• Analytical Science and Technology
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• v.34 no.1
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• pp.23-35
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• 2021

In order to measure the volatile organic compounds (VOCs) of a sample which is too large to use commercially available chamber, a stainless steel vacuum chamber (VC) (with an internal diameter of 205 mm and a height of 50 mm) was manufactured and the temperature of the chamber was controlled using an oven. After concentrating the volatiles of the sample in the chamber by helium gas, it was made possible to remove residual volatile substances present in the chamber under reduced pressure ((2 ± 1) × 10-2 mmHg). The chamber was connected to a purge & trap (P&T) using a 6 port valve to concentrate the VOCs, which were analyzed by gas chromatography-mass spectrometry (GC-MS) after thermal desorption (VC-P&T-GC-MS). Using toluene, the toluene recovery rate of this device was 85 ± 2 %, reproducibility was 5 ± 2 %, and the detection limit was 0.01 ng L-1. The method of removing VOCs remaining in the chamber with helium and the method of removing those with reduced pressure was compared using Korean drinking water regulation (KDWR) VOC Mix A (5 μL of 100 ㎍ mL-1) and butylated hydroxytoluene (BHT, 2 μL of 500 ㎍ mL-1). In case of using helium, which requires a large amount of gas and time, reduced pressure ((2 ± 1) × 10-2 mmHg) only during the GC-MS running time, could remove VOCs and BHT to less than 0.1 % of the original injection concentration. As a result of analyzing volatile substances using VC-P&T-GC-MS of six types of cell phone case, BHT was detected in four types and quantitatively analyzed. Maintaining the chamber at reduced pressure during the GC-MS analysis time eliminated memory effect and did not affect the next sample analysis. The volatile substances in a cell phone case were also analyzed by dynamic headspace (HT3) and GC-MS, and the results of the analysis were compared with those of VC-P&T-GC-MS. Considering the chamber volume and sample weight, the VC-P&T configuration was able to collect volatile substances more efficiently than the HT3. The VC-P&T-GC-MS system is believed to be useful for VOCs measurement of inhomogeneous large sample or devices used inside clean rooms.

• Economic and Environmental Geology
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• v.45 no.3
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• pp.265-276
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• 2012

Current study includes the analysis of mine tailings and leachate water and prediction of species originated from the tailings. The variation of contaminants were measured upon the distance from the tailings to the nearby stream. The ions concentration was highest at the tailings and pit mouth and it becomes lower as it goes far away from the origin. This is the reason that the leachate was diluted with the uncontaminated stream water. The tailings were mainly classified into reddish one and yellow one. The main mineral of reddish tailings were quarts, illite, plumbojarosite and a small amount of sphalerite. The main mineral of yellow tailings were muscovite, quarts, plumbojarosite, and a small amount of chalcopyrite and sphalerite. Pb and Zn were found in the leachate in high concentration and become the major contaminants. These come from the dissolution of plumbojarosite and sphalerite contained in the mine tailings.

• The Korean Journal of Quaternary Research
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• v.18 no.2 s.23
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• pp.3-3
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• 2004

One short core with length of 146cm(HB-107, at coordinates of $N51^{\circ}$11'37.5";$E100^{\circ}$24'45.6", from 229m water depth was subject of the present study. The sub-samples of the core were analyzed for the water contents (WC%), biogenic silica, identification of the main phases, grain size distribution, geochemistry and some physical properties of sediment(Wet density and Magnetic susceptibility) with aims of recording palaeo-environmental changes in Northem Mongolia. The evaluation of the geochemical and mineralogical proxies on palaeo-climated and palaeo-environmental changes are based on comparison to the behvior of biogenic silica through core, as later one had been showed itself, as good indicator of the climate and environmental fluctuation. Age model of the investigating core based on previously C 14 dated core HB105 taken from the central part of the Hobsgol Lake and the result had been published elsewhere. The core consists of two litological varieties : upper diatomaceous silt, lower clay. According to the age model the upper diatomaceous silt formed during the Holocene, lower caly-during the late Pleistocene glacial period. The geochemistry and phase identification analysis on the core samples are resulted in determining main minerals that form the bottom sediments and their geochemistry. The main include quartz, felspar, muscovite, clinochlore, amphibole and carbonate phase(dolomite and calcite). Through the core not only occur the relative quantitative changes of the main phases, but also happen that the carbonate phase completely disappear in diatomaceous silt. This is believed to be related to the lake water salinity changes, which occurred during the trassition period from Pleistocene glacial-to the Holocene interglacial. These abrupt changes of the mineralogy have been clearly traced in geochemistry of sediments, specially in calcium concentration, which is high in lower clay and low in upper diatomaceous silt. That means, geochemistry and mineralogy of the bottom sediments can be used as proxy data on palaeo-climate and palaeo-environmental changes.

• Journal of the Korean Geotechnical Society
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• v.20 no.5
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• pp.49-58
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• 2004

Consolidation properties of Shihwa deposits were analysed by means of depositional environments. Depositional environments including particle size distributions, sediment structures, geochemical properties, porewater chemistries and carbon age dating were analysed using undisturbed samples retrieved successively from a boring hole in the study area. Laboratory oedometer tests and anisotropic consolidated triaxial tests (CKoUC) for undisturbed samples were performed to examine the overconsolidation phenomena. Based on the results of analysis of depositional environments, it was found that the upper silt/clay mixed layer was deposited under marine condition while underlying sand and clay layers were deposited under fluvial condition. Planar laminated structures of silts and clays were dominant in marine deposits. Although there was no clear evidences that geological erosion had occurred in marine deposits, overconsolidation ratios of the upper marine samples were greater than unity Stress Paths of the upper marine samples behaved similarly to those of normally consolidated clays. Data plotted in stress state charts showed that the marine deposits were normally consolidated in geological meaning. These apparent overconsolidation of the marine deposits can be explained by the structures i.e. chemical bonding due to the difference of the rate of deposition, not by geological erosions and ground water fluctuations.

• Journal of Soil and Groundwater Environment
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• v.25 no.1
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• pp.25-36
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• 2020

In a redox transition zone, geochemical reactions are facilitated by active bacteria that mediate reactions involving electrons, and arsenic (As) and iron (Fe) cycles are the major electron transfer reactions occurring at such a site. In this study, the effect of repetitive redox changes on soil bacterial community in As-contaminated soil was investigated. The results revealed that bacterial community changed actively in response to redox changes, and bacterial diversity gradually decreased as the cycle repeated. Proportion of strict aerobes and anaerobes decreased, while microaerophilic species such as Azospirillum oryzae group became the predominant species, accounting for 72.7% of the total counts after four weeks of incubation. Bacterial species capable of reducing Fe or As (e.g., Clostridium, Desulfitobacterium) belonging to diverse phylogenetic groups were detected. Indices representing richness (i.e., Chao 1) and phylogenetic diversity decreased from 1,868 and 1,926 to 848 and 1,121, respectively. Principle component analysis suggests that repetitive redox fluctuation, rather than oxic or anoxic status itself, is an important factor in determining the change of soil bacterial community, which in turn affects the cycling of As and Fe in redox transition zones.

• Economic and Environmental Geology
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• v.31 no.4
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• pp.277-290
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• 1998

The purpose of this research is to investigate the dispersion pattern of gold during skarnization and genesis of gold mineralization in the Sangdong skarn deposits. The Sangdong scheelite orebodies are embedded in the Cambrian Pungchon Limestone and limestone interbedded in the Myobong Slate of the Cambrian age. The tungsten deposits are classified as the Hangingwall Orebody, the Main Orebody and the Footwall Orebody as their stratigraphic locations. Recently, the Sangdong granite of the Cretaceous age (85 Ma) were found by underground exploratory drillings below the orebodies. In geochemisty, the W, Mo, Bi and F concentrations in the granite are significantly higher than those in the Cretaceous granitoids in southern Korea. Highest gold contents are associated with quartz-hornblende skarn in the Main Orebody and pyroxene-hornblende skarn in the Hangingwall Orebody. Also Au contents are closely related to Bi contents. This could be inferred that Au skarns formed from solutions under reduced environment at a temperature of $270^{\circ}C$. According to the multiple regression analysis, the variation of Au contents in the Main Orebody can be explained (87.5%) by Ag, As, Bi, Sb, Pb, Cu. Judging from the mineralogical, chemical and isotope studies, the genetic model of the deposits can be suggested as follows. The primitive Sangdong magma was enriched in W, Mo, Au, Bi and volatiles (metal-carriers such as $H_2O$, $CO_2$ and F). During the upward movement of hydrothermal ore solution, the temperature was decreased, and W deposits were formed at limestone (in the Myobong Slate and Pungchon Limestone). In addition, meteoric water influx gave rise to the retrogressive alterations and maximum solubility of gold, and consequently higher grade of Au mineralization was deposited.

• Economic and Environmental Geology
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• v.41 no.5
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• pp.517-526
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• 2008

Geological and related thematic maps make various economical and social benefits at many sectors. Recently, development of information managing technology such as GIS, Geographic Information System, enlarges the usage of geological map and information. In this research, using the Analytic Hierarchy Process, we analyzed the weight of attributes which compose value of geological map and information. Results of research are as follows. By the analysis of the weight of attributes, we found that the weight of confidence, upper hierarchy attribute, was above 50%. The weight of convenience and additional effect was about $16%{\sim}30%$ in the geological map, geophysical map, geochemical map and hydrogeologic map. And the consumption of each maps will increase, especially in large scale map.

• The Journal of Engineering Geology
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• v.18 no.1
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• pp.103-115
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• 2008

The purposes of this study are to understand characteristic water-rock interaction mechanisms of groundwater in the granite area of Geochang and Hapcheon areas, Gyeongnam-do and to clarify the origin of fluoride. The possible water-rock interaction process and the source of fluorine were studied using water chemistry, rock chemistry, mineralogy by XRD, and microtexture analysis by backscattered electron image of the electron microprobe. No clear relationships between F and hardness was found. But the fluorine content increases to some extent with pH and well depth. Preferential alteration due to water-rock interaction took place along edges or cleavage, or margins of biotite. Because biotite is highly subject to alteration in granite aquifer, fluorine in groundwater is originated from the leaching of biotite.

• The Korean Journal of Malacology
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• v.10 no.2
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• pp.10-23
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• 1994

패류화석은 지구를 이루는 퇴적암 중 석회암을 이루고 있는 주요 구성원 중의 하나이다. 지난 20년간 지질학자 및 해양학자들은 주로 심해에 쌓여 있는 퇴적물 중의 미화석(microfossil)을 이용하여 과거의 기후 및 해양의조건을 규명하기 위하여 많은 노력을 하여왔다. 그 결과로서 지질학적 시대 중 중생대 이후로부터 신생대에 이르기까지 지구 전반에 영향을 주었던 고기후에 대한 많은 정보가 얻어졌다. 또한 일부 학자들에 의하여 천해에 서식하였던 여러 화석들의 생태와 지화학적 분석(geochemical analysis)을 통하여 지엽적인 고기후(paleoclimate) 및 고해양학적(paleoceanographic)이해도 증진되어 온 것이 사실이다. 천해에 서식하고 있는 석회질 골격(calcareous skeleton)을 만드는 생물종들은 주로 생화확적인 작용을 통하여 아라고나이트와 방해석이라는 탄산염 광물을 침전시킨다. 특히 이 중에서 아라고나이트라는 광물은 불안정하여 속성작용 (퇴적물이 쌓인 후 거치는 물리, 화학적 작용)동안에 방해석으로 변하게 된다. 따라서 특이한 속성환경의 조건에 의해 아라고나이트로 보존되어 있는 패류를 제외하고는 주로 방해석으로 이루어진 화석의 분석을 통하여 고환경 복원을 위한 여러 정보를 얻을 수 있다. 이를 근거로 하여 분석 대상이 주로 된 것은 완족류나 방해석으로 이루어진 이매패류(e.g., 굴등)이었다.우리나라에서는 최근에 이르러서야 패류 화석의 지화학적 분석을 통하여 고해양학적 연구가 수행되기 시작하였다. 신생대 제 3기 마이오세에 해당하는 포항 부근에서 발견되는 연체동물 화석들은 변질이 안된 상태로서 우리에게 매우 귀중한 고해양학적 정보를 제공한다. 과거에 생물이 자랐던 성장 온도는 산소 동위원소의 비를 측정하여 구할 수 있는데 그결과에 의하면 해수의 온도가 현재보다 약간 높았음을 지시한다. 제주도 내의 서귀포 부근에서는 현재 천연기념물로 지정되어 있는 서귀포층내에서 많은 화석들이 산출되고 있다. 이 시대는 빙하기와 간빙기가 교호하던 시대로서, 분석 결과에 의하면 서귀포층이 쌓일 당시에 우리 나라는 빙하기의 영향을 받았던 것으로 생각된다.

• Journal of Korea Soil Environment Society
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• v.4 no.1
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• pp.25-34
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• 1999

This geochemical study was carried out to find out the distribution of metals and cyanide in the soils around the Keum-Jung abandoned mine. Chemical analysis showed that extractable As contents in the soils near the mine exceeded 15mg/kg, Korean standard of soil contamination for farm land. The Results suggests that As contamination is due to input of tailings in the soils. According to total decomposition of tailings, As was highly concentrated in tailings. The water in a tailings impoundment was changed to acidic and contaminated by metals and sulfate which were released through oxidation of impoundment. Acid mine drainage from the tailings impoundment distribution channels directed to the paddy soils. The proper measures are required to prevent contamination of the soil and water in the vicinity of the Keum-Jung mine.