• Journal of Environmental Science International
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• v.25 no.1
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• pp.11-21
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• 2016

The soil contamination by heavy metals in playgrounds of kindergartens in Vilnius city is analysed in this article. The aim of this research is to investigate and evaluate soil contamination by heavy metals in playgrounds of kindergartens in different territories of Vilnius city. Concentrations of heavy metals were measured using Thermo Fisher Scientific Niton$^{(R)}$ XL2 X-ray fluorescence spectrometer. Maximum allowable and background concentrations that are given in Lithuanian hygiene standard and Lithuania geochemical atlas are used to compare and evaluate concentrations of heavy metals. Concentrations of heavy metals and their spatial distribution were analysed in order to exclude the most contaminated areas relating with different functional areas of the city. Geo-statistical analysis and maps of spatial distribution were developed using IDW interpolator in ArcMap software. Detail soil surveys helps to assess the extent of anthropogenic impact in different parts of the city which can be harmful to the soil ecosystem and human health. Such researches can help to change or select different function for city areas in territorial planning process.

• Membrane and Water Treatment
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• v.4 no.4
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• pp.265-275
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• 2013

China is one of the countries with the highest reserves of coal bed methane (CBM) in the world. Likewise, the CBM industry is significantly growing in China. However, activities related to CBM development have led to more environmental problems, which include serious environmental damage and pollution caused by CBM-produced water. In this paper, the detailed characteristics of CBM-produced water in the southern Qinshui Basin were investigated and analyzed and compared with local surface water and coal mine drainage. Most of CBM-produced water samples are contaminated by higher concentration of total dissolved solids (TDS), K (Potassium), Na (Sodium) and $NH_4$. The alkalinity of the water from coalmines and CBM production was higher than that of the local surface water. The concentrations of some trace elements such as P (Phosphorus), Ti (Titanium), V (Vanadium), Cr (Chromium), Ni (Nickel), Zn (Zinc), Ge (Germanium), As (Arsenic), Rb (Rubidium), and Pd (Palladium) in water from the coalmines and CBM production are higher than the acceptable standard limits. The ${\delta}D$ and ${\delta}^{18}O$ values of the CBM-produced water are lower than those of the surface water. Similarly, the ${\delta}D$ values of the CBM-produced water decreased with increasing drainage time.

• Journal of the korean society of oceanography
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• v.32 no.3
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• pp.112-119
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• 1997

Coastal sediments collected near the Youngkwang Nuclear Power Plant were analysed for major(Al$_2$O$^_3$, Fe$^_2$O$^_3$, MgO, CaO, Na$^_2$O, K$^_2$O, TiO$^_2$, MnO), trace (Ba, Sr, V, Co, Cr, Cu, Ni, Zn, Pb) metal, and P$^_2$O$^_5$ contents. The composition of bulk metals from most stations fits within the range as those in the average crustal and sedimentary rocks, suggesting that the anthropogenic perturbation of these components is insignificant. The abundance and distribution of total contents for the majority of metals in the surface sediment could be explained by the grain size and were associated with mud (<63 ${\mu}$m) contents. However, distributions of Ca, K, Sr and Ba did not have any significant association with the sediment grain size. This may be due to the geochemical coherence among these metals in certain minerals abundant in coarse grained fractions. The distribution of Pb appears to be partly affected by the contribution from aerosol fallout. Using the R'-mode factor analysis, we show that the variance of the metal contents could be explained by four factors which account for 93.7% of the total variance. It appears that texturally controlled and/or sorting factors influenced by fine fraction are the most dominant factors which determine the relative abundance and distribution of metals in the study area.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.1
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• pp.25-32
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• 1999

In order to examine the degree of heavy metal pollutions around Samcheonpo and Youngkwang power plants, marine sediment samples were analyzed to determine heavy metal contents. Some of these sediment samples were also analyzed by using of a sequential extraction technique to know geochemical forms of the metals. The results showed that the spatial distribution of heavy metals coincided very well with those of mean grain size, carbonates and organic matters. The chemical speciation data using sequential extraction analysis also showed that a considerable amount of heavy metals except for Mn were bounded in the residual fraction, which mode of occurrence of heavy metals was generally interpreted as being the result of the lithogenic origin.

• Economic and Environmental Geology
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• v.8 no.4
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• pp.211-221
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• 1975

Weathering of granites has a geochemical role of great significance, because of their abundance and because of chemical instability near the surface of the earth, which is more pronounced than in most other rocks. On the other hand the granites are tectonically fragile and "react" to deformation with marked facility, giving rise to a whole gamut of deformed rocks. Therefore, the writer has studied on the weathering of granitic rocks at of Iri city and Jeonju city Jeollabukdo, Korea, The fresh and weathered rocks were used as material for the investigation. The results obtained by chemical analysis and observation are as follows. 1) The order of mobility in major elements was Ca, Na and K$H_2O$ was observed clearly and late stages of weathering processes. 3) The early stage of weathering is commenced by physical weathering and followed by chemical weathering. 4) The ratio of FeO/. $Fe_2O_3$, FeO/MgO, and $SiO_2/Al_2O_3 $ decreased uniformly from early to late stage of weathering processes. 5) It was proved that weathering potential of granite was larger than that of basaltic rocks.

• Advances in environmental research
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• v.6 no.1
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• pp.15-23
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• 2017

Powdered marble wastes (PMW) generated by Utique marble cutting industries (North of Tunisia) with abundant amounts were used in this study as low-cost materials to investigate the stabilization of heavy metals (Pb, Zn, Fe) in sludge generated from a local Zn-Electroplating factory. Powdered marble wastes were evaluated by means of chemical fractions of heavy metals in sludge and concentrations of heavy metals in leachate from columns to determine their ability to stabilize heavy metals in contaminated sludge. Results indicated that chemical fractions of heavy metals in sludge were affected by application of the PMW mineral materials and pH, however, the effects varied with heavy metals. Application of the powdered marble wastes mineral materials reduced exchangeable metals in the sequence of Pb (60.5%)>Fe (40.5%)>Zn (30.1%). X-ray diffraction and hydro-geochemical transport code PHREEQC analysis were successfully carried out to get a better understanding of the mechanisms of reactive mineral phases involved in reduced exchangeable heavy metals in sludge after PMW material amendments. Therefore, metal immobilization using powdered marble wastes materials is an effective stabilization technique for industrial metallic hydroxide sludge.

• Journal of The Geomorphological Association of Korea
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• v.23 no.2
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• pp.95-108
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• 2016

Several flights of marine terraces were developed along the Eastern coast of Korea (Gangneung-Donghae). Various dating techniques have been applied to determine the age of these terraces, with a view to better understand the regional uplift history. In this study, we compare the major element compositions of the terrace deposits and modern beach sediments to estimate the relative formation age of these terraces. We observed a discernible difference in major element geochemistry between modern beach sediments and various elevated terrace deposit (i.e. palaeobeach sediments). In general, weathering properties of marine terrace sediments are expected to be affected by the formation ages of terraces, and here, we confirm that the chemical composition are indicative of the relative age of the terraces in this region.

• Geosystem Engineering
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• v.21 no.5
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• pp.262-272
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• 2018

The U-statistic method is one of the most important structural methods to separate the anomaly from background. It considers the location of samples and carries out the statistical analysis of the data without judging from a geochemical point of view and tries to separate subpopulations and determine anomalous areas. In the present study, 3D U-statistic method has been applied for the first time through the three-dimensional (3D) modeling of an ore deposit. In order to achieve this purpose, 3D U-statistic is applied on the data (Fe grade) resulted from the drilling network in Baghak mine, central part of the Sangan iron mines (in Khorassan Razavi Province, Iran). Afterward, results from applying 3D U-statistic method are used for 3D modeling of the iron mineralization. Results show that the anomalous values are well separated from background so that the determined samples as anomalous are not dispersed and according to their positioning, denser areas of anomalous samples could be considered as anomaly areas. And also, final results (3D model of iron mineralization) show that output model using this method is compatible with designed model for mining operation. Moreover, seen that U-statistic method in addition for separating anomaly from background, could be very efficient for the 3D modeling of different ore type.

• Advances in environmental research
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• v.10 no.1
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• pp.43-57
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• 2021

Evaluation of groundwater quality is vital due to its diverse use for several purposes. In the present study, groundwater quality and suitability from the Peshawar basin, Pakistan, were evaluated for drinking and irrigation purposes. The water samples were analysed for major cations (Ca, Mg, Na and K) and anions (chloride, bicarbonate and sulphate) along with other physicochemical parameters (pH, electrical conductivity, total dissolved solids, and total hardness). About 95% of the water samples were found to be within the WHO, US-EPA and Pak-EPA permissible levels for drinking purposes. Seventy percent (70%) of the water samples belonged to the hard water category. Irrigation water quality parameters, such as, chloride, residual sodium bicarbonate, sodium adsorption ratio, percent sodium, magnesium adsorption ratio, Kelly's ration and permeability index were evaluated which demonstrated that the groundwater was highly to moderately suitable for irrigation. A correlation study was conducted to find out the mutual associations among the variables. Piper diagram indicated the overall chemical nature of the study area was calcium-magnesium bicarbonate type. Cluster analysis revealed mutual apportionment of various parameters in the groundwater of the Peshawar basin, Pakistan.

• Journal of the Korean earth science society
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• v.38 no.6
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• pp.421-426
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• 2017

In this study, we selected three representative granite samples and conducted petrological observation to establish the Korean geostandards. Samples were taken from the two Jurassic (KJG-1, KJG-2) and one Cretaceous (KCG-1) granites in South Korea. The powder samples were prepared by the standard pulverization process, and glass beads were made for geochemical analysis using X-ray fluorescence (XRF) method, and finally, major element contents of the samples were acquired. The analytical data are shown with mean, standard deviation and relative standard deviation. The accuracy of the analysis was confirmed within an estimated error range of about 5% by comparing the recommended true values of the USGS and GSJ geostandards. Also, we checked the analytical precision by calculating a relative standard deviation of about 3% from the XRF analytical results for the three samples.