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http://dx.doi.org/10.12989/aer.2017.6.1.015

Marble wastes as amendments to stabilize heavy metals in Zn-Electroplating sludge  

Riahi, Khalifa (Higher Institute on Rural Engineering and Equipment Medjez El Bab, University of Jendouba)
Chaabane, Safa (Higher Institute on Rural Engineering and Equipment Medjez El Bab, University of Jendouba)
Thayer, Bechir Ben (Higher Institute on Rural Engineering and Equipment Medjez El Bab, University of Jendouba)
Publication Information
Advances in environmental research / v.6, no.1, 2017 , pp. 15-23 More about this Journal
Abstract
Powdered marble wastes (PMW) generated by Utique marble cutting industries (North of Tunisia) with abundant amounts were used in this study as low-cost materials to investigate the stabilization of heavy metals (Pb, Zn, Fe) in sludge generated from a local Zn-Electroplating factory. Powdered marble wastes were evaluated by means of chemical fractions of heavy metals in sludge and concentrations of heavy metals in leachate from columns to determine their ability to stabilize heavy metals in contaminated sludge. Results indicated that chemical fractions of heavy metals in sludge were affected by application of the PMW mineral materials and pH, however, the effects varied with heavy metals. Application of the powdered marble wastes mineral materials reduced exchangeable metals in the sequence of Pb (60.5%)>Fe (40.5%)>Zn (30.1%). X-ray diffraction and hydro-geochemical transport code PHREEQC analysis were successfully carried out to get a better understanding of the mechanisms of reactive mineral phases involved in reduced exchangeable heavy metals in sludge after PMW material amendments. Therefore, metal immobilization using powdered marble wastes materials is an effective stabilization technique for industrial metallic hydroxide sludge.
Keywords
powdered marble wastes; heavy metals; stabilization; sludge; Zn-Electroplating;
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1 Alloway, B.J. (1995), Heavy Metals in Soils, Blackie Academic & Professional, Glasgow, Scotland.
2 APHA (1992), Standard Methods for the Examination of Water and Wastewater, 18th Edition, American Public Health Association, Washington, U.S.A.
3 Basta, N. and Mc Gowen, S. (2004), "Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil", Environ. Pollut., 127(1), 73-82.   DOI
4 Bolan, N., Kunhikrishnan, A., Thangarajan, R., Kumpiene, J., Park, J., Makino, T., Kirkham, M.B. and Scheckel, K. (2014), "Remediation of heavy metal(loid)s contaminated soils-to mobilize or to immobilize?", J. Hazard. Mater., 266, 141-166.   DOI
5 Brallier, S., Harrison, R.B., Henry, C.L. and Dongsen, X. (1996), "Liming effects on availability of Cd, Cu, Ni and Zn in a soil amended with sewage sludge 16 years previously", Wat. Air Soil Pollut., 86(1-4), 195-206.   DOI
6 Cazalet, M. (2012), "Caracterisation physico-chimique d'un sediment marin traite aux liants hydrauliquesevaluation de la mobilite potentielle des polluants inorganiques", Ph.D. Dissertation, L'Institut National des Sciences Appliquees de Lyon, France.
7 Garau, G., Castaldi, P., Santona, L., Deiana, P. and Melis, P. (2007), "Influence of red mud, zeolite and lime on heavy metal immobilization, culturable heterotrophic microbial populations and enzyme activities in a contaminated soil", Geoderma, 142(1), 47-57.   DOI
8 Chen, S., Xu, M., Ma, Y. and Yang, J. (2007), "Evaluation of different phosphate amendments on availability of metals in contaminated soil", Ecotoxicol. Environ. Saf., 67(2), 278-285.   DOI
9 Contin, M., Mondini, C., Leita, L. and Nobili, M.D. (2007), "Enhanced soil toxic metal fixation in iron (hydr) oxides by redox cycles", Geoderma, 140(1), 164-175.   DOI
10 Dermentzis, K., Marmanis, D. and Christoforidis, A. (2014), "Remediation of heavy metal bearing wastewater by photovoltaic electrocoagulation", Proceedings of the 2nd International Conference-Water Resources and Wetlands, Romania, September.
11 Kumar, E., Bhatnagar, A., Hogland, W., Marques, M. and Sillanpaa, M. (2014), "Interaction of inorganic anions with iron-mineral adsorbents in aqueous media", Adv. Colloid. Interf. Sci., 203, 11-21.   DOI
12 Grebenyuk, V.D., Sorokin, G.V., Verbich, S.V., Zhiginas, L.H., Linkov, V.M., Linkov, N.A. and Smith, J.J. (1996), "Combined sorption technology of heavy metal regeneration from electroplating rinse waters", Wat. SA, 22(4), 381-384.
13 Kandil, H., El-Kherbawy, M.I., Ibrahim, S., Abd-Elfattah, A., Abd El-Moez, M.R. and Badawy, S.H. (2012), "Effect of different sources and rates of some organic manure on content of some heavy metals in different soils and plants grown therein: II. Effect on corn plants, soil form", Fact. Proc. Temp. Zone, 11(1), 19-32.
14 Katsioti, M., Katsiotis, N., Rouni, G., Bakirtzis, D. and Loizidou, M. (2008), "The effect of bentonite/cement mortar for the stabilization/solidification of sewage sludge containing heavy metals", Cement Concrete Compos., 30(10), 1013-1019.   DOI
15 Simon, M., Diez, M., Gonzalez, V., Garcia, I., Martín, F. and De Haro, S. (2010), "Use of liming in the remediation of soils polluted by sulphide oxidation: A leaching-column study", J. Hazard. Mater., 180(1), 241-246.   DOI
16 Mench, M., Vangronsveld, J., Didier, V. and Clijsters, H. (1994), "Evaluation of metal mobility, plant availability and immobilization by chemical agents in a limed-silty soil", Environ. Pollut., 86(3), 279-286.   DOI
17 Mendez, A., Gomez, A., Paz-Ferreiro, J. and Gasco, G. (2012), "Effects of sewage sludge biochar on plant metal availability after application to a mediterranean soil", Chemosp., 89(11), 1354-1359.   DOI
18 Parkhurst, D.L. and Appelo, C.A.J. (1999), User's Guide to PHREEQC (version 2)-A Computer Program for Speciation, Batch-Reaction, One-Dimensional Transport, and Inverse Geochimical Calculations", U.S. Geological Survey Water-Resources Investigations, Denver, U.S.A.
19 Song, H., Carraway, E.R., Kim, Y.H., Batchelor, B., Jeon, B.H. and Kim, J.G. (2008), "Amendment of hydroxyapatite in reduction of tetrachloroethylene by zero-valent zinc: Its rate enhancing effect and removal of Zn(II)", Chemosp., 73(9), 1420-1427.   DOI
20 Singh, A. and Prasad, S.M. (2015), "Remediation of heavy metal contaminated ecosystem: An overview on technology advancement", J. Environ. Sci. Technol., 12(1), 353-366.   DOI
21 Szrek, D., Bajda, T. and Manecki, M. (2011), "A comparative study of the most effective amendment for Pb, Zn and Cd immobilization in contaminated soils", J. Environ. Sci. Health, 46(13), 1491-1502.   DOI
22 Wang, L.K., Chen, J.P., Hung, Y.T. and Shammas, N.K. (2010), Handbook on Heavy Metals in the Environment, Taylor & Francis and CRC Press, Florida, U.S.A.
23 WHO (2007), Health Risks of Heavy Metals from Long-Range Transboundary Air Pollution.
24 Xu, Y.P. and Schwartz, F.W. (1994), "Lead immobilization by hydroxyapatite in aqueous solutions", J. Contamin. Hydrol., 15(3), 187-206.   DOI
25 Zhang, M. and Pu, J. (2011), "Mineral materials as feasible amendments to stabilize heavy metals in polluted urban soils", J. Environ. Sci., 23(4), 607-615.   DOI
26 Zhao, M., Duncan, J.R. and Van Hille, R.P. (1999), "Removal and recovery of zinc from solution and electroplating effluent using azolla filiculoides", Wat. Res., 33(6), 1516-1522.   DOI