• 제목/요약/키워드: gel property

검색결과 398건 처리시간 0.025초

파라-페닐렌디아민이 함유(含有)된 산화형(酸化形) 영구염모제(永久染毛制)의 물리화학적(物理化學的) 특성평가(特性評價)에 관(關)한 연구(硏究) (A Study on the Physico-Chemical Property Evaluation of Oxidative Permanent Hair Color Products Containing p-Phenylene Diamine)

  • 하병조;전동원;김경선
    • 패션비즈니스
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    • 제9권5호
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    • pp.136-144
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    • 2005
  • Oxidative hair color is currently widely used because of its beautiful light color and good dyeability. In this study, hair color, oxidative agents, and dye intermediate were reacted. Modifier, which changes color with various hue, and alkaline agent, which opens the cuticle of hair fiber and enhances the dyeing reaction, were added. For gel formation, isocetyl alcohol was used as solvent in preparing three kinds of permanent oxidative hair color. Physiochemical study of prepared permanent oxidative hair color was done for basic information acquisition. Acid perspiration test, pH measurement both at room temperature and at high temperature, drop movement test, dyeability efficiency upon the amount of hydrogen peroxide added, and humidity fastness were studied. Shampoo fastness and light fastness of prepared permanent oxidative hair color dyed hair sample were also investigated. All three kinds of hair color prepared showed good properties overall, however, dyed hair sample became reddish upon shampoo fastness and lightfastness tests.

Effects of Heating Time and Temperature on Functional Properties of Proteins of Yellow Mealworm Larvae (Tenebrio molitor L.)

  • Lee, Ha-Jung;Kim, Ji-Han;Ji, Da-Som;Lee, Chi-Ho
    • 한국축산식품학회지
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    • 제39권2호
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    • pp.296-308
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    • 2019
  • Although the yellow mealworm (Tenebrio molitor L.) is a promising alternative protein source, the effects of processing conditions on functional properties are unclear. In this study, a protein extract of yellow mealworm larvae (PEYM) was subjected to different heat temperature ($55^{\circ}C$, $75^{\circ}C$, and $95^{\circ}C$) with different time (20, 40, and 60 min) to evaluate the functional properties and protein oxidation. Different heat temperature treatment significantly affected the exposure of surface hydrophobicity of the proteins and protein molecule aggregation, which reached maximum levels at $95^{\circ}C$ for 60 min. Protein oxidation was inversely proportional to the temperature. Both the highest carbonyl value (1.49 nmol/mg protein) and lowest thiol value (22.94 nmol/mg protein) were observed at $95^{\circ}C$ for 60 min. The heating time-temperature interaction affected several functional properties, including solubility, emulsifying potential, and gel strength (GS). Solubility decreased near the isoelectric point (pH 5 to 6). As the temperature and heating time increased, emulsifying properties decreased and GS increased. The oil absorption capacity and foaming properties decreased and the water absorption capacity increased. These results confirmed that PEYM is a suitable source of proteins for processing and applications in the food industry.

Structural and electrical properties of Ba(Sr,Ti)O3/K(Ta,Nb)O3 multilayer thin film for the application of electro-caloric devices

  • Kwon, Min-Su;Lee, Sung-Gap;Kim, Kyeong-Min;Choi, Seungkeun
    • Journal of Ceramic Processing Research
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    • 제20권6호
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    • pp.603-608
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    • 2019
  • In this study, the multilayered thin films of (Ba,Sr)TiO3/K(Ta,Nb)O3 were fabricated by the sol-gel and spin coating methods, and their structural and electrical properties were investigated. The specimen showed polycrystalline X-ray diffraction (XRD) characteristics with a tetragonal structure. The average grain size and film thickness for one coating were about 30~40nm and 60nm, respectively. The phase transition temperature of specimen was lower than 10 ℃. The dielectric constant and loss at 20 ℃ of the specimen coated six times were 1,231 and 0.69, respectively. The rate of change in dielectric constant at an applied direct current (DC) voltage of the six times coated thin films was 17.3%/V. The electrocaloric effect was the highest around the temperature at which the remanent polarization rapidly changed. When an electric field of 660kV/cm was applied to the triply coated thin films, the highest electrocaloric property of 4.41 ℃ was observed.

Physicochemical Properties and Antioxidant Effects of Fucoidans Degraded by Hydrogen Peroxide under Electron Beam at Various Irradiation Doses

  • Jeong, Gyeong-Won;Choi, Yoo-Sung
    • 공업화학
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    • 제33권3호
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    • pp.322-327
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    • 2022
  • Fucoidans were degraded by hydrogen peroxide under the electron beam (2.5 MeV) with various radiation doses (5 kGy, 10 kGy, 15 kGy, and 20 kGy) at room temperature. The degradation property was analyzed with a gel permeation chromatography (GPC-MALLS) method. An average molecular weight of fucoidan decreased from 99,956 at the irradiation dose of 0 kGy to 6,725 at the irradiation dose of 20 kGy. The solution viscosity of fucoidans showed a similar pattern to the molecular weight change. The number of chain breaks per molecule (N) increased with increasing the irradiation dose and concentration of hydrogen peroxide. The radiation yield of scission value markedly increased with increasing the irradiation dose up to 15 kGy. Also a 10% hydrogen peroxide concentration was more efficient than that of 5%. The structures of degraded fucoidan samples were studied with Fourier transform infrared spectroscopy (FT-IR). The results showed that the degradation process did not significantly change the chemical structure or the content of sulfate group. The sulfur content of each sample was determined with an Elemental Analyzer. With increasing the concentration of hydrogen peroxide, the ratios of sulfur/carbon, hydrogen/carbon, and nitrogen/carbon slightly decreased. The antioxidant activities of fucoidans were investigated based on hydroxyl radical scavenging activities. The ability of fucoidan to inhibit the hydroxyl radical scavenging activity was depended on its molecular weight.

Rheological, Physicochemical, Microbiological, and Aroma Characteristics of Sour Creams Supplemented with Milk Protein Concentrate

  • Chan Won Seo;Nam Su Oh
    • 한국축산식품학회지
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    • 제43권3호
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    • pp.540-551
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    • 2023
  • Milk protein concentrate (MPC) is widely used to enhance the stability and texture of fermented dairy products. However, most research has focused on yogurt products, and the effects of MPC on sour cream characteristics remain unknown. Therefore, we investigated the effects of different MPC levels (0%, 1%, 2%, and 3% w/w) on the rheological, physicochemical, microbiological, and aroma characteristics of sour creams in this study. We found that MPC supplementation stimulated the growth of lactic acid bacteria (LAB) in sour creams, resulting in higher acidity than that in the control sample due to the lactic acid produced by LAB. Three aroma compounds, acetaldehyde, diacetyl, and acetoin, were detected in all sour cream samples. All sour creams showed shear-thinning behavior (n=0.41-0.50), and the addition of MPC led to an increase in the rheological parameters (ηa,50, K, G', and G"). In particular, sour cream with 3% MPC showed the best elastic property owing to the interaction between denatured whey protein and caseins. In addition, these protein interactions resulted in the formation of a gel network, which enhanced the water-holding capacity and improved the whey separation. These findings revealed that MPC can be used as a supplementary protein to improve the rheological and physicochemical characteristics of sour cream.

방사선으로 제조된 가교 구조의 Poly(Styrene-Butadiene-Styrene) 블록 공중합체 특성에 관한 연구 (Study on the Physicochemical Properties of Crosslinked Poly(Styrene-Butadiene-Styrene) Block Copolymers Prepared by Radiation)

  • 이선영;송주명;손준용;신준화
    • 방사선산업학회지
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    • 제6권2호
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    • pp.171-176
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    • 2012
  • In this study, a crosslinked poly(styrene-butadiene-styrene) [SBS] block copolymers were prepared by using gamma ray irradiation method. The effects of various radiation doses on the degree of crosslinking, thermo property, and morphology of crosslinked SBS block copolymer were investigated. The degree of crosslinking of crosslinked SBS block copolymers were measured by gel-fraction and FT-IR. It was found that the degree of crosslinking of crosslinked SBS block copolymers increases with increase of the irradiation dose while the TGA result shows that the initial degradation temperature of irradiated SBS block copolymer was shifted to lower temperature with increasing irradiation dose. These results indicate that degradation reaction also occurs when SBS block copolymer is exposed to gamma ray irradiation for crosslinking reaction. The SAXS and FE-SEM results indicate that the phase separation of the styrene block and butadiene block was reduced with increasing irradiation dose.

Effect of medium molecular weight chitosan coating on quality of houndfish (Tylosurus crocodilus) during ice storage

  • Nguyen Thi Nhu Ha;Pham Thi Dan Phuong;Nguyen Cong Minh;Vo Trung Nguyen;Nguyen Thi Huynh Giao;Le Thi Minh Thuy
    • Fisheries and Aquatic Sciences
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    • 제27권9호
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    • pp.600-613
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    • 2024
  • This study assessed the applicability of medium molecular weight chitosan solution at different concentrations (0.5%, 1%, 1.5% and 2% w/v) in houndfish preservation. Furthermore, by comparing chitosan-coated fish and the uncoated ones (i.e., treated with distilled water [DW] and 1% acetic acid [AA] solution), the study determined the effectiveness of the chitosan coating on the preservation of on-skin houndfish during ice storage for 20 days. The quality of chitosan-coated houndfish was investigated by periodical analysis for microbiological (total viable count), chemical (pH, water holding capacity, total volatile basic nitrogen of refrigerated houndfish, thiobarbituric acid reactive substances, TCA-soluble peptide, and sodium dodecyl sulfate-polyacrylamide gel electrophoresis), physical parameters (hardness, and color), and sensory properties. According to the findings, the methods of using 1.5% and 2% chitosan solutions showed better preservation results than others. These methods were found to be the most effective coatings for maintaining the quality of houndfish compared to the treatments involving DW and 1% AA solution.

수분-열처리로 제조한 멥쌀가루의 호화 특성과 겔 강도 (Pasting Properties and Gel Strength of Non-Waxy Rice Flours Prepared by Heat-Moisture Treatment)

  • 서혜인;김창순
    • 한국식품영양과학회지
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    • 제40권2호
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    • pp.196-204
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    • 2011
  • HMT가 아밀로오스 함량이 다른 쌀가루의 이화학적 특성과 물리적 변화에 미치는 효과를 조사하였다. 고 아밀로오스 쌀은 태국산 수입쌀 TG(29.2%)와 국내산 특수미인 고아미GM(28.9%)을 사용하였고, 중간 아밀로오스 쌀은 추청미CC(23.6%)와 고시히카리 KSHK(21.2%)를 사용하였다. HMT 쌀가루는 습식제분 쌀가루를 수분함량 21%, 24%, 27%, 30%로 조절하여 각각 $100^{\circ}C$$105^{\circ}C$에서 30, 60, 90분 처리하여 제조하였다. HMT GM, HMT, TG 쌀가루의 RVA 특성 변화는 HMT 처리시간, 수분함량 증가에 따라 PV와 BD가 낮아지면서 peak가 사라지는 경향을 보였으며, HMT KSKH 쌀가루는 처리온도와 처리시간 증가에 의해 BD의 현저한 감소와 높은 FV값을 보였고, HMT CC는 다른 쌀가루에 비하여 현저한 PV와 SB 증가와 낮은 BD로 FV가 매우 크게 상승하였다. HMT GM과 HMT TG는 수분 21%, $100^{\circ}C$, 30분에서 HMT 효과가 크게 이루어졌으나 HMT CC와 HMT KSKH는 그보다 높은 $105^{\circ}C$ HMT 온도나 긴 처리 시간이 요구되는 것으로 나타났다. 모든 HMT 쌀가루의 BD는 수분함량, 처리온도와 처리시간이 증가함에 따라 감소하여 수분함량 30%, $105^{\circ}C$, 90분의 HMT 조건에서 최소값을 보였다. HMT로 모든 쌀가루의 팽윤력은 증가였으며 용해도는 CC 이외의 다른 쌀가루에서 모두 증가하였다. 무처리쌀가루시료의 겔 강도는 TG(79.23 g)> GM(38.24 g)> CC (32.26 g)> KSHK(25.66 g) 순이었고 HMT로 모든 쌀가루의 겔 강도는 증가하였으며, HMT GM과 HMT TG가 큰 증가폭을 보였다. 겔 강도는 SB(r=0.777, p<0.01)와 강한 양의 상관관계를, BD(r=-0.713, p<0.01)와 PV(r=-0.355, p<0.05)와는 음의 상관관계를 보여 HMT에 의해 쌀가루의 전분입자 내 분자 간 결합력 강화에 의한 BD 감소와 SB 증가가 겔 강도 상승에 영향을 미친 것을 알 수 있다.

Hypoallergenic and Physicochemical Properties of the A2 β-Casein Fractionof Goat Milk

  • Jung, Tae-Hwan;Hwang, Hyo-Jeong;Yun, Sung-Seob;Lee, Won-Jae;Kim, Jin-Wook;Ahn, Ji-Yun;Jeon, Woo-Min;Han, Kyoung-Sik
    • 한국축산식품학회지
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    • 제37권6호
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    • pp.940-947
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    • 2017
  • Goat milk has a protein composition similar to that of breast milk and contains abundant nutrients, but its use in functional foods is rather limited in comparison to milk from other sources. The aim of this study was to prepare a goat A2 ${\beta}$-casein fraction with improved digestibility and hypoallergenic properties. We investigated the optimal conditions for the separation of A2 ${\beta}$-casein fraction from goat milk by pH adjustment to pH 4.4 and treating the casein suspension with calcium chloride (0.05 M for 1 h at $25^{\circ}C$). Selective reduction of ${\beta}$- lactoglobulin and ${\alpha}_s$-casein was confirmed using sodium dodecyl sulphate-polyacrylamide gel electrophoresis and reverse-phase high-performance liquid chromatography. The hypoallergenic property of A2 ${\beta}$-casein fraction was examined by measuring the release of histamine and tumor necrosis factor alpha from HMC-1 human mast cells exposed to different proteins, including A2 ${\beta}$-casein fraction. There was no significant difference in levels of both indicators between A2 ${\beta}$-casein treatment and the control (no protein treatment). The A2 ${\beta}$-casein fraction is abundant in essential amino acids, especially, branched-chain amino acids (leucine, valine, and isoleucine). The physicochemical properties of A2 ${\beta}$-casein fraction, including protein solubility and viscosity, are similar to those of bovine whole casein which is widely used as a protein source in various foods. Therefore, the goat A2 ${\beta}$-casein fraction may be useful as a food material with good digestibility and hypoallergenic properties for infants, the elderly, and people with metabolic disorders.

난백분말과 유제품을 이용한 요구르트의 제조 (The Preparation of Yogurt from Egg White Powder and Milk Products)

  • 고영태
    • 한국식품과학회지
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    • 제29권3호
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    • pp.546-554
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    • 1997
  • 본 연구에서는 난백분말 3% (w/v)와 포도당 2% (w/v)에 4종의 유제품 4% (w/v)를 각각 첨가하여 기질을 만들고 젖산균(Lactobacillus)으로 발효하여 호상의 요구르트를 만든 후, 첨가된 유제품이 젖산균의 생육과 산생성 및 요구르트의 품질(관능성, 휘발성 향기 성분)에 미치는 영향을 조사하였다. L. acidophilus로 24시간 발효된 시료의 경우, 산도는 우유 시료(대조군)에 비하여 유제품 첨가 시료가 유의적으로 낮았으며(p<0.05), 유제품 첨가 시료 가운데는 카제인 시료의 산도가 가장 낮았다. 생균수는 우유 시료가 $2.0{\times}10^{9}/mL$인데 비하여 유제품 첨가 시료는 $5.0{\times}10^{8}{\sim}8.0{\times}10^{8}/mL$으로 현저하게 낮았다. L. acidophilus로 16.5시간 발효시켜 만든 호상요구르트의 관능성을 보면, 전반적인 기호도는 우유요구르트(표준시료)보다 유제품 첨가 시료가 저조하였으나 카제인 시료의 경우는 표준시료와 유의적인 차이를 보이지 않았으며(p<0.05), 유제품 첨가 시료 중에서는 유청 시료의 관능성이 가장 저조하였다. 본 실험에서 사용된 L. acidophilus (KCTC 2182)는 시료에 따라서 다소 차이가 있으나 발효 과정에 acetone, ethanol, diacetyl, acetoin을 생성하였다.

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