• 전자공학회논문지A
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• 제29A권11호
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• pp.106-112
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• 1992

In this paper, we analyze the structure characteristics of $As_{40}Se_{50-x}S_{x}Ge_{10}$ system bulk and thin films. As the results of XRD patterns, it identified amorphous state. In order to find the glass transition temperature($T_g$), crystallization($T_c$) and melting point ($T_m$)of bulk sample, it ascertained that TS1gT is 238$^{\circ}C$ in $As_{40}Se_{15}S_{35}Ge_{10}$, and 231$^{\circ}C$ in $As_{40}Se_{25}S_{25}Ge_{10}$ & $As_{40}Se_{50}Ge_{10}$ following the thernal analysis by DSC, DTA, & TGA method. Also it was confirmed the phase seperation of continuous phase and dispertion phase by the optical texture of polarizing microscope and $T_g$ near 20$0^{\circ}C$ in thin film. Therefore, it was found that it occurs the phase seperation of Ge-rich dontinuous phase and Se-rich dispersion phase following the EDS analysis of thin film and the surface SEM photograph.

• Elastomers and Composites
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• 제40권3호
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• pp.166-173
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• 2005

본 논문에서는 세가지 종류의 경화제 (D-230, G-5022 및 HN-2200)를 사용하여 열화가 에폭시 접착제의 질량변화 및 흡수량에 미치는 영향을 고찰하였다. 경화된 시편의 열적 및 기계적 특성은 유리전이온도와 전단강도 측정을 통하여 알아보았다. 실험 결과, D-230와 HN-2200를 경화제로 사용하였을 경우 열화 시간이 시스템의 질량 변화에 영향을 주지 않았으며, G-5022를 경화제로 사용하였을 경우 시스템의 질량은 열화 시간에 따라 현저하게 감소하였다. 열화 이전의 DGEBA/G-5022 시편을 제외하고 모든 시편의 흡수량은 시간에 따라 점차 증가하였다. 또한, DGEBA/HN-2200 시스템이 제일 높은 $T_g$ 값을 나타내었으며, 이는 경화된 시스템이 지방족 고리를 함유한 3차원 네트워크 구조를 형성한 것으로 판단된다. 에폭시 수지의 접착강토는 열화 시간에 따라 점차 증가하였으며, 이는 에폭시 수지의 경화도 증가와 보다 발달된 3차원 네트워크 구조의 형성에 기인한다. 또한, 내수 실험 후 열화 전후의 모든 시편의 유리전 이온도와 전단접착강도는 흡수시간에 따라 감소하였다.

• 접착 및 계면
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• 제5권4호
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• pp.1-8
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• 2004

다이싱 테이프에 사용되는 UV경화형 점착제를 아크릴 공중합체를 butyl acrylate, acrylic acid, methyl methacrylate를 용액 중합을 통해 중합한 뒤, trimethylolpropane triacrylate를 블렌딩하여 제조하였다. 제조된 점착제는 UV 조사량에 따라 접착력, 유리전이온도 ($T_g$)를 측정하였는데 UV 조사량이 증가할수록 접착력은 급격하게 감소하였고 $T_g$도 증가하였다. 웨이퍼 표면에 점착 샘플을 부착하여 UV 조사 후 박리하여 표면을 관찰한 결과 점착잔류물을 남기지 않았다.

• 한국분말재료학회지
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• 제16권2호
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• pp.110-114
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• 2009

Mechanical coating process was applied to form 89 %-hydrolyzed poly vinyl alcohol (PVA) onto boron carbide ($B_4C$) nanopowder using one step high energy ball mill method. The polymer layer coated on the surface of B4C was changed to glass-like phase. The average particle size of core/shell structured $B_4C$/PVA was about 50 nm. The core/shell structured $B_4C$/PVA was formed by dry milling. However, the hydrolyzed PVA of $98{\sim}99%$ with high glass transition temperature ($T_g$) was rarely coated on the powder. The $T_g$ of polymer materials was one of keys for guest polymer coating on to the host powder by solvent free milling.

• Journal of Magnetics
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• 제18권4호
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• pp.395-399
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• 2013

The metallic glass ribbons of $[(Fe_xCo_{1-x})_{0.75}B_{0.2}Si_{0.05}]_{96}Mo_4$ (x = 0, 0.3, 0.6, 0.9 at.%) and $[(Fe_xCo_{1-x})_{0.75}B_{0.2}Si_{0.05}]_{96}Nb_4$ (x = 0, 0.3, 0.6, 0.9 at.%) were obtained by melt spinning with 25-30 ${\mu}m$ thickness. The thermal stability, mechanical properties and magnetic properties of Fe-Co-B-Si based systems were investigated. The values of thermal stability were measured using differential scanning calorimetry (DSC), including glass transition temperature ($T_g$), crystallization temperature ($T_x$) and supercooled liquid region (${\Delta}T_x=T_x-T_g$). These amorphous ribbons were identified as fully amorphous, using X-ray diffraction (XRD). The mechanical properties of Febased samples were measured by nano-indentation. Magnetic properties of the amorphous ribbons were measured by a vibrating sample magnetometer (VSM). The amorphous ribbons of $[(Fe_xCo_{1-x})_{0.75}B_{0.2}Si_{0.05}]_{96}Mo_4$ (x = 0, 0.3, 0.6, 0.9 at.%) and $[(Fe_xCo_{1-x})_{0.75}B_{0.2}Si_{0.05}]_{96}Nb_4$ (x = 0, 0.3, 0.6, 0.9 at.%) exhibited soft magnetic properties with low coercive force ($H_c$) and high saturation magnetization (Ms).

• 한국세라믹학회지
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• 제48권1호
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• pp.63-68
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• 2011

The investigation is directed to lead free (Pb-free) frits that can be used for organic light emitting diode, plasma display screen devices and other sealing materials. $P_2O_5$-SnO system glasses have been prepared for Pb-free low temperature glass frit. Structure and properties of the glasses with the composition SnO-$xB_2O_3-(60-x)P_2O_5$ (x=0, 5, 10, 15, 20, 25, 30, 35, 40 mol%) were characterized by infrared spectra (IR), X-ray diffraction(XRD), Density, Molar volume, Thermo mechanical analysis(TMA) and weight loss after immersion test. Glass transition temperature($T_g$), dilatometric softening temperature($T_d$) and chemical durability increased, and coefficient of thermal expansion($\alpha$) decrease with the substitution of $B_2O_3$ for $P_2O_5$ in the range of 0~25 mol%.

• 폴리머
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• 제24권1호
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• pp.128-132
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• 2000

Polycaprolactone (PCL) 블록의 함량이 62.7 wt%인 PCL-폴리아미드 블록공중합체와 poly(vinyl chloride) (PVC)의 상용거동을 시차주사열량계로 열적 성질을 관찰하여 조사하고, 블렌드물의 인장물성을 측정하였다. PCL과 PVC 세그먼트는 상용성을 가졌으며, PVC의 함량이 많은 경우 PCL의 결정화가 방해받아 PCL과 PVC 세그먼트로 구성된 비결정성 균일상이 형성됨을 알 수 있었다. PCL/PVC 균일 비결정상과 폴리아미드의 결정상이 병존하는 경우 균일 비결정상의 유리전이온도와 결정상의 녹는점 사이의 온도 영역에서 블렌드물은 고무탄성을 가졌다.

• Journal of the Korean Wood Science and Technology
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• 제37권5호
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• pp.434-439
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• 2009

This study investigates the thermal properties of nanocomposites prepared from poly(lactic acid) (PLA), wood flour (WF) and montmorillonite (MMT) by melt compounding with a twin screw extruder. In order to enhance the mechanical properties of PLA/WF composites, maleic anhydride grafted PLA (MAPLA) is synthesized as a compatibilizer. MAPLA prepared in the laboratory is characterized using FR-IR. From SEM microphotographs, the presence of MAPLA has a positive effect on the mechanical properties of WF-reinforced PLA composites. The addition of WF/MAPLA into neat PLA increased the glass transition temperature ($T_g$). The addition of 1 to 5 wt% MMT into PLA/WF/MAPLA composite decreases the $T_g$. The cold crystallization temperature ($T_{cc}$) was decreased by the addition of MMT. The MMT could act as effective nucleating sites of PLA crystallization. The thermal stability evaluated by thermogravimetric analysis (TGA) is improved with the contents of MMT up to 3 wt%.

• 한국분말재료학회지
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• 제12권6호
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• pp.406-412
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• 2005

This work is to present a new synthesis of metallic glass (MG)/metallic glass (MG) composites using gas atomization and spark plasma sintering (SPS) processes. The MG powders of $Cu_{54}Ni_6Zr_{22}Ti_{18}$ (CuA) and $Ni_{59}Zr_{15}Ti_{13}Nb_7Si_3Sn_2Al_1$(NiA) as atomized consist of fully amorphous phases and present a different thermal behavior; $T_g$ (glass transition temperature) and $T_x$ (crystallization temperature) are 716K and 765K for the Cu base powder, but 836K and 890K for the Ni base ones, respectively. SPS process was used to consolidate the mixture of each amorphous powder, being $CuA/10\%NiA\;and\;NiA/10\%CuA$ in weight. The resultant phases were Cu crystalline dispersed NiA matrix composites as well as NiA phase dispersed CuA matrix composites, depending on the SPS temperatures. Effect of the second phases embedded in the MG matrix was discussed on the micro-structure and mechanical properties.

• 한국포장학회지
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• 제27권2호
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• pp.85-90
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• 2021

The gamma irradiation was on to Poly(butylene sebacate-co-terephthalate) (PBSeT), Poly(butylene adipate-co-terephthalate) (PBAT), Poly(lactic acid) (PLA) and casting polypropylene (CPP) at dose levels from 0 to 50 kGy. The properties of gamma irradiated samples were analyzed using DSC, TGA, UTM and FT-IR spectra. The mechanical and thermal properties of PBSeT and PBAT after gamma irradiation were less affected than CPP. The tensile strength and elongation of PBSeT was not affected by gamma irradiation, while these of PBAT, PLA and CPP were significantly decreased at 50 kGy gamma-ray dose. The thermal stability of PBSeT, PBAT, PLA and CPP showed a similar tendency to tensile strength. The glass transition temperature(T_g) and melting temperature(T_m) of PBSeT and PBAT were not altered by increasing gamma-ray dose, while these of PLA and CPP decreased. The chemical composition of all samples was not modified by gamma irradiation, and it was confirmed by FT-IR spectra. Based on mechanical and thermal stability studies of gamma irradiation on bioplastics, tested biodegradable packaging materials showed a potential to be used in sterilization process up to 35 kGy.