• Clean Technology
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• v.27 no.1
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• pp.61-68
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• 2021

Selective catalytic reduction (SCR) is widely used as a method of removing nitrogen oxide in large-capacity thermal power generation systems. Uniform mixing of the injected ammonia and the inlet flue gas is very important to the performance of the denitrification reduction process in the catalyst bed. In the present study, a computational analysis technique was applied to the ammonia injection system design process of a denitrification facility. The applied model is the denitrification facility of an 800 MW class coal-fired power plant currently in operation. The flow field to be solved ranges from the inlet of the ammonia injection system to the end of the catalyst bed. The flow was analyzed in the two-dimensional domain assuming incompressible. The steady-state turbulent flow was solved with the commercial software named ANSYS-Fluent. The nozzle arrangement gap and injection flow rate in the ammonia injection system were chosen as the design parameters. A total of four (4) cases were simulated and compared. The root mean square of the NH3/NO molar ratio at the inlet of the catalyst layer was chosen as the optimization parameter and the design of the experiment was used as the base of the optimization algorithm. The case where the nozzle pitch and flow rate were adjusted at the same time was the best in terms of flow uniformity.

• Journal of Korean Society of Water and Wastewater
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• v.35 no.6
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• pp.533-544
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• 2021

Ion exchange (IX) performance on the exchanger bed is essentially evaluated for the generation of ultrapure water in electronics and chemical industries and for the corrosion control in nuclear power plants. The breakthrough characteristics of IX bed with multi-component were investigated with both cation- and mixed-IX beds of H- and ETAH-form for four kinds of cation exchange resins by using the combined solution of ethanolamine (ETA) and ammonia (NH₃) at trace NaCl. Unlike major components (ETAH⁺ and NH₄⁺ ), the phenomena of breakthrough and overshooting at bed outlet were not observed by Na⁺ over the test period (> 3 times theoretical exchange capacity of IX bed). The breakthrough from H-form resin bed was sequentially reached by ETAH⁺ and NH₄⁺, while the overshooting was observed for ETAH⁺ at the breakthrough of NH₄⁺. NH₄⁺ was 51.5% higher than ETAH⁺ in terms of the relative selectivity determined with the width of breakthrough zone. At the increased concentration of Na⁺ at bed inlet, the selectivity and the overshooting were decreased and increased, respectively. Na⁺ leakage was higher from ETAH-form resin bed and was not identical for four kinds of cation-exchange resins, which may be reduced by improving the intrinsic property of IX resin.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.49 no.12
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• pp.963-969
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• 2021

The wind data measured from local meteorological masts is used to evaluate wind speed distribution and energy production in the specified site for wind farm However, wind data measured from meteorological masts often contain missing information or insufficient desired height or data length, making it difficult to perform wind turbine control and performance simulation. Therefore, long-term continuous wind data is very important to assess the annual energy production and the capacity factor for wind turbines or wind farms. In addition, if seasonal influences are distinct, such as on the Korean Peninsula, wind data with seasonal characteristics should be considered. This study presents methodologies for generating synthetic wind that take into account fluctuations in both wind speed and direction using the hidden Markov model, which is a statistical method. The wind data for statistical processing are measured at Maldo island in the Kokunnsan-gundo, Jeonbuk Province using the Automatic Weather System (AWS) of the Korea Meteorological Administration. The synthetic wind generated using the hidden Markov model will be validated by comparing statistical variables, wind energy density, seasonal mean speed, and prevailing wind direction with measurement data.

• Journal of Korea Water Resources Association
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• v.55 no.7
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• pp.531-543
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• 2022

Integrated water resources management (IWRM) has focused on efficient response to various water related disasters by climate change. In particular, more flexible usage of conventional water resources infrastructures is expected to provide an eco-friendly water management. Multi-purpose dams and water supply dams are well known as water management facilities for securing and supplying water in drought season. Recently, based on the report '2021 multi-purpose use of hydropower dams in Han river', contribution of hydropower dams on water resources management is becoming more significant beyond the traditional role of hydropower generation. In drought conditions, the dams control water supply depending on the pre-defined drought stages. In the case of multi-purpose dams, an operation standard during drought has been already prepared and applied; however, for the hydropower dams, specific standards are not fully prepared yet in South Korea. In this study, a method for calculation of standard water storage and discharge reduction of hydropower dams according to drought stage is newly proposed reflecting the characteristics of hydropower dams. The proposed method was applied to the hydropower dams in Han river, where six hydropower dams are located. A case study of the historical droughts occurred in 2014-2017 demonstrated that the proposed hydropower dam operation rule could improve the water supply stability under severe drought conditions compared to the conventional operations. In the future, the role of hydropower dams for water resources management is expected to become more important, and this study can be widely used for water supply planning such as drought response using hydropower dams.

• Journal of the Korean Electrochemical Society
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• v.25 no.1
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• pp.1-12
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• 2022

Lithium metal is the most promising anode for next-generation lithium-ion batteries due to its lowest reduction potential (-3.04 V vs. SHE) and high specific capacity (3860 mAh/g). However, the dendritic formation under high charging current density remains one of main technical barriers to be used for commercial rechargeable batteries. To address these issues, tremendous research to suppress lithium dendrite formation have been conducted through new electrolyte formulation, robust protection layer, shape-controlled lithium metal, separator modification, etc. However, Li/Li symmetric cell test is always a starting or essential step to demonstrate better lithium dendrite formation behavior with lower overpotential and longer cycle life without careful analysis. Thus, this review summarizes overpotential behaviors of Li/Li symmetric cells along with theoretical explanations like initial peaking or later arcing. Also, we categorize various overpotential data depending on research approaches and discuss them based on peaking and arcing behaviors. Thus, this review will be very helpful for researchers in lithium metal to analyze their overpotential behaviors.

• Applied Chemistry for Engineering
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• v.34 no.4
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• pp.331-346
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• 2023

Recently, green processes that can be directly used in an energy-efficient and electrified society to achieve carbon neutrality are attracting attention. Existing heat and pressure-based desalination technologies that consume tremendous amounts of energy are no exception, and the growth of next-generation electrochemical-based desalination technologies is remarkable. One of the most representative electrochemical desalination technologies is electrochemical ion separation (EIONS) technology, which includes capacitive desalination (CDI) and battery desalination (BD) technology. In the research field of EIONS, various system applications have been developed to improve system performance, such as capacity and cyclability. However, it is very difficult to understand the meaning and novelty of these applications immediately because there are only a few papers that summarize the research background for domestic readers. Therefore, in this review paper, we aim to describe the technological advances and individual characteristics of each system in clear and specific detail about the latest EIONS research. The driving principle, research background, and strengths and weaknesses of each EIONS system are explained in order. In addition, this paper concluded by suggesting the future development and research direction of EIONS. Researchers who are just beginning out in EIONS research can also benefit from this study because it will help them understand the research trend.

• Journal of Christian Education in Korea
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• v.72
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• pp.273-291
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• 2022

The Industrial Revolution brought great development to the whole human history by the improvement of productive capacity. However, high speed development absorbed just on growth gave rise to resource depletion attack and economical inequality. If it might be neglected human society will meet unsustainable development situation. So UN has made effort to make sustainable development(SD) through global band together. SD concept considers it important to promote current development not giving damage to next generation's development. Then economy, environment and social integration should be harmonized and it demands governance for its actualization. SD gets to be a matter of common interest in education. New Millenium development Goals make African poor countries that are in blind spots of development advance toward gradual sustainable development by supporting programmes to these countries. Thus sustainable development education(SDE) is for future. It has an aim to give suitable education for all people who are all over the world. SDE tries to make health society and successful economical life for all. The concept of SD is found in the essential aims of Christian school and Christian education seeking justice and shalom. Christians are called as transformers for servant mission giving recover in corrupt world. Firstly, Christian school practise this mission making students think on Christian perspectives. Then it makes students serve for environment, economical fairness, social integration with servant mission. Also Christian school has a mission to seek both justice and shalom as a praxis beyond the intellectual dimension of education until fulfilling justice and shalom for all who are all over the world. Thus it can be that Christian school is an important educational institution for realizing sustainable development in that it is always to seek justice and shalom through restoration on the Christian educational perspective.

• Applied Chemistry for Engineering
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• v.34 no.5
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• pp.534-540
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• 2023

The high-rate performance is limited by several factors, such as polarization generation, low electrical conductivity, low surface energy, and low electrolyte permeability of CF_X, which is widely used as a cathode active material in the lithium primary battery. Therefore, in this study, we aimed to improve the battery performance by using carbon fluoride modified by surface treatment using oxygen plasma as a cathode for lithium primary batteries. Through XPS and XRD analysis, changes in the surface chemical characteristics and crystal structure of CF_X modified by oxygen plasma treatment were analyzed, and accordingly, the electrochemical characteristics of lithium-ion primary batteries were analyzed and discussed. As a result, the highest number of semi-ionic C-F bonds were formed under the oxygen plasma treatment condition (7.5 minutes) with the lowest fluorine to carbon (F/C) ratio. In addition, the primary cell prepared under this condition using carbon fluoride as the active material of the cathode showed the highest 3 F/C(3 C rate-performance) rate-performance and maintained a relatively high capacity (550 mAh/g) even at high rates. In this study, it was possible to produce lithium primary batteries with high-rate performance by adjusting the fluorine contents of carbon fluoride and the type of carbon-fluorine bonding through oxygen plasma treatment.

• Economic and Environmental Geology
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• v.57 no.1
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• pp.83-91
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• 2024

According to the IEA (2022), global rechargeable battery demand is expected to reach 1.3 TWh in 2040. EV batteries will account for about 80% of this demand, and used EV batteries are expected to be discharged after 30 years. Used EV batteries can be recycled and reused to create new value. They can also resolve one of the most vulnerable parts of the battery supply chain: raw material insecurity. In this study, we analyzed the amount of used batteries generated by EV in Korea and their potential for reuse and recycling. As a result, it was estimated that the annual generation of used batteries for EV began to increase to more than 100,000 in '31 and expanded to 810,000 in '45. In addition, it was found that the market for recycling EV batteries in '45 could be expected to be equivalent to the production of 1 million batteries, and the market for reuse could be expected to be equivalent to the production of 36 Gwh of batteries. On the other hand, according to the plan standard disclosed by the recycling company, domestic used EV batteries can account for 11% of the domestic recycling processing capacity (pre-treatment) ('30). So it will be important to manage the import and export of used batteries in terms of securing raw materials.

• Journal of the Korean Geotechnical Society
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• v.40 no.1
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• pp.29-37
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• 2024

In this study, recycled concrete aggregates (RCA) were treated in a 5-kg-scale prototype reactor with carbon dioxide (CO₂) to enhance their material quality and geotechnical performance. The aggregate crushing value (ACV) and California bearing ratio (CBR) were measured on untreated RCAs and CO₂-treated RCAs. After CO₂ treatment, the ACV decreased from 35.6% to 33.2%, and the CBR increased from 97.5% to 102.4%. The CO₂ treatment caused a reduction of fine particle generation and an increase in bearing capacity through carbonation. When CO₂ treatment was performed with mechanical agitation, which provided additional enhancement in mechanical quality, the ACV was reduced further to 30.3%, and the CBR increased to 137.7%. If upscaled effectively, the proposed CO₂ treatment technique would be an effective method to reduce carbon emissions in construction industries.