• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.3
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• pp.120-128
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• 2005

In the construction industry, due to the cost rise of raw material for concrete, we have looked into recycling by-products which came from foundry. When using the Ground Granulated Blast-Furnace Slag(SG), it is good for enhancing the qualities of concrete such as reducing hydration heat, increasing fluidity, long-term strength and durability, but it has some problems : construction time is increased or the rotation rate of form is decreased due to low development of early strength. In this study, therefore, to enhance the early strength of SG mortar, we used some alkali activators(KOH, NaOH, $Na_2CO_3$, $Na_2SO_4$, water glass, $Ca(OH)_2$, alum. This paper deals with reacted products, setting time, heat evolution rate, flow and the strength development of SG cement mortar activated by alkali activators. From the results, if alkali activators were selected and added properly, SG is good for using as the materials of mortar and concrete.

• Journal of the Korean Ceramic Society
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• v.47 no.5
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• pp.381-386
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• 2010

Some basic properties of inorganic coatings hardened by the room temperature reaction with alkalies were examined. The coating paste was prepared from the powders in the system $Al_2O_3-SiO_2$-CaO using blast furnace slag, fly ash and amorphous ceramic fiber after mixing with a solution of sodium hydroxide and water glass. The mineralogical and morphological examinations were performed for the coatings prepared at room temperature and after heating to $1200^{\circ}C$ respectively. The binding force of the coating hardened at room temperature was caused by the formation of fairly dense matrix mainly composed of oyelite-containing amorphous phase formed by the reaction between blast furnace slag and alkali solution. At the temperature, fly ash and ceramic fiber was not reacted but imbedded in the binding phase, giving the fluidity to the paste and reinforcing the coating respectively. During heating up to $1200^{\circ}C$, instead of a break in the coating, anorthite and gehlenite was crystallized out by the reaction among the binding phase and unreacted components in ternary system. The crystallization of these minerals revealed to be a reason that the coating maintains dense morphology after heating. The maintenance of binding force after heat treatment is seemed to be also caused by the formation of welldispersed fiber-like mineral phase which is originated from the shape of the amorphous ceramic fiber used as a raw materials.

• Journal of the Korean GEO-environmental Society
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• v.12 no.4
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• pp.17-24
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• 2011

For the purpose of cut off and ground stabilization, water glass chemical grouting method using sodium silicate has problems of weakening durability and ground water pollution because leaching was conducted when the homogel is exposed to the ground water as time elapses. The purpose of this study is to identify the effect of alkali silica sol ground injection materials, it was compared with the sodium silicate ground injection materials using water glasses. For sodium silicate and alkali silica sol by mixing each case is divided into four different specimens were made and tested. The characteristic of alkali silica sol ground injection material was analyzed by unconfined compression test and environmental impact statement of ordinary portland cement and blast furnace slag cement. Alkali silica sol specimens were made mixing A-solution and B-solution in the proportion of one on one. Through this study, alkali silica sol ground injection mixing blast furnace slag cement has excellent strength and environment-friendly.

• Resources Recycling
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• v.33 no.1
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• pp.37-47
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• 2024

In grouting, the LW method is commonly employed to induce the gelation of cementitious material using water glass, thereby restricting the extent of material injection. Nevertheless, challenges manifest when materials are lost before gelation, particularly in regions with high groundwater flow rates or significant subsurface voids. This study developed a thixotropic grout material using LFS and GGBFS to mitigate material loss during injection, with an assessment of its flow characteristics, durability in marine exposure, strength, and injection properties. The outcomes revealed that the thixotropic grout material exhibited flow ranging from 105 to 143 mm and enhanced strength and durability compared to the LW method. Furthermore, field tests substantiated that applying vibration and impact improved impermeability.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.6
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• pp.603-612
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• 2016

The objective of this study was to estimate the emission characteristics for PM, $PM_{10}$, and $PM_{2.5}$ in the various stationary sources. The particulate matters collected in the various stationary sources such as power plants (Coal and B-C oil), incinerators(municipal and industrial waste), and glass furnaces. The PM and $PM_{10}$, PM and $PM_{2.5}$, $PM_{10}$ and $PM_{2.5}$ samples were collected using the cyclone type $PM_{10}$, $PM_{2.5}$ samplers and 30 species(19 inorganic species, 9 ionic species, OC and EC) were analyzed by ICP, IC, and TOR/IMPROVE methods. The mass concentrations of PM, $PM_{10}$, $PM_{2.5}$ from nine stationary sources ranged $0.63{\sim}9.58mg/Sm^3$, $0.26{\sim}7.47mg/Sm^3$ and $0.13{\sim}6.34mg/Sm^3$, respectively. The level of $PM_{10}$, $PM_{2.5}$ portion in PM calculated 0.63~0.99, 0.38~0.94, respectively. In the case of emission trend for species, power plant showed high concentrations for Al, Mg, Na, Si, V and $SO_4{^{2-}}$, respectively. Also, Ca, Fe, K, Si, $Cl^-$, and $K^+$ showed high in incinerator. In the case of glass furnace, Na, Pb, K, Si, $Na^+$ and $SO_4{^{2-}}$ represented high concentrations. Power plant showed higher EC/OC concentrations than other sampling sites. These results suggest the possible role for complement establishment process of emission inventory and emission management for PM.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.5
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• pp.51-58
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• 2014

This paper presents a fire exposure test result to evaluate fire resistance capacity of retrofit method using FRP (Fiber Reinforced Polymer) in reinforcement concrete structure. Especially, this paper focused on near-surface-mounted retrofit method; FRP is mounted into the groove after making a groove in concrete. In the test, main parameters are retrofit method and materials for fire proofing. Spray type of perlite and board type of calcium silicate were considered as external fire proof on surface while particle of calcium silicate and polymer mortar as internal one in groove. By increasing the temperature of inside heating furnace, the transfer of temperature from surface of fire proofing material to groove in specimen was measured. As a result, fire proofing using the board of calcium silicate was more effective to delay the heat transfer from outside than spraying with perlite. It was found that the fire proofing could resist outside temperature of $820^{\circ}C$ at maximum to keep the temperature of epoxy below glass transit temperature (GTT).

• Journal of Korea Foundry Society
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• v.23 no.5
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• pp.276-285
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• 2003

In the undercooled melt of $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy, the solidification behavior including nucleation and growth of crystals at the micrometer level has been observed in-situ by use of a confocal scanning laser microscope combined with an infrared image furnace. The $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy specimens were cooled from the liquid state to glass transition temperature. 575 K, at various cooling late under a helium gas flow. According to the cooling rate, the morphologies of the solidification front are changed among various types, irregular jog like front, columnar dendritic front, cellular grain, star like shape jog and fine grain, etc. The velocities of the solid-liquid interface are measured to be $10^{-5}{\sim}10^{-8}$ m/s which are at least two orders higher than the theoretical crystal growth rates. Combining the morphologies observed in terms of cooling rates and their solidification behaviors, we conclude that phase separation takes place in the undercooled molten $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy. The continuous cooling transformation (CCT) diagram was constructed from solidification onset time at various linear cooling conditions with different rate. The CCT diagram suggests that the critical cooling rate for glassy solidification is about 1.5 K/s, which is in agreement with the previous calorimetric findings.

• Journal of the Korean Vacuum Society
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• v.5 no.4
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• pp.348-353
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• 1996

Rapid thermal annealing (RTA) was applied to polycrystalline CdTe thin films evaporated on CdS/ITO/glass substrate and the effect of the annealing temperatures and the atmosphere on physical properties of polycrystalline CdTe thin films and CdTe/CdS solar cell characteristics were studied. Results obtained by EDX showed that the bulk composition of CdTe remained stoichiometric after annealing at $550^{\circ}C$ in the air but the surface composition became Cd-rich. Cross-sectional TEM and micro EDX showed that columnar grains and micro-twins remained even after RTA, however, and the sulfur content in the annealed CdTe (added by sulfur diffusion from CdS during the annealing) was much smaller than that by furnace annealing. Among the investigated RTA temperatures and gas environments, the cell made with CdTe annealed at $550^{\circ}C$ in air showed the best solar energy conversion efficiency.

• Resources Recycling
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• v.26 no.1
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• pp.43-50
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• 2017

In the present study, the multiple light scattering method was used for analysis of early hardening behavior of natural hydraulic lime (NHL) containing inorganic additives. In order to improve the properties of self-manufactured NHL, blast furnace slag and three types of gypsum were mixed with mixing ratio, and a water/solid ratio of fresh NHL paste was fixed 0.6. The fresh pastes in flat-bottomed cylindrical glass tubes were placed in the instrument. The backscattering flux (BS) of light from fresh pastes was then periodically measured at 10 minutes intervals the entire length of the sample (55mm) at $23^{\circ}C$ for 24 hours. The rate of increase of BS, slope of a linear equation to the mean value of BS (%) as a function of hydration time, was increased from 0.02 to 0.38 BS %/hour due to addition of blast furnace slag and gypsum. In the case of addition of hemi-hydrate, BS (%) and rate of increase in BS were highest.

• Journal of the Korean institute of surface engineering
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• v.38 no.1
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• pp.7-13
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• 2005

Bismuth thin films were prepared on glass substrate with RF magnetron sputtering and effects of substrate temperature on surface morphology and their electrical transport properties were investigated. Grain growth of bismuth after nucleation and the onset of coalescense of grains at 393 K were observed with field emission secondary electron microscopy. Continuous thin films could not be obtained above 473 K because of grain segregation and island formation. Hall effect measurements showed that substrate heating yields the decrease of carrier density and the increase of mobility. Resistivity of bismuth film has its minimum (about 0.7 x 10/sup -3/ Ωcm) in range of 403～433 K. Annealing of bismuth films deposited at room temperature was carried out in a radiation furnace with flowing hydrogen gas. The change of resistivity was not significant due to cancellation of the decrease of carrier density and the increase of mobility. The abrupt change of electrical properties of film annealed above 523 K was found to be caused by partial oxidation of bismuth layer in x-ray diffraction analysis.