• Title/Summary/Keyword: glass behavior

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Carbon Nanotube/Nafion Composites for Biomimetic Artificial Muscle Actuators

  • Lee, Se-Jong;Yoon, Hyun-Woo;Lee, Deuk-Yong
    • Journal of the Korean Ceramic Society
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    • v.44 no.4 s.299
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    • pp.198-201
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    • 2007
  • Multi-walled carbon nanotube (M-CNT)/Nafion nanocomposites were prepared by solution casting to elucidate the effect of M-CNT addition, from 0 to 7 wt%, on the viscoelastic behavior of the composites. The M-CNT bundles induced by the Nafion polymer were determined to be uniformly distributed for the 1 wt% M-CNT/Nafion nanocomposites. The 1 wt% M-CNT/Nafion composite exhibited the highest blocking stress of 2.3 kPa due to its high elastic modulus of 0.485 GPa. From a dynamic mechanical analysis, the 1 wt% M-CNT had the highest storage and loss moduli compared with the other samples in all frequency and temperature ranges. From the storage modulus data, the M-CNT loaded composites had similar $T_g$ values near $120^{\circ}C$. The glass transition temperatures of the M-CNT loaded composites were $120^{\circ}C$ (1 wt%), $117^{\circ}C$ (3 wt%), $117^{\circ}C$ (5 wt%), and $135^{\circ}C$ (7 wt%), suggesting that the effect of the M-CNTs on the Nafion film begins at 1 wt%. Thus, it has been concluded that the 1 wt% M-CNT disported composite is attractive for actuator applications.

Clinical Experiment Results of Cerec Inlab using Vita9 (VITA VM9 Zirconia powder를 이용한 Cerec inlab의 임상증례에 관하여)

  • Jung, Hyo-Kyung;kim, Jeong-Sook;Lee, Jong-Do
    • Journal of Technologic Dentistry
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    • v.29 no.2
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    • pp.119-128
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    • 2007
  • Although there are many different ways that restorations can be made, it can be said that the biocompatibility of abutment and crown is very important in this experiment. When placed in the actual oral cavity, the differences were obvious. Compared to In-ceram Aluminium, the structure that is obtained after firing reveals a particularly homogeneous distribution of the crystal and glass phase. The In-ceram aluminium system had many problems, such as having weak tensile strength, and having low bonding strength due to the shrinking that occurs after firing. Because of the opaque finish of the metal frame, the two may look similar from the outside, but it is evident that there are differences between using a metal frame and In-ceram. VITA VM9 has been designed as a special ceramic featuring a fine structure or stabilized Zro2 substructures, and so the VITA VM9 excels in its light refraction and reflection behavior, which is similar to natural teeth. It also has outstanding chemical balance, which presents advantages such as considerably reduced accumulation of plaque on the ceramic surface.? This ultimately results in easier care and cleaning for the patient.

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Experimental study on durability of strengthened corroded RC columns with FRP sheets in tidal zone of marine environment

  • Kashi, Amin;Ramezanianpour, Ali Akbar;Moodi, Faramarz
    • Computers and Concrete
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    • v.19 no.4
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    • pp.339-346
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    • 2017
  • The main objective of this paper was to illuminate the effect of marine environmental condition on durability of reinforced concrete (RC)-corroded columns strengthened with carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) layers. Small-scale columns were prepared and corroded by an accelerated corrosion process. After strengthening, compressive strength tests were carried out on control and weathered specimens. In this research, a marine simulator was designed and constructed similar to the tidal zone of marine environment in south of Iran which was selected as a case study in this research. Mechanical properties of wrapped specimens were studied after placing them inside the simulator for 3000 hours. Marine environment decreased ultimate strength by 4.5% and 26.3% in CFRP and GFRP-wrapped columns, respectively. In some corroded-columns, strengthening was carried out after replacing damaged cover by self-compacted mortar. In this method, by confining with one layer of CFRP and GFRP, 4.2% and 22.4% reduction in ultimate strength was observed, respectively, after exposure. Furthermore, the elastic-brittle behavior has been verified in this retrofit method. Also results of tension tests revealed, the ultimate tensile strength was degraded by 2% and 28.8% in CFRP and GFRP sheets, respectively, after applying marine exposure.

NH3 Sensing Properties of SnO Thin Film Deposited by RF Magnetron Sputtering

  • Vu, Xuan Hien;Lee, Joon-Hyung;Kim, Jeong-Joo;Heo, Young-Woo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.272-272
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    • 2014
  • SnO thin films, 100 nm in thickness, were deposited on glass substrates by RF magnetron sputtering. A stack structure of $SnO_2/SnO$, where few nanometers of $SnO_2$ were determined on the SnO thin film by X-ray photoelectron spectroscopy. In addition, XPS depth profile analysis of the pristine and heat treated thin films were introduced. The electrical behavior of the as-sputtered films during the annealing was recorded to investigate the working conditions for the SnO sensor. Subsequently, The NH3 sensing properties of the SnO sensor at operating temperature of $50-200^{\circ}C$ were examined, in which the p-type semiconducting sensing properties of the thin film were noted. The sensor shows good sensitivity and repeatability to $NH_3$ vapor. The sensor properties toward several gases like $H_2S$, $CH_4$ and $C_3H_8$ were also introduced. Finally, a sensing mechanism was proposed and discussed.

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Urea Diffusional Characteristics of Film from Dispersion Based on Poly(ethylene-co-acrylic acid) (Poly(ethylene-co-acrylic acid)의 분산입자 제조와 그 필름의 요소 투과특성)

  • Yu, Dong-Guk;An, Jeong-Ho
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.90-97
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    • 2001
  • Dispersions are prepared from poly(ethylene-co-acrylic acid) (PEAA) ionomer with two different counter-ions, ammonium and sodium. The diffusional characteristic of urea aqueous solution are measured for the films prepared from the above mentioned dispersions. It is attempted to find the relationship between diffusional behavior and various chemical and physical characteristics of films. DSC is employed to characterize glass transition temperature and degree of crystallinity and the structural features of crystal phase and ionic clusters are examined by WAXD and FTIR. The diffusional characteristics of ionomer is found to be dependent on various parameters such as the size of initial dispersion as well as the kind of counter ion and the degree of neutralization.

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The Fabrication and Properties of Lead-tree Transparent Dielectric Thick Films for PDP (PDP 무연 투명유전체 후막의 형성 및 특성)

  • Heo, Sung-Cheol;Choi, Duck-Kyun;Oh, Young-Jei
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.10
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    • pp.1107-1113
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    • 2004
  • Dry film method for large size of PDP(Plasma Display Panel) module has been actively investigated. This method for lead-free transparent dielectric formation depends on green sheet technology. By adjusting the composition of transparent dielectric powders and organics, uniformly dispersed slurry was fabricated, Viscosity of the slurry exhibited pseudoplastic behavior for tape casting, Cast green sheets were tested under tensile condition at room temperature. It was found that the increase in transparent dielectric powder and binder ratio leads to decrease in strain to failure of green sheets from 120 % to 34 % and from 255 % to 4 %, respectively. Tensile strength of green sheets decreased abruptly with increase of transparent dielectric powder ratio, with minimum at 0.13 MPa. On the other hand, tensile strength increased continuously from 0.1 MPa to 2.4 MPa with increase of binder ratio. The green sheets were attached on the glass substrate and heated by following firing schedule. As a result, the best result was obtained when fired at 580 $^{\circ}C$ for 15 min and had transmittance of 78 % in visible range 550 nm.

Flux pinning and critical current density in $TiO_2$-doped $MgB_2$ superconductor

  • Gang, Ji-Hun;Park, Jeong-Su;Park, Jin-U;Lee, Yeong-Baek;Prokhorov, V.G.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.172-172
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    • 2010
  • $MgB_2$ doped with $TiO_2$ was prepared by the in-situ solid state reaction to study the effects of $TiO_2$ dopant on the flux pinning behavior of $MgB_2$ superconductor. From the field-cooled and the zero-field-cooled temperature dependences of magnetization, the realms of vortex-glass and vortex-liquid states of $TiO_2$-doped $MgB_2$ were determined in the H-T diagram (the temperature dependence of upper critical magnetic field and irreversibility line). The critical current density was estimated from the width of hysteresis loops in the framework of Beam's model at different temperatures. The results indicate that nano-scale $TiO_2$ inclusions play a role of the effective pinning centers and lead to the enhanced upper critical field and critical current density. It is suggested that the grain-boundary pinning mechanism is realized in $TiO_2$-doped $MgB_2$ superconductor.

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The Effect of P and Mo for Thermal and Chemical Properties of Fe-PC-B-Al-Mo Amorphous Alloys (Fe-P-C-B-Al-Mo계 비정질합금의 열적.화학적 성질에 미치는 P 및 Mo의 영향)

  • Gook, Jin-Seon;Chon, Woo-Young
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.2
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    • pp.76-81
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    • 2002
  • The melt-spun amorphous $Fe_{77-X}P_{13}C_4B_4Al_2Mo_X$(x=4~10) and $Fe_{82-X}P_XC_4B_4Al_2Mo_8$(x=9~15) alloys were found to exhibit a large supercooled liquid region(${\Delta}T_x$) exceeding 40 K before crystallization. The largest ${\Delta}T_x$ for the glassy alloys containing Mo reaches as large as 65 K for the $Fe_{69}P_{13}C_4B_4Al_2Mo_8$ alloy. The corrosion behavior of the amorphous $Fe_{77-X}P_{13}C_4B_4Al_2Mo_X$(x=4~15) and $Fe_(82-X)P_XC_4B_4Al_2Mo_8$ (x=9~17) alloys were examined by electrochemical measurements in 9M $H_2SO_4$ solution at 303 K. The addition of Mo(or P) for replacing some portion of Fe is effective in improving the corrosion resistance of the investigated Fe-based glassy alloys. They are spontaneously passivated and have a wide passive region with low passive current density.

An Experimental Study on the Flexural Fatigue Behavior of Glass fiber Reinforced Plastec Pipes (유리섬유 보강 플라스틱관의 휨 피로 거동에 관한 실험적 연구)

  • Jang, Dong-Il;Go, Jae-Won
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.219-226
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    • 1994
  • In the comparison result of residual strain calculated from the load-strain curve under the repeated loading cycles, it was found that the larger the laminates is, the larger the stiffness of GFRP pipes under fatigue load is. This phenomenon is true until the fatigue failure. According to the S-N curves drawn by the regression analysis on the fatigue test results, the fatigue strength for percentage of the static ultimate strength increases by increasing the laminates of GFRP pipes. The fatigue strength for 2, 000, 000 repeated loading cycles In GFRP pipes with the laminates varing 15, 25, 35 shows 75.2%, 79.5%, 84.2% on the static ultimate strength, respectively.

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Deformation Behaviors of Materials during Nanoindentation Test and Simulation by Three-Dimensional Finite Element Analysis (재료의 나노인덴테이션 변형 거동과 3차원 유한요소해석)

  • Kim Ji-soo;Yang Hyeon-yun;Yun Jon-do;Cho Sang-bong
    • Korean Journal of Materials Research
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    • v.14 no.6
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    • pp.436-442
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    • 2004
  • Elastic and plastic deformation behaviors of the high purity aluminum and the silica glass were studied using nanoindentation and finite element analysis(FEA) techniques. Berkovich- and cone-type indenters were used for the nanoindentation test. Deformation behaviors and nanoindent profiles of elastic, elastic-plastic or plastic materials were clearly visualized by FEA simulation. Effects of the penetration depth and strain hardening on the deformation behavior were examined. Pile-up and sink-in behaviors were studied by using FEA technique. Degree of pile-up or sink-in was found to be a function of the ratio of elastic modulus to yield strength of materials. FEA was found to be an effective method to study deformation behaviors of materials under nanoindentation, especially in the case when pile-up or sink-in phenomena occurred.