• 월간산업보건
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• s.308
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• pp.52-54
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• 2013

Phenyl glycidyl ether의 직업적 노출기준 TLV-TWA는 0.1 ppm($0.6mg/m^3$)으로 권고되고 있다. TLV-TWA는 동물실험에서 고환(정소) 독성, 비암 그리고 감작반응에 대한 위험도를 줄일 수 있다고 증명된 수준이다. 또한 사람에서의 감작반응이 보고되고 흰쥐에서 비암이 입증되어 경고표시(notation)로 SEN과 A3(동물에서 발암성 물질)를 권고하였다. Phenyl glycidyl ether와 다른 glycidyl ether에 노출된 근로자들에서 평균 6.5개월 후에 감작반응이 발견되어, 교차 감작반응의 가능성을 인지하여야 한다. Phenyl glycidyl ether를 흰쥐와 토끼에게 급성으로 피부에 도포한 결과 빠르게 흡수되어 조혈독성이 유발되는 것을 확인하여 피부(Skin) 경고표시의 타당성을 입증하였다.

• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.26-33
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• 1996

This study is related to the investigation of the characteristics of phase transfer catalysts on the addition reaction of carbon dioxide and phenyl glycidyl ether(PGE). Quaternary ammonium salts showed a good conversion of PGE at l atm of $CO_2$. Among the quaternary ammonium salts tested, the ones with higher alkyl chain length and with more hydrophilic counter anion showed higher catalytic activity. Polyethylene glycol and crown ether were also effective catalysts when they are used with NaI. High pressure of $CO_2$increased the conversion of PGE by increasing solubility of $CO_2$in NMP. A mechanism of the reaction involving the role of phase transfer catalyst was also proposed.

• 월간산업보건
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• s.310
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• pp.9-12
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• 2014

• 월간산업보건
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• s.309
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• pp.29-32
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• 2014

• Macromolecular Research
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• v.17 no.4
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• pp.221-226
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• 2009

The present study firstly describes the synthesis of novel, thermo-latent initiators based on xanthenyl phosphonium salts with different counter anions and phosphine moieties and secondly examines their efficiency in the bulk polymerization of glycidyl phenyl ether(GPE). The polymerization was performed with phosphonium salt initiators($I_{SbF6}$, $I_{PF6}$, $I_{AsF6}$ and $I_{BF4}$) at ambient temperature to $200^{\circ}C$ for 1 h. The order of initiator activity was $I_{SbF6}>I_{PF6}>I_{AsF6}>I_{BF4}$. To examine the effect of the phosphine moiety on the initiator activity, polymerization was carried out with $I_{SbF6}(Ph_{3}P)$ and $II_{SbF6}(Bu_{3}P)$ at ambient temperature to $170^{\circ}C$ for 1 h. The order of reactivity was $I_{SbF6}>II_{SbF6}$. In general, the conversion percentage increased with increasing polymerization temperature. The thermal stability of these salts was measured by thermo gravimetric analysis(TGA). The solubility of phosphonium salts in various organic solvents and epoxy monomers was also investigated.

• Applied Chemistry for Engineering
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• v.5 no.6
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• pp.1030-1035
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• 1994

Curing behavior and glass transition temperatures of epoxy resins into which reactive diluents were added to control processability were investigated. Heat of cure generated of the epoxy resin was reduced with butyl glycidyl ether(BGE) and phenyl glycidyl ether(PGE) contents. $T_g$ of the resin was decreased with the amount of reactive diluents and it was attributed to increased molecular weight between crosslink points. Cure kinetics of the resins was studied employing autocatalytic reaction model and found that reaction constants decreased as the contents of reactive diluent was increased.

• Korean Journal of Materials Research
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• v.8 no.9
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• pp.797-801
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• 1998

The cure kinetics for diglycidyl ether of bisphenol A(DGEBA)/4, 4'-methylene dianiline(MDA) system with or without lOphr of phenyl glycidyl ether(PGE)-acetamide(AcAm) was studied by autocatalytic cure expression. On the dynamic DSC curves, the exothermic peak temperature and the onset temperature of reaction decreased with the addition of PGE-AcAm. Regardless of the addition of PGE-AcAm, the shape of the conversion curve showed sigmoid, and this meant that DGEBA/MDA and DGEBA/MDA/PGE-AcAm systems followed autocatalytic cure reaction. When PGE-AcAm was added to DGEBA/MDA system, the cure rate increased about 1.2~1.4 times due to the catalytic role of hydroxyl groups in PGE-AcAm.

• Korean Journal of Materials Research
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• v.7 no.3
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• pp.229-233
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• 1997

Estimation of thermal stability for diglycidy1 ether of bisphenol A(DGEMA)/4, 4'-methylene dianiline (MDA)/pheny1 glycidy1 ether(PGE)-acetamide(AcAm)/carboxy1-terminated acrylonitrile butadiene copolymer (CTBN) system was studied by thermogravimetry(TG) analysis. To get activation energy for thermal degradation, Freeman & Carroll, Kissinger, and Flynn & Wall expressions were used. The activation energy of Freeman & Wall expression was 112.9kj/mol, that of Kissinger expression was 151.5 kj/mol and that of Flynn & Wall was 168.3kj/mol.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.356-361
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• 1996

Cure kinetics of diglycidyl ether of bisphenol A(DGEBA)/4,4'-methylene dianiline(MDA) with hydroquinone-phenyl glycidyl ether(HQ-PGE) as a reactive additive, which was preliminarily synthesized, was investigated by DSC and FT-IR analyses. Kissinger equation and Arrhenius' equation were used to calculate activation energy and pre-exponential factor. When HQ-PGE was added to DGEBA/MDA system, it reduced activation energy of system. When the 5 phr of HQ-PGE was added to DGEBA/MDA system, activation energy was 7.8 kcal/mol by FT-IR analysis and 11.3 kcal/mol by DSC, in comparison with the system without HQ-PGE, activation energy decreased about 30% and 9%, respectively. According to these results, HQ-PGE, introducing agent of this system, acted as a catalyst.

• Korean Journal of Materials Research
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• v.11 no.9
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• pp.727-732
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• 2001

The cure kinetics of diglycidyl ether of bisphenol A (DGEBA)/4,4'- methylene dianiline (MDA) system with synthesized phenyl glycidyl ether-dimethylurea (PGE-DMU) was studied by Kissinger and Ozawa equations with DSC analysis in the temperature range of $20~300^{\circ}C$ To investigate the reaction mechanism between epoxy group of PGE and urea group of DMU, FT-lR spectroscopy analysis was used. The epoxide group of PGE reacted with the urea group of DMU and formed a hydroxyl group which acted as a catalyst on the cure reaction of other epoxide and amine groups. The activation energy of DGEBA/MDA system without PGE-DMU was 46.5 kJ/mol and those of the system with 5 and 10 phr of PGE- DMU were 43.4 and 37.0 kJ/mol, respectively. Ozawa method also showed the same tendency.