• 제목/요약/키워드: glass properties

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상업용 유리프릿의 소결 공정을 이용한 내수성을 갖는 CsPbBr3/Glass 세라믹 복합체의 제작 (Simple Fabrication of Green Emission and Water-Resistant CsPbBr3 Encapsulation Using Commercial Glass Frits)

  • 문나은;김성훈
    • 한국재료학회지
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    • 제31권1호
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    • pp.54-59
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    • 2021
  • In this work, narrow-band green-emitting CsPbBr3 particles are embedded in commercialized glass composites by a facile dry process. By optimizing the method through sintering in glass frit (GF) composites including CsBr and PbBr2, used as precursors, the encapsulation of CsPbBr3 particles made them waterproof with green fluorescence. To improve the fluorescent properties by reducing aggregation of CsPbBr3, fumed silica (FS) is additionally used to help particles avoid bulking up in the glass matrix. The CsPbBr3 perovskite/glass composites are characterized using scanning electron microscopy (SEM) images and energy-dispersive X-ray spectroscopy (EDS) maps, which support the existence of CsPbBr3 particles in the glass matrix. The photoluminescence (PL) properties demonstrate that the emission spectrum peak, full width at half maximum (FWHM), and photoluminescence quantum yield (PLQY) values are 519 nm, 17 nm, and 17.7 %. We also confirm the water-resistant properties. To enhance water/moisture stability, the composite sample is put directly into water, with its PLQY monitored periodically under UV light.

PDP의 격벽 형성 공정인 감광성 공법에서 $B_2O_3-Al_2O_3-SiO_2$계 유리 조성의 열적 특성과 굴절률 변화 (Thermal Properties and Refractive Index of $B_2O_3-Al_2O_3-SiO_2$ Glasses for Photolithographic Process of Barrier Ribs in PDP)

  • 황성진;원주연;김형순
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.321-321
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    • 2008
  • To obtaingood resolution in PDP, one of the important factors is to achieve the accuracy of barrier ribs. The photolithographic process can be used to form patterns of barrier rib with high accuracy and a high aspect ratio. The composition for photolithography is based on the $B_2O_3-SiO_2-Al_2O_3$ glass system including additives such as alkali oxides and alkali earth oxides. The refractive index and thermal properties in glass system are changed by amount of alkali oxides and alkali earth oxides. Therefore, it is important that additives are controlled to have proper refractive index and thermal properties. The additives are contributed to non-bridging oxygen within the glass network, causing a change of density. In addition to a change of the structural cross-link density, the refractive index, dielectric and thermal properties glass are correlated with ionic radius and polarizability of cations. In this study, we investigated the refractive index and the thermal properties such as glass transition temperature, glass softening temperature and coefficient of thermal expansion by changing composition in the $B_2O_3-SiO_2-Al_2O_3$ glass system.

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Staggered and Inverted Staggered Type Organic-Inorganic Hybrid TFTs with ZnO Channel Layer Deposited by Atomic Layer Deposition

  • Gong, Su-Cheol;Ryu, Sang-Ouk;Bang, Seok-Hwan;Jung, Woo-Ho;Jeon, Hyeong-Tag;Kim, Hyun-Chul;Choi, Young-Jun;Park, Hyung-Ho;Chang, Ho-Jung
    • 마이크로전자및패키징학회지
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    • 제16권4호
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    • pp.17-22
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    • 2009
  • Two different organic-inorganic hybrid thin film transistors (OITFTs) with the structures of glass/ITO/ZnO/PMMA/Al (staggered structure) and glass/ITO/PMMA/ZnO/Al (inverted staggered structure), were fabricated and their electrical and structural properties were compared. The ZnO thin films used as active channel layers were deposited by the atomic layer deposition (ALD) method at a temperature of $100^{\circ}C$. To investigate the effect of the substrates on their properties, the ZnO films were deposited on bare glass, PMMA/glass and ITO/glass substrates and their crystal properties and surface morphologies were analyzed. The structural properties of the ZnO films varied with the substrate conditions. The ZnO film deposited on the ITO/glass substrate showed better crystallinity and morphologies, such as a higher preferred c-axis orientation, lower FWHM value and larger particle size compared with the one deposited on the PMMA/glass substrate. The field effect mobility ($\mu$), threshold voltage ($V_T$) and $I_{on/off}$ switching ratio for the OITFT with the staggered structure were about $0.61\;cm^2/V{\cdot}s$, 5.5 V and $10^2$, whereas those of the OITFT with the inverted staggered structure were found to be $0.31\;cm^2/V{\cdot}s$, 6.8 V and 10, respectively. The improved electrical properties for the staggered OITFTs may originate from the improved crystal properties and larger particle size of the ZnO active layer.

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Li2O-Al2O3-SiO2계 결정화 유리의 특성(I) (Properties of Li2O-Al2O3-SiO2 Glass Ceramic System(I))

  • 양준환;정헌생
    • 한국세라믹학회지
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    • 제25권5호
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    • pp.431-436
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    • 1988
  • The properties of scid-resistance to boiling HCl, thermal expansion coefficient and softening temperature of mother glass and glass-ceramic of LAS systems were investigated at the contents of SiO2 varing from 57 to 67wt%. The nucleation and growth of crystalline phase of LAS compositions were carried out at 50$0^{\circ}C$ and $700^{\circ}C$. The crystalline phase jconsists of lithium alumino silicate, lithum meta silicate, lithium disilicate, $\alpha$-crystobalite and $\alpha$-quartz. Lithium alumino silicate(virgilite) is the major crystalline phase in the glass ceramics. The degree of acid resistant property was increased in proportion with the silica content for both glass and ceramics. Glass-ceramic gives lower acid-resistance and thermal expansion coefficient while softening temperature shows higher for glass-ceramic than for mother glass.

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Effect of the Oxide Glass on the Metal Sintering Behavior in Silver Thick-Film System

  • ;김호기
    • 한국세라믹학회:학술대회논문집
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    • 한국세라믹학회 1986년도 Priceedings Of The Third Korea-Japan Seminar On New Ceramics
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    • pp.259-267
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    • 1986
  • The sintering behavior of silver-oxide glass composite thick-film has been studied with varing glass content. It is shown that during heat treatment glass became liquid phase to deeply affect the microstructure development of the silver particles and to control the physical properties of the thick-films. As glass content increased, the initial repacking of silver particles took place rapidly but the homogeneities of the microstructure showed different features. When the glass content was over some range, the silver particles exuded glass to decrease net energy and glass formed liquid pools separated from the solid skeletons. Finally the relations between the microstructures and electrical properties of the thick-film were discussed.

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HIC용 $RuO_2$ 후막저항체에서 유리의 물리적 성질이 TCR에 미치는 영향 (Effects of Physical Properties of Glass on the TCR of $RuO_2$ Thick Film Resistors for Hybrid Integrated Circuits (HIC))

  • 이병수;이준
    • 한국세라믹학회지
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    • 제30권11호
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    • pp.974-978
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    • 1993
  • Glass viscosity effects on the electrical properties and microstructure of RuO2 based thick film resistors (TFR) using alumina modified lead borosilicate glasses were studied. AT 85$0^{\circ}C$, the glass viscosities were increased from 4.24Pa.s to 51.5Pa.s when the alumina was added from none to 14 weight percent to the standard glass of 63% PbO, 25% B2O3 and 12% SiO2. The resistivities of resistors were generally decreased and the microstructure development was retarded as the viscosity of the glass increased. This is contrary to the generally accepted thought that the low resistivity is due to fast microstructure development kinetics in TFR. Even though the glass viscosity retards the microstructure development kinetics, the overall network formations are favored for higher viscosity of glass, such that the sheet resistivities were decreased as the glass viscosity increased.

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Mechanical properties of recycled fine glass aggregate concrete under uniaxial loading

  • Liang, Jiong-Feng;Yang, Ze-Ping;Yi, Ping-Hua;Wang, Jian-Bao
    • Computers and Concrete
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    • 제16권2호
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    • pp.275-285
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    • 2015
  • This paper reports the results of an experimental study on the compressive strength and the stress-strain curve (SSC) of recycled fine glass aggregate concrete with different replacement percentages of recycled fine glass aggregate. The results show that the recycled fine glass aggregate contents have significant impact on the workability, compressive strength, the elastic modulus, the peak and the ultimate strains of recycled fine glass aggregate concrete. Analytical expressions for the stress-strain relationship of recycled fine glass aggregate concrete are given, which can satisfactorily describe the effect of the recycled fine glass aggregate on the SSC.

개량형 가동보에 적용하기 위한 하이브리드 강판/GFRP 패널 게이트의 강판게이트 표면형상에 따른 휨 및 계면 부착 특성 평가 (Flexural and Interfacial Bond Properties of Hybrid Steel/Glass Fiber Reinforced Polymer Composites Panel Gate with Steel Gate Surface Deformation for Improved Movable Weir)

  • 김기원;권형중;김필식;박찬기
    • 한국농공학회논문집
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    • 제57권2호
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    • pp.57-66
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    • 2015
  • The purpose of this study was to improved the durability of a improved movable weir by replacing the improved movable weir's metal gate with a hybrid steel/glass fiber reinforced polymer composites panel gate. Because the metal gate of a improved movable weir is always in contact with water, its service life is shortened by corrosion. This study made four type of hybrid steel/glass fiber reinforced polymer composites panel gate with different steel gate surface deformation (control, sand blast, scratch and hole), flexural. Fracture properties tests were performed depending on the steel gate surface deformation. According to the test results, the flexural behavior, flexural strength and fracture properties of hybrid steel/glass fiber reinforced polymer composites panel gate was affected by the steel panel gate surface deformation. Also, the sand blast type hybrid steel/glass fiber reinforced polymer composites panel gate shows vastly superior flexural and fracture performance compared to other types.

섬유강화 복합재료에서 섬유열화에 따른 계면특성의 변화 (Change of Interfacial properties by the Fiber Degradation in the Fiber Reinforced Composites)

  • 문창권;김영대;노태영
    • 한국해양공학회지
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    • 제12권3호통권29호
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    • pp.31-41
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    • 1998
  • Single fiber fragmentation technique was used to evaluate the change of interfacial properties by degradation of fiber tensile strength in the fiber reinforced composites. The influences of fiber tensile strength on the interfacial properties have been evaluated by the fragmentation specimens(weak fiber samples) of glass fiber/epoxy resin that was made using the pre-degraded glass fiber in distilled water at $80^{circ}C$ for specified periods. The effects of the immersion time on the interfacial properties in the distilled water at $80^{circ}C$ also have been evaluated by the fragmentation specimens(original fiber samples) of glass fiber/epoxy resin that was made using the received glass fiber. As the result, the tensile strength of glass fiber was decreased with the increasing of the treatment time in the distilled water at $80^{circ}C$ and the interfacial shear strength was independent of the change of the glass fiber strength in the single fiber fragmentation test. But in the durability test using the single fiber fragmentation specimen, interfacial shear strength decreased with the increasing of the immersion time in distilled water ar $80^{circ}C$. And it turned out that the evaluating of interfacial shear strength using original fiber tensile strength was valuable in the durability test for the water environment by the single fiber fragmentation technique.

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유리 분말과 함께 소결한 (Na,K)NbO3계 압전체의 미세구조 및 전기적 특성 (Microstructures and Electrical Properties of (Na,K)NbO3-Based Piezoceramics Sintered with Glass Frit)

  • 피지희;권순용
    • 한국전기전자재료학회논문지
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    • 제26권9호
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    • pp.646-650
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    • 2013
  • $(Na,K)NbO_3$-based piezoelectric ceramics were synthesized by a liquid phase sintering method with a selected glass frit. The effects of the content of the glass frit and the sintering temperature on the microstructure and the electrical properties of the samples were investigated. With the 0.1 wt% of glass frit content, $(Na_{0.52}K_{0.44}Li_{0.06})(Nb_{0.84}Ta_{0.10}Sb_{0.06})O_3$ (NKL-NTS) ceramics showed the maximum values of the relative density (99.1%) and the electro-mechanical coupling factor ($k_p$: 0.32) at the sintering temperature of $1,050^{\circ}C$. It might mean that a liquid phase sintering with a suitable glass frit having the lower flow temperature could improve the relative density and the piezoelectric properties.