• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.12
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• pp.333-338
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• 2016

The purpose of this study was to understand the pollution level of the surface sediment of Sihwa Lake by assessing its geochemical characteristics and investigating the spatial distribution of trace metals and organic matter. In the surface sediment of Sihwa lake, the mean grain size was between 2.94 and 6.35 Ø and the main type of sediment was sandy silt. The concentrations of As, Co, Cr, Ni, V and Li among the metal elements in the surface sediment were correlated with the mean crust concentration (p<0.05). Based on the strong correlation between the metals (Cd, Cu, Pb and Zn) and organic matter (Ignition Loss), the concentrations of these metal elements seem to be controlled by the organic matter dilution effect. The trace metal pollution level, determined by applying the Republic of Korea Marine environmental standard and the US National Oceanic and Atmospheric Administration's sediment quality guidelines, showed the pollution level of As to be either close to or in excess of the above-mentioned standards at almost all levels. The enrichment factor and geoaccumulation index of As showed that there was an incremental increase of pollution by elements other than V, Cr, Co, Fe, Al and Mn. Moreover, the nearby industrial area and dike were more polluted than the other areas, so the surface sediments in Sihwa lake should be monitored by taking into consideration the geological variations.

• Journal of Korea Soil Environment Society
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• v.2 no.1
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• pp.73-81
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• 1997

Retention ponds have been dug along some of the motorways to control water flow during rainstorms and to minmize environmental pollution. A retention pond located at Les Ardilleres about 20km South of Orleans along the A-71 motorway has been selected to evaluate the effectiveness of such a pond as a trap for heavy metals. Based on the "index of geoaccumulation" and the "enrichment factor" normalized to Fe introduced by Muller in 1979 and by Helz in 1976, respectively, the degree of contamination by heavy metals for the roadside soil and the settling particles was evaluated. As expected, the contamination was very severe in the roadside soil, while it was not so great in the settling particles. Using these methods, cadmium anomaly was traced in the settling particles of the retention pond, their occurrence being attributed partly to natural and partly to anthropogenic pollution. The estimated input of heavy metals associated with settling particles to the pond was 0.9 g/day Pb, 2.1 g/day Zn and 6mg/day Cd. A tentative mass balance of Pb and Zn originated by motor vehicles suggested that only 5 to l1% of heavy metals deposited on the surface of the motorway is carried to the retention pond by runoff water ; suggestions are made to improve their efficiency.ve their efficiency.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.39 no.2
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• pp.106-117
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• 2006

We measured the concentrations of organic matter and metallic elements (Al, Fe, Cr, Mn, Ni, Cu, Zn, As, Cd, Pb and Hg) in the surface sediments of Masan Harbor (in the southern sea, Korea) to evaluate the geochemical characters of sediment and the pollutions by organic matter and metallic elements. The mean grain size of the surface sediments in the study area ranged from $5.6{\phi}$ to $7.8{\phi}$, indicating silt sediment. The water content of the surface sediments exceeded 60% except at some stations. The contents of ignition loss (IL), total organic carbon (TOC) and total nitrogen (TN) ranged from 7.2-14.3%, 1.2-3.2%, and 0.10-0.28%, respectively. Based on the C/N ratios, the organic matter in the surface sediments of Masan Harbor may originate from terrigenous sources including fluvial inputs (mainly sewage in urban areas). The chemical oxygen demand (COD) and acid volatile sulfide (AVS) ranged from $11.3-29.9\;mgO_2/g\;dry$ and 0.20-4.47 mgS/g dry, respectively, and low concentrations were observed near a shipping route. In addition, the concentrations of metallic elements showed large spatial variations in Masan Harbor and the distributions of metallic elements were also comparable to those of organic matter. This implies that the distributions of organic matter and metallic elements in the surface sediments of Masan Harbor are mainly controlled by biogenic matter and artificial action (mainly dredging). In addition, we calculated the enrichment facto. (EF) and geoaccumulation index (Igeo) in order to evaluate pollution by metallic elements. The enrichment of metallic elements relative to Al was three to eighteen times higher at the study sites, compared to levels in the Earth's crust except for Fe, Ni and Mn. In addition, the Igeo class indicated that the surface sediments in the study area were moderately to strongly polluted in terms of metallic elements.

• Journal of the Korean earth science society
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• v.24 no.4
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• pp.346-360
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• 2003

In order to investigate the geochemical characteristics of surface sediments in streams of Gwangju City, sediment samples from the main stream of Yeongsan river, Hwangryong river, and Gwangjucheon in the city were collected and analyzed for grain size and metal and organic carbon contents. The sediment types of the streams widely vary from pebble to mud. The metal contents in the sediments from Yeongsan river and Hwangryong river are mainly dependent on the grain size of the sediments and the geology around the streams, while the sediments in Gwangiucheon are controlled by organic matter contents from the domestic sewage. The enrichment factor (Ef) and index of geoaccumulation (Igeo) representing the degree of metal contamination in the sediments are relatively low in the mainstream of Yeongsan river and Hwangryong river. However, those of Gwangjucheon show EF values of P=8.30, Cu=5.54, Zn=14.28 and Pb=7.41 and Igeo values of P=3.78, Cu=2.79, Zn=3.66 and Pb=1.59. The heavy metal contamination is especially significant near the area where the Seobangcheon and Donggyecheon branches of Gwanjucheon, join. Therefore, it is suggested that the metallic contaminations of these small streams are significantly influenced by the domestic sewage of the city.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.48 no.4
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• pp.542-554
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• 2015

Grain size, the content of ignition loss (IL), and the concentrations of chemical oxygen demand (COD), acid volatile sulfide (AVS), and trace metals (Fe, Mn, Cu, Pb, Zn, Cd, Cr, As, and Hg) in surface sediments from the Taehwa River estuary, Ulsan, were measured to evaluate pollution levels and potential ecological risks of organic matter and trace metals in estuarine sediment. The mean grain size (Mz) of sediments in the study region ranged from $-0.8-7.7{\varphi}$ (mean $2.8{\pm}2.4{\varphi}$). Surface sediments in the upstream region of the Taehwa River were mainly composed of coarse sediments compared to the downstream region. The concentrations of IL, COD, AVS and trace metals in the sediment were much higher at downstream sites of Myeongchon Bridge in the vicinity of industrial complexes than at upstream sites of those in the vicinity of the residential areas due to the anthropogenic input of organic matter and trace metals by industrial activities. On the basis of several geochemical assessment techniques [sediment quality guidelines (SQGs), enrichment factor (EF), geoaccumulation index ($I_{geo}$), pollution load index (PLI) and ecological risk index (ERI)], the surfaces sediments in the study region are not highly polluted for trace metals, except for As. However, the higher concentrations in downstream study regions of the Taehwa River could impact benthic organisms including shellfish (i.e. Manila clam) in sediments.

• Economic and Environmental Geology
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• v.33 no.3
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• pp.195-204
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• 2000

order to investigate physical characteristics and element concentrations of sediments, coastal bottom sediments were collected at 20 stations in the vicinity of Youngkwang Nuclear Power Plant. After air drying of samples in the laboratory. article size distribution was examined by Master sizer (X-350F), radio-activity by HPGe ${\gamma}$-spectrphotometer, and element concentrations by ICP-AES and AAS. According to particle size analysis , sediments are mainly composed of silt fraction weith 23% of sand, 65% of silt and 12% of clay on average. Most sediments are derived from muddy environment that silt dominates with the characteristics of 5.3${\varsigma}$ mean particle size, poorly sorted, very fine skewed and lepto-kurtic. Only two sediments are well sorted with sandy silt owing to wind, winnowing action, tide and current andits complex reactions. Element concentrations in the coastal bottom sediments are relatively high at finer sediment and show significant relationship with grain size. Index of geoaccumulation by heavy metals at every sampling station is classified as practically unpolluted. The radioactivities of the sediments were measured for 15 isotope elements, and 2 elements of K-40 and Cs-137 were detected in most sediments. The K-40 is the natural nuclide and the artificial nuclide of Cs-137 was thought to be derived from the fallout of past nuclear weapon test. The results of correlation coefficient between grain size and radioactivity shows that the activity of Cs-137 significantly increases in finer grain.

• Journal of the Korean earth science society
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• v.42 no.4
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• pp.412-424
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• 2021

Understanding the distribution of heavy metals in sediment is necessary because labile heavy metals can partition into the water column and bioaccumulate in aquatic organisms. Here we investigated six heavy metals (Co, Cu, Mn, Ni, Pb, and Zn) in sediment cores using a five-step sequential leaching method to examine the occurrence of heavy metals in the sediment. The results showed that all elements, except Mn, are depleted in the exchangeable and carbonate fractions. However, heavy metal concentrations are much higher in the Fe-Mn oxide and organic matter fractions, especially for Cu, indicating enrichment in the organic matter fraction. Furthermore, contamination parameters (contamination factor and geoaccumulation index) indicate that Mn contamination is high, primarily derived from anthropogenic sources, presenting a potential risk to ecosystems in the Nakdong River.

• Journal of Soil and Groundwater Environment
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• v.8 no.2
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• pp.19-35
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• 2003

In order 새 investigate the spatial and seasonal variations of heavy metal pollution in heavily industrialized urban area, urban roadside sediments were collected for five years from gully pots in Seoul City. A series of studies have been carried out concerning the physicochemical characteristics of the sediments in order to evaluate the contamination of heavy metals such as Cd, Co, Cr, Cu, Ni, Pb and Zn. Roadside sediments and uncontaminated stream sediments were analyzed for total metal concentrations using acid extraction. The roadside sediments are characterized by very high concentrations of Zn (2,665.0$\pm$1,815.0 $\mu\textrm{g}$/g), Cu (445.6$\pm$708.0 $\mu\textrm{g}$/g), Pb (214.3$\pm$147.9 $\mu\textrm{g}$/g) and Cr (182.1$\pm$268.8 $\mu\textrm{g}$/g), indicating an artificial accumulation of these metals to the sediment chemistry. Comparing with average contents of uncontaminated stream sediments, roadside sediments were shown zinc 14 times (up to 64.4), copper 9 times (up to 181.7), lead 6 times (up to 63.7), cobalt 6 times (up to 168.7), nickel 4 times (up to 98.4), cadmium 2 times (up to 12.8) and chrome 2 times (up to 40.2) high content. The relative degree of heavy metal pollution for roadside sediments collected from each district in Seoul City is evaluated using the “geoaccumulation index”. As a result, heavy-metal contamination is highest centering the oldest residential district and industry area, and contamination level decreases as go to outer block of the city. The factor analysis results indicate that the levels of Cu, Ni, Fe and Cr are strongly related to numbers of factories, whereas the concentrations of Cr, Zn and Cd dependant on pollution index, indicating artificial contamination due to site-specific traffic density.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.44 no.6
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• pp.772-784
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• 2011

We measured grain size, organic matter, and metallic elements (Fe, Cu, Pb, Zn, Cd, Cr, Mn, Hg, and As) in intertidal sediments collected from six islands in the western part of Jellanam Province in order to evaluate heavy metal contamination in the tidal flat sediments of coastal islands. The evaluation of metal contamination was carried out using geochemical assessment techniques such as sediment quality guidelines (SQGs), enrichment factor (EF), and geoaccumulation index ($I_{geo}$). Surface sediments were classified into four sedimentary facies: sand, gravelly muddy sand, slightly gravelly mud, and silt. The concentrations of heavy metals in intertidal sediments from Jaeun, Amtae, Biguem, and Docho islands showed good positive correlations with mean grain size and ignition loss, indicating that the concentrations of metallic elements in these sediments were dependent on grain size and the organic matter content. The concentrations of heavy metals in sediments from almost all of the stations were lower than two criterion values proposed by the National Oceanic and Atmospheric Administration (NOAA) in the United States. Based on the EF and $I_{geo}$ results, surface sediments were a little polluted for Cr and were moderately polluted for As. Our results suggest that more intensive studies are necessary in the future in order to determine the major source of As in intertidal sediment and to evaluate the As pollution level in macrobenthos.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.44 no.6
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• pp.759-771
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• 2011

We evaluated the pollution levels of organic matter and metallic element (Fe, Cu, Pb, Zn, Cd, Ni, Cr, Mn, As, and Hg) in the intertidal surface sediments of Aphae Island using several sediment quality guidelines (SQGs) and assessment techniques for sediment pollution. Based on the textural composition of sediment, the surface sediments were classified into two main sedimentary facies: slightly gravelly mud and silt. The concentrations of chemical oxygen demand (COD) and acid volatile sulfide (AVS) in the sediments ranged from 4.6-9.9 (mean $7.4{\pm}1.1$) $mgO_2/g{\cdot}dry$ and from ND-0.53 (mean $0.04{\pm}0.10$) mgS/$g{\cdot}dry$, respectively. These values were considerably lower than those reported from a farming area in a semi-enclosed bay of Korea and for SQGs in Japan. The metallic element concentrations in the sediments varied widely with the mean grain size and organic matter content, implying that the concentrations of metallic elements are influenced mainly by secondary factors, such as bioturbation, the resuspension of sediment, and anthropogenic input. The overall results for the comparison with SQGs, enrichment factor (EF), and geoaccumulation index ($I_{geo}$) indicate that the surface sediments are slightly polluted by Cr and Ni, and moderately polluted by As. Our results suggest that the intertidal surface sediments of Aphae Island are not polluted by organic matter or metallic elements and the benthic conditions are suitable for healthy organisms.