• Title/Summary/Keyword: geoscience and mineral resources technology

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The Effect of Mercaptoundecanoic Acid (MUA) Coating on Dispersion Property of Au Nanoparticles in Synthesis of Au/TiO2 Core-shell Nanoparticles (Au/TiO2 core-shell 나노입자의 합성에 있어서 Au 나노입자의 분산특성에 미치는 Mercaptoundecanoic acid (MUA)의 피복 효과)

  • Yu, Yeon-Tae;Kim, Byoung-Gyu
    • Korean Journal of Materials Research
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    • v.16 no.12
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    • pp.754-760
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    • 2006
  • Mercaptoundecanoic acid (MUA) has been used to enhance the dispersity of Au nanoparticles in organic solvent and the affinity between the Au nanoparticles surface and titanium dioxide shell in the synthesis of $Au/TiO_2$ core-shell composite nanoparticles. The dispersity of the MUA-coated Au nanoparticles in ethanol aqueous solution with different concentration of $H_2O$ was investigated by UV-Vis. absorption spectrum and the coating amount of MUA was varied from 0.02 mM to 1.0 mM. The MUA-coated Au nanoparticles were highly dispersed in pure $H_2O$ in the wide range of the coating amount of MUA. On the contrary, the MUAcoated Au nanoparticles showed an enhanced stability in the ethanol/$H_2O$=8/2 mixed solution only when the coating amount of MUA was 0.05 mM, and in the ethanol/$H_2O$=7/3 mixed solution when the coating amount of MUA was in the range from 0.02 mM to 0.17 mM. From this systematic study, it can be inferred that the stability and the dispersibility of Au nanoparticles in organic solvents are highly sensitive towards the amount of MUA coating.

Background Reduction for the ${\gamma}$-Ray Spectrometry of Environmental Radioactivity (환경방사능의 감마선 분광분석을 위한 백그라운드 소멸)

  • Seo, Bum Kyoung;Lee, Kil Yong;Yoon, Yoon Yeol;Lee, Dae Won
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.212-220
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    • 2001
  • This study was performed to establish the analytical method of radium and radon in various environmental samples with the ${\gamma}$-ray spectrometry. The major problem in the measurements of low level ${\gamma}$-ray, such as environmental radioactivity, is the fluctuation of ${\gamma}$-ray background spectrum. To overcome this problem, a nitrogen gas was filled up in the detector chamber to reduce the background counts due to airborne radioactivities, i.e., $^{214}Pb$ and $^{214}Bi$, the daughters of $^{222}Rn$ in air. When nitrogen gas flowed around the detector, peak counts of ${\gamma}$-rays from the daughters of $^{222}Rn$ decreased about 80% below 1 MeV and about 20~50% above 1 MeV. The use of nitrogen purging results in approximately tenfold increment of sensitivity.

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A Random Walk Model for Estimating Debris Flow Damage Range (랜덤워크 모델을 이용한 토석류 산사태 피해범위 산정기법 제안)

  • Young-Suk Song;Min-Sun Lee
    • The Journal of Engineering Geology
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    • v.33 no.1
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    • pp.201-211
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    • 2023
  • This study investigated the damage range of the debris flow to predict the amount of collapsed soil in a landslide event. The height of the collapsed slope and the distance traveled by the collapsed soil were used to predict the total trajectory distance using a random walk model. Debris flow trajectory probabilities were calculated through 10,000 Monte Carlo simulations and were used to calculate the damage range as measured from the landslide scar to its toe. Compiled information on debris flows that occurred in the Cheonwangbong area of Mt. Jirisan was used to test the accuracy of the proposed random walk model in estimating the damage range of debris flow. Results of the comparison reveal that the proposed model shows reasonable accuracy in estimating the damage range of debris flow and that using 10 m × 10 m cells allows the damage range to be reproduced with satisfactory precision.

Determination of L-Alanine Using Silver Nanoparticles Chemiluminescence System (은 나노입자를 이용한 화학발광법에 의한 L-alanine의 정량)

  • Jo, Hae Jin;Jang, Taek Gyun;Choi, Jong Ha;Suh, Jung Kee;Jeon, Chi Wan;Kim, Young Ho;Lee, Sang Hak
    • Applied Chemistry
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    • v.15 no.1
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    • pp.37-40
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    • 2011
  • A chemiluminescent method with silver nanoparticles for determination of L-alanine has been presented. The chemilumiscence intensity was further enhanced by silver nanoparticles in the luminol system by its catalytic role. The silver nanoparticles enhanced chemiluminescent method is applicable for the determination of an amino acid such as alanine. When alanine was introduced to the luminol system with silver nanoparticles, chemiluminescence intensity was reduced with the concentration of the added alanine. The effects of pH, concentrations of luminol, hydrogen peroxide and silver nanoparticles on the chemiluminescence intensity were investigated. The calibration curve for L-alanine was linear over the range from 6.60×10-8 M to 4.00×10-7 M, coefficient of correlation was 0.996 and detection limit was 3.5×10-9 M under the optimal conditions of 4.0×10-3 M, 4.0×10-2 M, 4.0×10-4 M, 12.8 for the concentration of luminol, H2O2, silver nanoparticles and pH, respectively.

Utilization of Mean Shear Wave Velocity to a Depth Shallower than 30m for Efficient Seismic Site Classification in Korea (우리나라 지진공학적 지반 분류를 위한 30m 미만 심도 평균 전단파 속도의 활용)

  • Sun, Chang-Guk;Chung, Choong-Ki;Kim, Dong-Soo
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.562-571
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    • 2006
  • Mean shear wave velocity of the upper 30m $(V_s30)$ used as the current site classification criterion for determining seismic design ground motions in Korea was established based on the typical depth of site investigations in western US, in which the depth to bedrock is much deeper than that in Korea. In this study, to establish appropriate site classification system for site conditions of Korea, site investigations including in-situ seismic tests to determine shear wave velocity $(V_s)$ were carried out at total 72 sites in Korean peninsula. The mean $V_s's$ to the depths of 5m, 10m, 15m, 20m and 25m together with the $V_s30$ at the testing sites were determined, and the correlation between the mean $V_s$ to a depth shallower than 30m and the $V_s30$ was drawn and suggested for the efficient seismic site classification in Korea. The proposed correlation could be utilized for the seismic design in case of the $V_s$ profiles shallower than 30 m in depth. The correlation in this study, nevertheless, requires further modification by means of the accumulation of various site data in Korea.

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Recovery of Silicon from Silicon Sludge by Electrolysis (실리콘 슬러지로부터 실리콘의 전해회수(電解回收))

  • Park, Jesik;Jang, Hee Dong;Lee, Churl Kyoung
    • Resources Recycling
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    • v.21 no.5
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    • pp.31-37
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    • 2012
  • As a recovery of elemental silicon from the sludge of Si wafer process, a process of mechanical separation-chlorine roasting-electrolysis has been suggested. The silicon sludge consisted of Si, SiC, machine oil, and metallic impurities. The oil and metal impurities was removed by mechanical separation. The Si-SiC mixture was converted to silicon chloride by chlorine roasting at $1000^{\circ}C$ for 1 hr and the silicon chloride was dissolved into an ionic liquid of $[Bmpy]Tf_2N$ as an electrolyte. Cyclic voltammetry results showed an wide voltage window of pure $[Bmpy]Tf_2N$ and a reduction peak of elemental Si from $[Bmpy]Tf_2N$ dissolved $SiCl_4$ on Au electrode, respectively. The silicon deposits could be prepared on the Au electrode by the potentiostatic electrolysis of -1.9 V vs. Pt-QRE. The elemental silicon uniformly electrodeposited was confirmed by various analytical techniques including XRD, FE-SEM with EDS, and XPS. Any impurity was not detected except trace oxygen contaminated during handling for analysis.

Estimation of surficial sediment thickness using mid-frequency ocean acoustic bottom reflected signals measured in shallow water off Geoje island (거제 인근해역에서 측정된 중주파수 음향 해저면 반사 신호를 이용한 표층 해저면 두께 추정)

  • Kwon, Hyuckjong;Choi, Jee Woong;Son, Su-Uk;Cho, Sungho;Hahn, Jooyoung;park, Joung-Soo;Park, Kyeongju
    • The Journal of the Acoustical Society of Korea
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    • v.35 no.6
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    • pp.419-426
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    • 2016
  • Measurements of bottom loss as a function of grazing angle (in range of $9{\sim}14^{\circ}$) at a frequency range of 4 ~ 8 kHz were conducted on an experimental site off Geoje island in October 2015. Geoacoustic inversion of the surficial sediment thickness is performed using the arrival time difference between the surficial layer and the sub-bottom layer reflected signal. To invert the thickness of surficial sediment, we used the grain size of $8{\sim}10{\phi}$ obtained by KIGAM (Korea Institute of Geoscience and Mineral Resources). The thickness of the surficial sediment was estimated to be 4 ~ 7 m. Finally, this inversion result was compared with the geoacoustic observation conducted by the KIOST (Korea Institute of Ocean Science & Technology) using sub-bottom profiler.

Review of China's National Earthquake Governance and Role-Sharing (중국 국가 지진 거버넌스 및 역할분담 고찰)

  • Kim, Seong-Yong
    • Economic and Environmental Geology
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    • v.54 no.1
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    • pp.127-136
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    • 2021
  • This study was carried out to understand China's earthquake governance and role-sharing, and to strategically use it for research cooperation in related fields with China. The characteristics of China's national earthquake governance and role-sharing are detailed in this study. First, unlike Korea, China's geoscience and earthquake research fields are separate, and are clearly distinguished from other fields of science and technology. They hold a higher status compared to other fields in China. Second, China's provincial earthquake agencies simultaneously carry out related tasks under the dual supervisory management system of the central and provincial governments. Third, the China Earthquake Administration (CEA) has the authority to do research and development, manpower training, and degree conferment, which are centered on directly affiliated institutions. Fourth, China carries out similar functions in directly affiliated institutions of the CEA and the China Geological Survey (CGS), and affiliated institutions of the Chinese Academy of Sciences (CAS), respectively. Fifth, the CEA is continuously expanding the seismic observation network that connects the vast land of the country. Sixth, China is considered to have detailed structures of earthquake-related laws and regulations. Given China's earthquake governance and role-sharing, it is considered that the possibility of success in research cooperation is high if Korea first determines whether it is under the jurisdiction of the CGS, CEA, and CAS, depending on the specific field.

The Effects of a Teacher Training Program for Elementary and Middle School Teachers: Focusing on International School for Geoscience Resources (초·중등 교원연수 프로그램의 효과 분석: 국제지질자원인재개발센터를 중심으로)

  • Lee, Yun Su;Kim, Hyoungbum
    • Journal of the Korean Society of Earth Science Education
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    • v.12 no.1
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    • pp.82-93
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    • 2019
  • The purpose of this study is to analyze the results of satisfaction for learning eco-system on the teacher training program conducted at the IS-Geo (International School for Geoscience Resources) which is KIGAM (Korea Institute of Geoscience and Mineral Resources), and to determine the satisfaction and educational effects of the teacher training programs on elementary and secondary teachers. And then, to suggest improvement points in the future operation of the teacher training program at the IS-Geo. Therefore, we conducted questionnaire of satisfaction for learning eco-system based on the data collected by a survey of 98 elementary and secondary teachers who participated in the teacher training program at the IS-Geo, from July 2017 to August 2018. The research results are as follows. First, the results of satisfaction for learning eco-system showed high values of 4.58 or higher in both the elementary and secondary programs, and the teacher training program conducted by the IS-Geo had a positive effect on the training participants. Second, internal factors indicating learning motivation and learning development were elementary teacher training 4.70 and secondary teacher training 4.64, and it is necessary to develop training contents and programs by classifying them into majors other than the earth science department. Third, intermediate factors indicating contents of education and learning curriculum were 4.67 for an elementary teacher training program and 4.72 for secondary teacher training program. In addition, in order to operate the teacher training program according to the purpose of science and technology culture, it is necessary to develop a teaching-learning model and to improve the quality of teaching. Fourth, external factors indicating learner support and quality of instructors were 4.83 for an elementary teacher training program and 4.72 for a secondary teacher training program. In particular, it is necessary to develop teaching materials that can be used immediately in school classes and can generate interest.

Effect of Foaming Agent Content on the Apparent Density and Compressive Strength of Lightweight Geopolymers (발포제 함량에 따른 경량 다공성 지오폴리머의 밀도와 강도 특성)

  • Lee, Sujeong;An, Eung-Mo;Cho, Young-Hoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.363-370
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    • 2016
  • Lightweight geopolymers are more readily produced and give higher fire resistant performance than foam cement concrete. Lowering the density of solid geopolymers can be achieved by inducing chemical reactions that entrain gases to foam the geopolymer structure. This paper reports on the effects of adding different concentrations of aluminum powder on the properties of cellular structured geopolymers. The apparent density of lightweight geopolymers has a range from 0.7 to $1.2g/m^3$ with 0.025, 0.05 and 0.10 wt% of a foaming agent concentration, which corresponds to about 37~60 % of the apparent density, $1.96g/cm^3$, of solid geopolymers. The compressive strength of cellular structured geopolymers decreased to 6~18 % of the compressive strength, 45 MPa of solid geopolymers. The microstructure of geopolymers gel was equivalent for both solid and cellular structured geopolymers. The workability of geopolymers with polyprophylene fibers needs to be improved as in fiber-reinforced cement concrete. The lightweight geopolymers could be used as indoor wall tile or board due to fire resistance and incombustibility of geopolymers.