• Journal of the Korean GEO-environmental Society
• /
• v.6 no.1
• /
• pp.63-72
• /
• 2005

From the geological and engineering point of view, the limestone is so rigid that it is able to act as a bedrock but if there are some unstable elements which are solubility cavity and cracking zone in the ground, the settlement and bearing capacity of a structure will be required to long-term stability investigations and countermeasures about those problems. When comparing the allowable bearing capacity, the results of Bell's method and the Bowles' method are similar but the results of Hoek-Brown's method are very larger than the others. For weathered limestone, stability is changed by size and depth of the cavity of limestone, but soft and hard rock are stable regardless of size and depth of the cavity.

• Economic and Environmental Geology
• /
• v.38 no.6 s.175
• /
• pp.663-673
• /
• 2005

This study investigates the relationship between the geochemical maps and the gold-silver deposit locations. Geochemical maps of 21 elements, which are published by KIGAM, locations of gold-silver deposits, and 1:1,000,000 scale geological map of Korea are utilized far this investigation. Pixel size of the basic geochemical maps is 250m and these data are resampled in 1km spacing for the statistical analyses. Relationship between the mine location and the geochemical data are investigated using bayesian statistics and decision tree algorithms. For the bayesian statistics, each geochemical maps are reclassified by percentile divisions which divides the data by 5, 25, 50, 75, 95, and $100\%$ data groups. Number of mine locations in these divisions are counted and the probabilities are calculated. Posterior probabilities of each pixel are calculated using the probability of 21 geochemical maps and the geological map. A prediction map of the mining locations is made by plotting the posterior probability. The input parameters for the decision tree construction are 21 geochemical elements and lithology, and the output parameters are 5 types of mines (Ag/Au, Cu, Fe, Pb/Zn, W) and absence of the mine. The locations for the absence of the mine are selected by resampling the overall area by 1 km spacing and eliminating my resampled points, which is in 750m distance from mine locations. A prediction map of each mine area is produced by applying the decision tree to every pixels. The prediction by Bayesian method is slightly better than the decision tree. However both prediction maps show reasonable match with the input mine locations. We interpret that such match indicate the rules produced by both methods are reasonable and therefore the geochemical data has strong relations with the mine locations. This implies that the geochemical rules could be used as background values oi mine locations, therefore could be used for evaluation of mine contamination. Bayesian statistics indicated that the probability of Au/Ag deposit increases as CaO, Cu, MgO, MnO, Pb and Li increases, and Zr decreases.

• Economic and Environmental Geology
• /
• v.40 no.4
• /
• pp.361-374
• /
• 2007

Rare earth elements(REEs) have been used as an useful tool in understanding the various geological processes such as evolution and differentiation in the crust. The REEs also have been used as an analog of actinides for radioactive wastes at the water-rock interactions. Using physicochemical properties of the REEs and actinides, we have shown that Eu is an optimum analogue for understanding the behavior of Am in subsurface environments. Factors affecting sorption behavior of radioactive nuclides in groundwater were investigated by batch experiments. Four nuclides such as $^{241}Am,\;^{152}Eu,\;^{160}Tb\;and\;^{60}Co$ were selected to test our hypothesis, and $^{160}Tb$ and $^{60}Co$ were specifically used to compare to the sorption behavior between $^{241}Am-^{152}Eu$ and other radioactive nuclides. Four different rock samples and one groundwater were used in the batch experiments where solution pH for all experiments was fixed at 5.5. Our results demonstrate that $^{241}Am,\;^{152}Eu,\;and\;^{160}Tb$ show similar sorption behavior whereas $^{60}Co$ is different in sorption behavior at the mineral-water interface, suggesting that the sorption behavior of $^{60}Co$ is affected by different rock types. Our results also show that 1) Eu in REEs is optimum analogue of fate and transport of Am in subsurface environments, and 2) mineral compositions such as $SiO_2,\;TiO_2,\;P_2O_5$ and distribution of REEs such as Eu anomaly play key roles in affecting sorption behavior of radioactive nuclides even though physicochemical properties of geological materials such as specific surface area and cation exchange capacity can not be ruled out.

• The Journal of the Petrological Society of Korea
• /
• v.21 no.3
• /
• pp.287-307
• /
• 2012

The study area, which is located in the southeastern part of the Jirisan province of the Yeongnam massif, Korea, consists mainly of the Precambrian Hadong northern anorthosite complex (HNAC) and the Jirisan metamorphic rock complex (JMRC) and the Mesozoic granitoids which intrude them. Its tectonic frame is built into NS trend, unlike the general NE-trending tectonic frame of Korean Peninsula. This paper researched the structural characteristics at each deformation phase to clarify the geological structures associated with the NS-trending tectonic frame which was built in the HNAC and JMRC. The result indicates that the geological structures of this area were formed at least through three phases of deformation. (1) The $D_1$ deformation formed the $F_1$ sheath or "A"-type folds in the HNAC and JMRC, and the $S_{0-1}$ composite foliation and the $S_1$ foliation and the $D_1$ ductile shear zone which are (sub)parallel to the axial plane of $F_1$ fold, and the $L_1$ stretching lineation which is parallel to the $F_1$ fold axis owing to the large-scale top-to-the SE shearing on the $S_0$ foliation. (2) The $D_2$ deformation (re)folded the $D_1$ structural elements under the EW-trending tectonic compression environment, and formed the NS-trending $F_2$ open, tight, isoclinal, intrafolial folds with the $S_{0-1-2}$ composite foliation and the $S_2$ foliation and the $D_2$ ductile shear zone with S-C-C' structure and the $L_2$ stretching lineation which is (sub)parallel to the axial plane of $F_2$ fold. The extensive $D_2$ ductile shear zone (Hadong shear zone) of NS trend was persistently developed along the eastern boundary of HNAC and JMRC which would be to the limb of $F_2$ fold on a geological map scale. The Hadong shear zone is no less than 1.4 km width, and was formed in the mylonitization process which produced the mylonitic structure and the stretching lineation with the reduction of grain size during the $F_2$ passive folding. (3) The $D_3$ deformation formed the EW-trending $F_3$ kink or open fold under the NS-trending tectonic compression environment and partially rearranged the NS-trending pre-$D_3$ structural elements into (E)NE or (W)NW direction. The regional trend of $D_1$ tectonic frame before the $D_2$ deformation would be NE-SW unlike the present, and the NS-trending tectonic frame in the HNAC and JMRC like the present was formed by the rearrangement of the $D_1$ tectonic frame owing to the $F_2$ active and passive folding. Based on the main intrusion age of (N)NE-trending basic dyke in the study area, these three deformation events are interpreted to have occurred before the Late Paleozoic.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.12
• /
• pp.333-338
• /
• 2016

The purpose of this study was to understand the pollution level of the surface sediment of Sihwa Lake by assessing its geochemical characteristics and investigating the spatial distribution of trace metals and organic matter. In the surface sediment of Sihwa lake, the mean grain size was between 2.94 and 6.35 Ø and the main type of sediment was sandy silt. The concentrations of As, Co, Cr, Ni, V and Li among the metal elements in the surface sediment were correlated with the mean crust concentration (p<0.05). Based on the strong correlation between the metals (Cd, Cu, Pb and Zn) and organic matter (Ignition Loss), the concentrations of these metal elements seem to be controlled by the organic matter dilution effect. The trace metal pollution level, determined by applying the Republic of Korea Marine environmental standard and the US National Oceanic and Atmospheric Administration's sediment quality guidelines, showed the pollution level of As to be either close to or in excess of the above-mentioned standards at almost all levels. The enrichment factor and geoaccumulation index of As showed that there was an incremental increase of pollution by elements other than V, Cr, Co, Fe, Al and Mn. Moreover, the nearby industrial area and dike were more polluted than the other areas, so the surface sediments in Sihwa lake should be monitored by taking into consideration the geological variations.

• Economic and Environmental Geology
• /
• v.40 no.1 s.182
• /
• pp.47-66
• /
• 2007

The Sitting Buddha Carved on Rockcliff (National treasure No. 201) in Bukjiri consists of porphyritic biotite granite, which was fractured by three joint sets of NE-SW, EW and NS directions. They produced a physical weathering that broke many parts of the Buddha and background. The chemical index of alteration is 59 to 61 from the major elements in the granite that was weathered into producing kaolin minerals from alteration of feldspars and biotite. With weathering degree, major element compositions increase in $SiO_2$ and MnO, whereas decrease in $TiO_2,\;{Fe_2O_3}^t,\;MgO,\;CaO\;and\;K_2O$. Change proporations of trace elements to $Al_2O_3$ increase in all transition elements, Rb and Y, whereas decrease in Li, Sr and Ba. REE pattern increases only in HREE. Particularly, a decrease in CaO, $K_2O$, Sr and Ba results in what they are effluxed to dissolve from feldspars by groundwater. The Buddha image has been deteriorated into joints, color changes, brown rusts, granular decay, microorganic smears by the such weathering causes as deformation, moisture, temperature variation and microorganic living. The moisture, which leaks along the joints in the granite, not only dissolve to decompose minerals but also grows many microorganism and is frozen over during winter. NE-SW and NS joint sets affect to seep in water during rainy days to deteriorate the image because they extend outward.

• Journal of Conservation Science
• /
• v.30 no.3
• /
• pp.249-261
• /
• 2014

This study aims to examine production technique of white wares from the Guyre-2ri 1st and 2nd kiln sites, Wonju, Gangwon Province and characteristics of the used materials, and to find a correlation among materials of the excavated white wares. X-ray fluorescence sequential spectroscopy(XRF), X-ray diffraction(XRD), Dilatometer and Inductively coupled plasma mass spectrometry(ICP-MS), Inductively coupled plasma automic emission spectrometer(ICP-AES) were applied to determine the chemical composition, crystalline phase of samples, firing temperatures, trace elements and rare earth elements. White wares from the Guyre-2ri kiln sites contained high contents of coloring oxides and fluxes. Though firing temperature of each sample was different, they were mostly fired at a temperature below $1200^{\circ}C$ and some of them experienced a low temperature of $1000^{\circ}C{\pm}20^{\circ}C$ and a high temperature above $1200^{\circ}C$. When analyzing body crystalline phases of the white wares using the XRD method, quartz and mullite were extracted from all the samples, and the proportions were similar to each other. When analyzing the excavated white wares using the Seger formula, also, all the samples showed similar clay sources and production techniques. Moreover, the white wares were made of host rocks of the same geological origin, according to the result of rare earth elements analysis.

• Geosciences Journal
• /
• v.23 no.1
• /
• pp.1-20
• /
• 2019

We present data from the Mesozoic Keumkang, Palbong, and Baekhwa granites in Garorim Bay, in the southwestern part of the Gyeonggi massif, South Korea. Using major and trace element concentrations, Sr-Nd-Pb isotopic compositions, and sensitive high-resolution ion microprobe (SHRIMP) zircon U-Pb ages, we aim to constrain the petrogenesis of the granites and explain their origin within a broader regional geological context. SHRIMP U-Pb zircon ages of $232.8{\pm}3.2$, $175.9{\pm}1.2$, and $176.8{\pm}9.8$ Ma were obtained from the Keumkang, Palbong and Baekhwa granites, respectively. The Late Triassic Keumkang granites belong to the shoshonite series and show an overall enrichment in large ion lithophile elements (LILE), a depletion in high field strength elements (HFSE) relative to primitive mantle, compared with neighboring elements in the primitive mantle-normalized incompatible trace element diagram with notable high Ba and Sr contents, and negligible Eu anomalies. The Keumkang granites are typified by highly radiogenic Sr and unradiogenic Nd and Pb isotopic compositions: $(^{87}Sr/^{86}Sr)_i=0.70931-0.70959$, $(^{143}Nd/^{144}Nd)_i=0.511472-0.511484$ [$({\varepsilon}_{Nd})_i=-17.0$ to -16.7], and $(^{206}Pb/^{204}Pb)=17.26-17.27$. The Middle Jurassic Palbong and Baekhwa granites belong to the medium- to high-K calc-alkaline series, and show LILE enrichment and HFSE depletion similar to the Keumkang granites, but exhibit significant negative anomalies in Ba, Sr, and Eu. Furthermore, they have elevated Y and Yb contents at any given $SiO_2$ content compared with other Jurassic granitoids from the Gyeonggi massif. The Palbong and Baekhwa granites have slightly less radiogenic Sr and more radiogenic Nd and Pb isotopic compositions [$(^{87}Sr/^{86}Sr)_i=0.70396-0.70908$, $(^{143}Nd/^{144}Nd)_i=0.511622-0.511660$, $({\varepsilon}_{Nd})_i=-15.4$ to -14.7, $(^{206}Pb/^{204}Pb)=17.56-17.76$] relative to the Keumkang granites. The Keumkang granites are considered to have formed in a post-collisional environment following the Permo-Triassic Songrim orogeny that records continent-continent collision between the North and South China blocks, and may have formed by fractional crystallization of metasomatized lithospheric mantle-derived mafic melts. The Palbong and Baekhwa granites may have been produced from a gabbroic assemblage at pressures of less than ~15 kbar, associated with subduction of the paleo-Pacific (Izanagi) plate at the Eurasian continental margin. Elevated ${\varepsilon}_{Nd}(t)$ values in the granitoids from the southwestern part of the Gyeonggi massif relative to those of the central and northern parts, together with the comparatively shallow depth of origin, imply the presence of an exotic block in the Korean lithosphere.

• Korean Journal of Mineralogy and Petrology
• /
• v.36 no.3
• /
• pp.199-212
• /
• 2023

Diffusion is a powerful tool to understand geological processes recorded in terrestrial rocks as well as extraterrestrial materials. Since the diffusive exchange of elements or isotopes may have occurred differently in the solar nebula (high temperature and rapid cooling) and on the parent bodies (fluid-assisted thermal metamorphism at relatively low temperature), it is particularly important to model elemental or isotopic diffusion profiles within the mineral grains to better understand the evolution of the early solar system. A numerical model with the finite difference method for the fast grain boundary diffusion was established for the exchange of elements or isotopes between constituent minerals in a closed system. The fast grain boundary diffusion numerical model was applied to 1) ²⁶Mg variation in plagioclase of an amoeboid olivine aggregate (AOA) from a CH chondrite and 2) Fe-Mg interdiffusion between chondrules, AOA, and matrix minerals in a CO chondrite. Equilibrium isotopic fractionation and equilibrium partitioning were also included in the numerical model, based on the assumption that equilibrium can be reached at the interfaces of mineral crystals. The numerical model showed that diffusion profiles observed in chondrite samples likely resulted from the diffusive exchange of elements or isotopes between the constituent minerals. This study also showed that the closure temperature is determined not only by the mineral with the slowest diffusivity in the system, but also strongly depends on the constituent mineral abundances.

• The Journal of the Petrological Society of Korea
• /
• v.24 no.4
• /
• pp.365-371
• /
• 2015

The rare earth element(REE)s play an important role in understanding of rock formation and evolution because of their similar geochemical behaviors. Sm and Nd are more useful than other REEs because Sm-Nd isotopic system has important applications for geochemical interpretation like age dating and crustal evolution. These studies require a chromatographic technique for Sm and Nd separation from the geological samples. Ln-resin method using 0.25 M HCl as the eluent is widely used for Nd separation. However, this technique has a disadvantage of the poor elemental selectivity that the Nd fraction contains Ce as a tailing of the previous fraction. This technical report is a comparison study on the effect of eluent concentration between 0.25 M HCl and 0.15 M HCl on the separation of Nd with Ln-resin method for improving the technique of Nd separation. The results showed that the separation of Ce and Nd using 0.15M HCl as the eluent was not effective compared to the separation using 0.25 M HCl. In this experiment, we could confirm that the dilution of eluent might not be effective on the high purity separation of Nd with Ln-resin method.