• 제목/요약/키워드: glass composition

검색결과 741건 처리시간 0.031초

알루미늄-실리콘 공융 조성 합금 페이스트를 이용한 국부 후면 전계 태양전지 특성 분석 (Properties of Silicon Solar Cells with Local Back Surface Field Fabricated by Aluminum-Silicon Eutectic Alloy Paste)

  • 최재욱;박성은;배수현;김성탁;박세진;박효민;강윤묵;이해석;김동환
    • Current Photovoltaic Research
    • /
    • 제4권4호
    • /
    • pp.145-149
    • /
    • 2016
  • Characteristic of aluminum-silicon alloy paste which is applied on the rear side of PERC cell was investigated. The paste was made by aluminum-silicon alloy with eutectic composition to avoid the formation of void which is responsible for the degradation of the open-circuit voltage. Also, the glass frit component of the paste was changed to improve the adhesion of aluminum-silicon paste. We observed the formation of void and local back surface field between aluminum electrode and silicon base by SEM. The light IV, quantum efficiency and reflectance of the solar cells were characterized and compared for each paste.

노즐 분사 방식의 ITO 표면 포토레지스트 박리과정 요인의 수치해석 (Numerical Investigation of Factors affecting Photoresist Stripping Process on the ITO Surface using the Spray Method)

  • 김준현;이준혁;강태성;주기태;김용성;정병현;이대원
    • 한국생산제조학회지
    • /
    • 제26권2호
    • /
    • pp.158-165
    • /
    • 2017
  • This study investigated spraying factors applicable to stripper usage. Cyclodextrine, as environment-friendly material, was included in the stripper composition. An efficient spray technology was applied for the Photoresist strip. For industrial applications, stripping requires a temperature below $50^{\circ}C$, a strip time within 50 s, and chemically stable activation. Spraying factors were organized considering many conditions-orifice diameter, working pressure (inlet speed), spray distance, and spray angle. For commercial practicability, the flow rate was limited to 3 L/min. The nozzle parameters were nozzle orifice diameter of 1.8-2.2 mm, spray distance of 40-60 mm, and injection speed of 0.7-1.2 m/s. Through the thermal spray movement of the fluid, the thermal boundary layer for a chemical reaction just above the ITO-glass surface and momentum region for sufficient agitation (above 4 m/s) was achieved.

Morphological Structural and Electrical Properties of DC Magnetron Sputtered Mo Thin Films for Solar Cell Application

  • Fan, Rong;Jung, Sung-Hee;Chung, Chee-Won
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.389-389
    • /
    • 2012
  • Molybdenum is one of the most important materials used as a back ohmic contact for $Cu(In,Ga)(Se,S)_2$ (CIGS) solar cells because it has good electrical properties as an inert and mechanically durable substrate during the absorber film growth. Sputter deposition is the common deposition process for Mo thin films. Molybdenum thin films were deposited on soda lime glass (SLG) substrates using direct-current planar magnetron sputtering technique. The outdiffusion of Na from the SLG through the Mo film to the CIGS based solar cell, also plays an important role in enhancing the device electrical properties and its performance. The structure, surface morphology and electrical characteristics of Mo thin films are generally dependent on deposition parameters such as DC power, pressure, distance between target and substrate, and deposition temperature. The aim of the present study is to show the resistivity of Mo layers, their crystallinity and morphologies, which are influenced by the substrate temperature. The thickness of Mo films is measured by Tencor-P1 profiler. The crystal structures are analyzed using X-ray diffraction (XRD: X'Pert MPD PRO / Philips). The resistivity of Mo thin films was measured by Hall effect measurement system (HMS-3000/0.55T). The surface morphology and grain shape of the films were examined by field emission scanning electron microscopy (FESEM: Hitachi S-4300). The chemical composition of the films was obtained by the energy dispersive X-ray spectroscopy (EDX). Finally the optimum substrate temperature as well as deposition conditions for Mo thin films will be developed.

  • PDF

발전소 온배수를 적용한 대규모 시설원예단지용 난방시스템의 열원이송 배관 재질 및 거리에 따른 성능평가 (Effects of Pipe Network Composition and Length on Power Plant Waste Heat Utilization System Performance for Large-scale Horticulture Facilities)

  • 이금호;이재호;이광호
    • 한국지열·수열에너지학회논문집
    • /
    • 제11권4호
    • /
    • pp.14-21
    • /
    • 2015
  • Korean government plans to establish large-scale horticulture facility complexes using reclaimed land in order to improve the national competitiveness of agriculture at the government level. One of the most significant problems arising from the establishment of those large-scale horticulture facilities is that these facilities still largely depend on a fossil fuel and they require 24 h a day heating during the winter season in order to provide the necessary breeding conditions for greenhouse crops. These facilities show large energy consumption due to the use of coverings with large heat transmission coefficients such as vinyl and glass during heating in the winter season. This study investigated the applicability of waste heat from power plant for large-scale horticulture facilities by evaluating the waste heat water temperature, heat loss and energy saving performance as a function of distance between power plant and greenhouse. As a result, utilizing power plant waste heat can reduce the energy consumption by around 85% compared to the conventional gas boiler, regardless of the distance between power plant and greenhouse.

의치 연성이장재에 대한 Candida albicans의 부착과 침투연구 (IN VITRO STUDY ON THE ADHERENCE AND PENETRATION OF CANDIDA ALBICANS INTO DENTURE SOFT LINING MATERIALS)

  • 김민주;신상완;이정열
    • 대한치과보철학회지
    • /
    • 제44권4호
    • /
    • pp.466-476
    • /
    • 2006
  • Purpose : Colonization of denture soft lining materials by Candida albicans can result in clinical problem, and deterioration of the materials. This study aimed to compare the retention and penetration of C. albicans into four denture soft lining materials commonly used. Materials and methods : Four denture soft lining materials (Coe-comfort$^{(R)}$, Coe-soft$^{(R)}$, GC soft liner$^{(R)}$, and Tissue conditioner$^{(R)}$) discs were prepared to glass slide and dental stone. Adherence of yeast to surfaces was monitored after one hour incubation of standardized washed cell suspension with test disc surfaces. Adherent cells stained with acridine orange were counted fluorescence microscopy. Penetration of yeast into materials bonded with acrylic resin after 1, 2, 3,4, 5, 6 and 7 days incubation was observed through sections stained using acridine orange and estimated to quantitative analysis using radioisotope. Results : There was statistical significance in cell numbers between smooth and rough surfaces(p<0.05). Higher numbers of cells were observed on rough surfaces. There was statistical significance in adherent cell numbers into smooth and rough surfaces individually(p<0.05). According to the increase of incubation periods, the cells penetrated into denture soft lining materials were shown to increase. The differences among all kinds of soft liner were statistically significant(p<0.05),and the largest number of cells penetrated into soft liners was observed in the Coe-soft$^{(R)}$. Conclusion : Initial adherence and penetration of yeast into denture soft lining materials has been influenced by surface roughness and chemical composition of them. The selection of appropriate materials and their fabrication may promote clinical performance.

선형 및 스타형 폴리락트산 입체블록 공중합체의 합성 및 물성 (Synthesis and Characterization of Linear and Star-shaped Poly(lactic acid) Stereo-block Copolymers)

  • 이선영;김지흥
    • 폴리머
    • /
    • 제24권5호
    • /
    • pp.638-645
    • /
    • 2000
  • 디올 또는 다가 알콜의 존재 하에서 DL-락트산 및 L-락티드를 연속 중합하여 선형 (ABA 형)과 스타형 ((AB)$_{n}$ 형)의 폴리락트산 입체블록 공중합체를 합성하고 분석하였다. 알콜의 함량에 따라 블록 공중합체의 분자량을 어느 정도 범위에서 조절할 수 있었으며, 합성된 중합체는 비교적 좁은 분자량 분포를 나타내었다. 폴리락트산 입체블록 공중합체의 유리전이온도는 5$0^{\circ}C$ 부근이었으며, 융점은 구조와 분자량에 따라 100~14$0^{\circ}C$ 범위에서 관찰되었다. 용융 엔탈피로부터 얻은 결정화도의 측정 결과로부터 블록구조를 갖는 공중합체는 D-입체이성질체 단량체의 높은 조성(~35%)에서도 결정화가 충분히 일어남을 확인하였는데 이는 유사한 조성의 랜덤 공중합체의 성질과 대비된다. 선형과 스타형 블록 공중합체의 경우 모두 열처리 온도와 시간에 따른 결정화도의 변화를 관찰하였다.다.

  • PDF

Doped Sol-gel TiO2 Films for Biological Applications

  • Gartner, M.;Trapalis, C.;Todorova, N.;Giannakopoulou, T.;Dobrescu, G.;Anastasescu, M.;Osiceanu, P.;Ghita, A.;Enache, M.;Dumitru, L.;Stoica, T.;Zaharescu, M.;Bae, J.Y.;Suh, S.H.
    • Bulletin of the Korean Chemical Society
    • /
    • 제29권5호
    • /
    • pp.1038-1042
    • /
    • 2008
  • Mono and multilayer TiO2(Fe, $PEG_{600}$) films were deposited by the dip-coating on $SiO_2$/glass substrate using sol-gel method. In an attempt to improve the antibacterial properties of doped $TiO_2$ films, the influence of the iron oxides and polyethilenglycol ($PEG_{600}$) on the morphological, optical, surface chemical composition and biological properties of nanostructured layers was studied. Complementary measurements were performed including Spectroscopic Ellipsometry (SE), Scanning Electron Microscopy (SEM) coupled with the fractal analysis, X-Ray Photoelectron Spectroscopy (XPS) and antibacterial tests. It was found that different concentrations of Fe and $PEG_{600}$ added to coating solution strongly influence the porosity and morphology at nanometric scale related to fractal behaviour and the elemental and chemical states of the surfaces as well. The thermal treatment under oxidative atmosphere leads to films densification and oxides phase stabilization. The antibacterial activity of coatings against Escherichia Coli bacteria was examined by specific antibacterial tests.

실란 변성아크릴수지의 합성과 고내후성 실리콘/아크릴수지 도료의 도막물성 (Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings)

  • 박홍수;홍석영;김송형;유규열;안성환;함현식;김성길
    • 한국응용과학기술학회지
    • /
    • 제24권1호
    • /
    • pp.10-22
    • /
    • 2007
  • To prepare weather-resistant silicone/acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by a radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The compositions of monomers were adjusted to fix the glass transition temperature of acrylic polymer for $20^{\circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects for weatherability were examined. The presence of MPTS in silicone/acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the silicone/acrylic resins containing 30 wt% of MPTS had weather-resistant properties.

Synthesis of IZTO(Indium Zinc Tin Oxide) particle by spray pyrolysis and post-heat treatment and characterization of deposited IZTO film

  • Lim, Seong Taek;Kim, Sang Hern
    • 한국응용과학기술학회지
    • /
    • 제33권4호
    • /
    • pp.734-740
    • /
    • 2016
  • The micron-sized indium zinc tin oxide (IZTO) particles were prepared by spray pyrolysis from aqueous precursor solution for indium, zinc, and tin and organic additives such as citric acid (CA) and ethylene glycol (EG) were added to aqueous precursor solution for indium, zinc, and tin. The obtained IZTO particles prepared by spray pyrolysis from the aqueous solution without organic additives had spherical and filled morphologies, whereas the IZTO particles obtained with organic additives had more hollow and porous morphologies. The micron-sized IZTO particles with organic additives were changed fully to nano-sized IZTO particles, whereas the micron-sized IZTO particles without organic additives were not changed fully to nano-sized IZTO particle after post-treatment at $700^{\circ}C$ for 2 hours and wet-ball milling for 24 hours. Surface resistances of micron-sized IZTO's before post-heat treatment and wet-ball milling were much higher than those of nano-sized IZTO's after post-heat treatment and wet-ball milling. From IZTO with composition of 80 wt. % $In_2O_3$, 10 wt. % ZnO, and 10 wt. % $SnO_2$ which showed a smallest surface resistance IZTO after post-heat treatment and wet-ball milling, thin films were deposited on glass substrates by pulsed DC magnetron sputtering, and the electrical and optical properties were investigated.

아크릴계 공중합체에서 이소보닐 메타크릴레이트의 함량에 의한 물리적 특성 변화 (The Effects of the Content of Isobornyl Methacrylate in Acrylate Copolymers on Physical Properties)

  • 김기상;심상연
    • 한국응용과학기술학회지
    • /
    • 제33권4호
    • /
    • pp.771-776
    • /
    • 2016
  • 내열, 코팅 및 접착특성이 우수한 아크릴계 공중합체를 설계, 제조하였다. 공중합체용 모노머로 methyl methacrylate(MMA), isobornyl methacrylate(IBMA) 그리고 2-hydroxyethyl methacrylate(HEMA)를 사용하여 괴상 중합 및 유화 중합으로 반응하여 > 95%이상 고수율로 중합체를 제조하였다. $^1H$-NMR로 화학구조를 확인하였고 DSC, DMA, TGA분석으로 내열성을 확인한 결과 유리전이온도가 $123^{\circ}C$이상 $140^{\circ}C$까지 높게 나타났다. 또한, IBMA성분이 증가함에 따라 저장 탄성율, 열분해온도 모두 증가하였다. 인장강도는 IBMA의 함량이 전체 모노머 조성물중 10%에서 30%로 증가함에 따라 괴상 및 유화 중합체 모두에서 22에서 30 MPa로 강도가 증가하였으며 IBMA의 소수성 특성으로 접촉각은 70도에서 88도까지 증가함을 확인하였다.