• 한국재료학회지
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• 제22권12호
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• pp.669-674
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• 2012

Yellow phosphor dispersed color conversion glasses are promising phosphor materials for white LED applications because of their good thermal durability, chemical stability, and anti-ultraviolet property. Six color conversion glasses were prepared with high Tg and low Tg specimens of glass. Luminous efficacy, luminance, CIE (Commission Internationale de l'Eclairage) chromaticity, CCT (Correlated Color Temperature), and CRI (Color Rendering Index) of the color conversion glasses were analyzed according to the PL spectrum. Color conversion glasses with high Tg glass frit, sintered at higher temperature, showed better luminous properties than did color conversion glasses with low Tg glass frit. The characteristics of the color conversion glass depended on the glass composition rather than on the sintering temperature. The XRD peaks of the YAG phosphor disappeared in the color conversion glass with major components of $B_2O_3$-ZnO-$SiO_2$-CaO and, in the XRD results, new crystalline peaks of $BaSi_2O_5$ appeared in the color conversion glass with major components of $Bi_2O_3$-ZnO-$B_2O_3$-MgO. The characteristics of CIE chromaticity, CCT, and the CRI of low Tg color conversion glasses showed worse color properties than those of high Tg color conversion glasses. However, these color characteristics of low Tg glasses were improved by thickness variation. So color conversion glasses with good characteristics of both luminous and color properties were attained.

• 대한기계학회논문집A
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• 제25권12호
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• pp.1988-1994
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• 2001

The CRT(Cathode-ray Tube) of salvage is a process of separating the panel and funnel to recycle a cathode-ray tube. In this paper, the thermal properties of glass for CRT were studied to improve its recycling ratio. In the salvage process, several patterns of breakage, as called 'comer pull', were easily generated on the sealing surface of panel or funnel glass due to the residual tensile stress, which had correlations with some parameters of the manufacturing process of CRT and the initial material properties of glass. Finite element analyses and experimental approaches on the flit sealing process were carried out to obtain the major characteristic of glass related to the residual stress. From this study, it was identified that the thermal expansion coefficient of glass had much influence on the residual stress of panel glass after frit sealing process. Therefore, the optimal conditions of thermal properties for CRT glass were proposed to achieve an effective salvage process. By using these optimal conditions, the size of comer pull on the panel and funnel glass was reduced to 10% level compared with the original size, and the recycling ratio of CRT was increased in the salvage process.

• 콘크리트학회논문집
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• 제14권3호
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• pp.440-448
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• 2002

산업의 발달과 더불어 폐유리의 발생량은 점차 증가되고 있다. 콘크리트에 폐유리를 사용할 경우 알칼리 실리카 반응(ASR)에 의한 팽창으로 콘크리트에 균열이 발생하여 성능저하를 일으킬 수 있다. 본 연구에서는 폐유리의 색깔(갈색, 녹색), 입도 및 폐유리로 인해 발생되는 ASR팽창을 저감시키기 위해 산업부산물의 종류(플라이애시, 고로슬래그 미분말)와 혼입율에 따른 ASR팽창과 강도특성을 분석하였다. 또한, 포졸란 재료로서 폐유리 분말의 사용가능성을 분석하였다. 연구결과, 폐유리의 색깔에 관계없이 폐유리의 퍼시멈 입도는 2.5~l.2mm로 나타났으며, 폐유리의 입도가 2.5~l.2 mm보다 작을수록 팽창은 점차 감소하는 것으로 나타났다. 또한, 폐유리에 산업부산물의 혼입은 ASR로 인한 팽창과 강도저하를 억제시키는데 효과적이며, 0.075 mm미만의 폐유리 분말이 포졸란 재료로서 적용이 가능한 것으로 나타났다.

• International Journal of Concrete Structures and Materials
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• 제18권2E호
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• pp.125-132
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• 2006

Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.

• 공업화학
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• 제16권3호
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• pp.440-448
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• 2005

폐 유리병을 비롯한 폐 유리들을 대상으로 이들을 세척 또는 불순물의 분리 등 전처리를 하지 않고 건축용 단열재로서 발포유리 제조를 위한 원료로서의 적용 가능성 여부를 타진하기 위하여 폐 병유리, 폐판유리 및 LCD 유리 등의 물리화학적 특성을 조사하였다. 이를 위해서 폐 유리의 화학적 성분 분석, 열분석, 결정학적 분석, 점성, 유변학적 분석을 시행하였으며 이 결과를 바탕으로 정성적인 발포유리 제조도 시도하였다. 모든 분석 및 검토의 결과 및 폐 유리병 및 판유리는 발포유리의 제조 원료로서 충분한 사용가능성을 보여 주었다.

• 한국광학회지
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• 제2권2호
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• pp.103-107
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• 1991

Nonlinearity of glass had not been remarkably large among all the available nonlinear materials. However, its superiority in optical and mechanical properties has attracted much attention for the practical application. To this goal the recent interests in this field have been shifting from the understanding of nonlinear mechanisms to the improvements of nonlinear properties.

• 한국세라믹학회지
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• 제56권2호
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• pp.173-177
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• 2019

Thermal properties of a SiO₂-B₂O₃-BaO ternary glass system depending on compositional change of BaO have been examined to find a proper sealing material for reversible oxide cells. Glass transition temperature and thermal expansion coefficients increased simultaneously up to 55 mol% of BaO content. The structural role of BaO with regard to the thermal properties has been discussed on the basis of Raman spectroscopy results. Flowability of the glass at sealing temperature has been examined with packed glass powders of 12 mm diameter along with a high temperature optical microscope. The practical sealing property of the glass was also examined with YSZ coated with NiO-yittria stabilized zirconia (NiO-YSZ) and it showed good adhesion without noticeable reaction with NiO-YSZ layer.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.323-323
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• 2007

Influence of $La_2O_3$ addition to $CaO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $La_2O_3-CaO-B_2O_3$(LCB) glass was ball milled for varying time, followed by mixing with $Al_2O_3$ crystalline phase to form $Al_2O_3$-LCB glass composites at $875^{\circ}C$ for 1h. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the LCB glass. Dielectric constant and quality factor of the composites were 6.31 and 13856 GHz, respectively, when the LCB glass was ball milled for 2h prior to mixing with $Al_2O_3$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.324-324
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• 2007

Influence of $La_2O_3$ addition to $ZnO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $La_2O_3-ZnO-B_2O_3$ (LZB) glass was ball milled for varying time, followed by mixing with $Al_2O_3$ crystalline phase to form $Al_2O_3$-LZB glass composites at $875^{\circ}C$ for lh. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the LZB glass. Dielectric constant and quality factor of the composites were 6.01 and 11676 GHz, respectively, when the LZB glass was ball milled for 2h prior to mixing with $Al_2O_3$.

• 한국재료학회지
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• 제31권1호
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• pp.54-59
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• 2021

In this work, narrow-band green-emitting CsPbBr3 particles are embedded in commercialized glass composites by a facile dry process. By optimizing the method through sintering in glass frit (GF) composites including CsBr and PbBr2, used as precursors, the encapsulation of CsPbBr3 particles made them waterproof with green fluorescence. To improve the fluorescent properties by reducing aggregation of CsPbBr3, fumed silica (FS) is additionally used to help particles avoid bulking up in the glass matrix. The CsPbBr3 perovskite/glass composites are characterized using scanning electron microscopy (SEM) images and energy-dispersive X-ray spectroscopy (EDS) maps, which support the existence of CsPbBr3 particles in the glass matrix. The photoluminescence (PL) properties demonstrate that the emission spectrum peak, full width at half maximum (FWHM), and photoluminescence quantum yield (PLQY) values are 519 nm, 17 nm, and 17.7 %. We also confirm the water-resistant properties. To enhance water/moisture stability, the composite sample is put directly into water, with its PLQY monitored periodically under UV light.