• Title/Summary/Keyword: geochemical analysis

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Geochemical Study on Geological Groups of Stream Sediments in the Gwangju Area (광주지역 하상퇴적물에 대한 지질집단별 지구화학적 연구)

  • Kim, Jong-Kyun;Park, Yeung-Seog
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.481-492
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    • 2005
  • The purpose of this study is to determine geochemical characteristics for stream sediments in the Gwangju area. We collect the stream sediments samples by wet sieving along the primary channels and dry these samples slowly in the laboratory and grind to under 200mesh using an alumina mortar fur chemical analysis. Major elements, trace and rare earth elements are determined by XRF, ICP-AES and NAA analysis methods. For geochemical characteristics on geological groups of stream sediments, we separate geologic groups which are derived from Precambrian granite gneiss area, Jurassic granite area and Cretaceous Hwasun andesite area. Contents range of major elements for stream sediments in the Gwangju area are $SiO_2\;51.89\~70.63\;wt.\%,\;Al_2O-3\;12.91\~21.95\;wt.\%,\;Fe_2O_3\;3.22\~9.89\;wt.\%,\;K_2O\;1.85\~4.49\;wt.\%,\;MgO\;0.68\~2.90\;wt.\%,\;Na_2O\;0.48\~2.34\;wt.\%,\;CaO\;0.42\~6.72\;wt.\%,\;TiO_2\;0.53\~l.32\;wt.\%,\;P_2O_5\;0.06\~0.51\;wt.\%\;and\;MnO\;0.05\~0.69\;wt.\%.$ According to the AMF diagram for stream sediments and rocks, the stream sediments are plotted on boundary of tholeiitic series and calk alkaline series, which shows that contents of $Fe_2O_3$ are higher in stream sediments than rocks. According to variation diagram of $SiO_2$ versus $(K_2O+Na_2O),$ stream sediments are plotted on subalkaline series. Contents range of trace and rare earth elements for stream sediments in the Gwangiu area are Ba$590\~2170$ppm, Be1\~2.4$ppm, Cu$13\~79$ppm, Nb$20\~34$ppm, Ni$10\~50$ppm, Pb$17\~30$ppm, Sr$70\~1025$ ppm, V$42\~135$ppm, Zr$45\~171$ppm, Li$19\~77$ppm, Co$4.3\~19.3$ppm, Cr$28\~131$ppm, Cs$3.1\~17.6$ppm, Hf$5\~27.6$ppm, Rb$388\~202$ppm, Sb$0.2\~l.2$ ppm, Sc$6.4\~17$ppm, Zn$47\~389$ppm, Pa$8.8\~68.8$ppm, Ce$62\~272$ppm, Eu$1\~2.7$ppm and Yb$0.9\~6$ppm.

Assemblage changes of benthic foraminifera and regional paleoenvironmental changes in a piston core from the Okinawa Trough, Japan (오끼나와 해곡 주장사료 퇴적물에 대한 저서생 유공충의 군집변화와 지역해 고환경변화)

  • Hyun, Sang-Min
    • The Korean Journal of Quaternary Research
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    • v.23 no.2
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    • pp.48-55
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    • 2009
  • To investigate the paleoceanographic environmental changes around the Okinawa Trough, Japan, a piston core (RN88-PC5) was conducted on benthic foraminiferal species composition, assemblage, sedimentological and geochemical analyses. Trubidite sediment intercalated in studied core contains different benthic foraminiferal species, dwelling in shallow coral reef species, from normal hemipelagic sediment. These different benthic foraminiferal species and its assemblage are interpreted as reworked sediment when turbidite current occurred, synchronically. Grain size analysis clearly showed that mean grain size difference occurred between trubidite and hemipelagic sediments. Geochemical analysis also showed the difference of chemical composition between two sedimentary facies. Results of the foraminiferal oxygen isotope analysis showing global surface water warming records since the last 10 ka. The geochemcial analysis and previous works showed that turbidite sediment of studied core indicating sporadic occurrence of regional paleoceanographic events. Assemblage of shallow coral reef benthic foraminifera especially occurred with turbidite layer clearly support the sporadic occurrence of paleoceanographic events such as regional earthquake.

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General Geochemical Characteristics of Dashinchilen Nb-Ta and Sant Cu Occurrences in Southeastern Part of Khangai Area, Mongolia (몽골 항가이 남동부 지역 다신칠렌 탄탈륨-니오븀 및 산트 동 산출지의 지구화학적 특성 개요)

  • Kim, In Joon;Lee, Bum Han;Heo, Chul-Ho
    • Economic and Environmental Geology
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    • v.46 no.5
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    • pp.455-468
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    • 2013
  • We performed reconnaissance survey on Dashinchilen Nb-Ta REE area and Sant Cu area which are located in southeastern part of Khangai rare metals mineralized belt. In Dashinchilen area, Nb and Ta have been found in pegmatitic granite that is largely distributed in the survey area and muscovite in pegmatite which is an intrusion in paleozoic sedimentary rocks which are mostly composed of sandstone. While grades of Nb and Ta are not high, an outcrop that has high Th and U contents (542 ppm of Th and 56.9 ppm of U) has been found. Average and maximum REE contents in the survey area is three times and seven times, respectively, larger than average REE contents in the crust of the Earth. In Sant area, copper oxides such as malachite has been found in quartzite in paleozoic sedimentary rocks. A sedimentary rock formation that has high grade of Mn (12.4-34.6 %) has been found in the survey area. This sedimentary rock formation is the same formation with that of Ugii Nuur Fe-Mn mineralization which is located about 200 km northwest of the survey area. Average and maximum REE contents in the survey area is two and half times and seven times, respectively, larger than average REE contents in the crust of the Earth. According to the factor analysis for the data of the geochemical analysis, Nb and Ta in Dashinchilen area are highly correlated with muscovite and Cu in Sant area is highly correlated with Mo, Sn, and Bi. Furthermore, the factor analysis results show that Fe in Sant area was deposited with rare earth elements.

A Geochemical Study on Pyrophyllite Deposits and Andesitic Wall-Rocks in the Milyang Area, Kyeongnam Province (경남 밀양지역 납석광상과 안산암질 모암의 지구화학적 연구)

  • Oh, Dae-Gyun;Chon, Hyo-Taek;Min, Kyoung-Won
    • Economic and Environmental Geology
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    • v.25 no.1
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    • pp.27-39
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    • 1992
  • Several pyrophyllite deposits occur around the Milyang area where Cretaceous andesitic rocks and spatially related granitic rocks are widely distributed. Pyrophyllite ores consist mainly of pyrophyllite, and quartz with small amount of sericite, pyrite, dumortierite, and diaspore. The andesitic rocks and spatially related granitic rocks in this area suggest that they could be formed from the same series of a calc-alkaline magma series. The contents of $SiO_2$, $Al_2O_3$, LOI(loss on ignition) are enriched, and $K_2O$, $Na_2O$, CaO, MgO, $Fe_2O_3$ are depleted in altered andesitic rocks and ores. Enrichment of As, Cr, Sr, V, Sb and depletion of Ba, Cs, Ni, Rb, U, Y, Co, Sc, Zn are characteristic during mineralization. The pyrophyllite ores can be discriminated from the altered-and unaltered wall-rocks by an increasing of $(La/Lu)_{cn}$ from 4.18~22.13 to 8.98~55.05. In R-mode cluster analysis, Yb-Lu-Y, La-Ce-Hf-Th-U-Zr, $TiO_2-V-Al_2O_3$, Sm-Eu, $CaO-Na_2O-MnO$, Cu-Zn-Ag, $K_2O-Rb$ are closely correlated. In the discriminant analysis of multi-element data, $P_2O_5$, As, Cr and $Fe_2O_3$, Sr are helpful to identify the ores from the unaltered-and altered wall-rocks. In the factor analysis, the factors of alteration of andesitic rocks and ore mineralization were extracted. In the change of ions per unit volume, $SiO_2$, $Al^{3+}$ and LOI are enriched and $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$, $Mn^{2+}$ and $Fe^{3+}$ are depleted during the alteration processes. The Milyang and the Sungjin pyrophyllite deposits could be mineralized by hydrothermal alteration in a geochemical condition of low activity ratio of alkaline ions to hydrogen ion with reference to spatially related granitic rocks.

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A Study on the Indexes and Properties of Mechanical Weathering to Granite Distributed in Korea (화강암의 풍화산물에 대한 기계적 풍화지수의 특성에 관한 연구)

  • Rheem, Chong-Ho
    • Journal of the Korean Geographical Society
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    • v.28 no.2
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    • pp.99-111
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    • 1993
  • The transformation of rocks into unconsoli-dated debris is the prime geomorphic processes including weathering and soil forming process. In these processes, rocks tend to be unconsol-idated debris with small particles. Particularly, typical granite is more likely affected by weathering, since the rock consists of quartz, feldspar and mica that can be easily coarse-grained and well jointed without bedding. The purposes of this study are to clarify the index and properties of mechanical weathering that contributed to transformation of granite distributed in Korea. A total of seventy-three samples of weathering products of granite in Korea were collected during the three-year period, March 30, 1989 to February 21, 1992. The prticle analysis was performed for clay, silt and sand using Sieve and Hydrometer. The results of the analysis are as the followings: First, soil textures in the study area are included seven categories of textures as C, CL, SCL, Sil, SL, LS, and S. Among these textures, the most frequent soil texture were SL, S and SCL in order. Second, the weathering products of granite are crumbled by weathering and hydrothermal. Clay texture consisted of fine materials seems to be influenced by hydrothermal, while Sand texture composed of coarse materials, seems to be significantly influenced by weathering. Third, the index of mechanical weathering by region indicates that Hawngdeung(1) is the lowest as 2.37 and the index by soil texture shows that Clay texture is the lowest as 2.46. Forth, the regression analysis of MW showes that sand/clay variable is the most significant variable. Finally, pedochemical weathering is prevailed on the clayey gruss and geochemical weathering is on the gruss and shattering is on the weathered rock, strongly, but the fine materials in some sites were formed by argillation of hydrothermal.

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Geochemical Relationship Between Shore Sediments and Land Geology in Keum River Area, West Coast of Korea (한반도 서해안 금강하구 연안퇴적물과 육상지질과의 지화학적 상관관계)

  • 지정만;장윤호;오재경;이연희
    • Economic and Environmental Geology
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    • v.33 no.6
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    • pp.447-467
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    • 2000
  • This study was carried out geochemically and mineralogically to define how Kunsan shore sediments are related to their terrestrial source rocks in the region of Keum River Basin, western Korea. As a whole the chemical composition for major elements, trace elements and rare earth elements analysis from shore sediments and river bed sediments doesn't show the big difference, and especially rare earth elements chondrite normalized patterns are almost same. Heavy minerals of shore sediments are identified as hornblende, epidote, ilmenite, garnet, hematite, magnetite, sphene and rutile. Compared with Taean Area of Seo et al. (1998) and Byeonsan Area of Kwon et al. (1999), Kunsan shore sediments of this study area were origined mostly from Keum River Basin.

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Enhancing LANDSAT TM to update the structural analysis of the Mirs Bay Basin, Hong Kong, China

  • Leung, K.F.;Vohora, V.K.;Chan, L.S.;Malpas, J.G.
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.295-297
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    • 2003
  • The coastal provinces of South China have been uniquely shaped by various tectonic events. During the midlate Mesozoic tectono-thermal event, the oblique subduction of the Paleo Kula-Pacific plate beneath the Eurasian plate has created a complicated tectonic setting for the whole region. However, the mechanism of this event is not completely understood. In this paper, we discuss the advantages of using LANDSAT TM satellite imagery over a small part of the region - the Mirs Bay Basin which is largely covered by dense vegetation and where limited outcrops is seen. The use of satellite imagery complements field mapping and the result shows a prominent sinistral offset along the eastern margin of the Mirs Bay Basin, which was not previously recognized on the ground.

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금정광산 주변 토양의 중금속 오염현황 및 그 처리 방안

  • 이기철;이승길;한인호;최광호;정덕영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.189-194
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    • 1998
  • Geochemical study was carried out to find out the distribution of metals and cyanide in soil in the vicinity of the abandoned Keum-Jung mine. Chemical analysis showed that content of As in soil around tailings exceeded 15mg/kg, Korean standard of soil contamination in the farm land. That means the contamination of soil by As is due to input of tailings. According to total decomposition of tailings, As was highly concentrated in tailings. However the water in tailings impoundment was changed to acidic and contaminated by metal and sulfate because the tailings in the top of the tailings impoundment had been oxidized. Acid mine drainage contaminated the water course in the vicinity of the paddy soils. The proper measures are required to prevent contamination of the soil and water in the vicinity of the Keum-Jung mine.

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A Study on the Soil Contamination in the Heaped Soil Dredged from Bottom of the Storage Pond in Pohang Industrial Complex (포항 공단유수지 준설토의 문덕리 성토에 따른 토양오염 조사)

  • Jang, Won;Kim, Dong-Gil
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.57-60
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    • 1999
  • Geochemical study was carried out to find out soil contamination at the heaped soil, moved from bottom of the storage pond in Pohang industrial complex, in Moondug, Chemical analysis showed that contents of heavy metals in the soil were higher than those of the ordinary soil. Contents of Cu and Cd in the soil exceeded Korean standard of soil contamination. Especially content of Cu exceeded Korean standard of soil contamination(50ppm) at the six points and at one point content of Cu was 113.3ppm. Contents of Be were so higher than U.S RCRA standard(0.2ppm) that they can affect soil environment. The followed research about relation between pollutant and soil and proper measures are required to prevent soil contamination from affecting environment of Moondug.

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Characterization of Groundwater Chemistry and Fluoride in Groundwater Quality Monitoring Network of Korea

  • Han, Jiwon
    • Journal of the Korean earth science society
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    • v.42 no.5
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    • pp.556-570
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    • 2021
  • This study presents the data analysis results of groundwater chemistry and the occurrence of fluoride in groundwater obtained from the groundwater quality monitoring network of Korea. The groundwater data were collected from the National Groundwater Information Center and censored for erratic values and charge balance (±10%). From the geochemical graphs and various ionic ratios, it was observed that the Ca-HCO3 type was predominant in Korean groundwater. In addition, water-rock interaction was identified as a key chemical process controlling groundwater chemistry, while precipitation and evaporation were found to be less important. According to a non-parametric trend test, at p=0.05, the concentration of fluoride in groundwater did not increase significantly and only 4.3% of the total groundwater exceeded the Korean drinking water standard of 1.5 mg/L. However, student t-tests revealed that the fluoride concentrations were closely associated with the lithologies of tuff, granite porphyry, and metamorphic rocks showing distinctively high levels. This study enhances our understanding of groundwater chemical composition and major controlling factors of fluoride occurrence and distribution in Korean groundwater.