side in accordance with the grain size changing through the interlayer deposition. From an experiment with inserting interlayer before deposit Cu, in thin film which has big grain size with high roughness, amount of stress movement is higher along direction of tensile stress after deposition that means, after deposition process, driving force of atoms moving in grain boundary and on the surface of the film is relatively higher than before.