• Title/Summary/Keyword: gas-liquid mixing

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Two Cases of Chemical Burns by Hydrofluoric Acid (불화수소산에 의한 화학화상 2례)

  • Jang, Sung-Won;Sohn, You-Dong;Choi, Woo-Ik
    • Journal of Trauma and Injury
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    • v.19 no.2
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    • pp.173-177
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    • 2006
  • Hydrofluoric acid is a colorless gas or fuming liquid with a strong, irritating odor. Hydrofluoric acid burns are uncommon; however, if severe burn occur, they caused death from systemic effects, such as fatal cardiac arrthmia. We experienced two cases of hydrofluoric acid chemical burns on digits. These patients had typical clinical features of hydrofluoric acid chemical burns, such as pulsating pain at the burn site, as well as ischemic and necrotic skin changes. The hydrofluoric acid chemical burn was confirmed by a history of exposure. Subsequently, we made a calcium gluconate gel by mixing 20% calcium gluconate, an antagonist against hydrofluoric acid, with lubricant, and we injected 10% calcium gluconate subcutaneously when they complained of pain rated at higher than 5 on the pain scale. Simultaneously, we monitored the patients' electrocardiographs and checked their serum total calcium, ionized calcium, and magnesium levels serially. Clinical presentations and the emergency management of hydrofluoric acid chemical burns were reviewed along with the current literature. These patients were discharged without any significant complications.

Preparation of Coated-Wire Nitrate Ion Selective Electrode and its Application for Environmental Analysis (질산이온 선택성 피복선 전극의 제작 및 환경분석에의 응용)

  • 李龍根;金昌圭;朴廷泰;金京燮;黃圭子
    • Journal of Korean Society for Atmospheric Environment
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    • v.1 no.1
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    • pp.99-107
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    • 1985
  • A coated wire ion selective electrode for nitrate (nitrate-CWE_ was constructed using epoxy resin, ion exchanger and plasticizer as a polymer membrane. It's stility, the composition of a polymer membrane, the response characteristics, the selectivity were examined and applied to the environmental analysis. The nitrate-CWE was prepared using a copper wire, wihch was coated with epoxy resin being incorporated with the nitrate ion exchanger and plasticizer. The best composition of the polymer membrane for the nitrate-CWE was obtained by mixing epoxy resin, ion exchanger and plasticizer in the ratio of 2:1:0.4. The potential (56.3$\pm$0.5 mV) of stick form nitrate-CWE in this composition was close to that (59.2 mV) of Nernstian response. The detection limit for nitrate ion were found to the about $6 \times 10^{-5}M$ and the useful pH was 2.5 $\sim$ 10.3. Furthermore, the selectivity of iodide and perchrorate for the nitrage-CWE was also much improved compared with that for a liquid membrane nitrate electrode. The nitrate-CWE was used to determind $NO_x$ in stack gas. The results were in good agreement with those obtained either by electrode method or by the improved NEDA method within a relative error of 4.0%.

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Study on flow characteristics in entrained flow gasifier with high speed impinging jet (고속충돌노즐을 이용한 분류층 가스화기내의 유동특성에 관한 연구)

  • Lee, Hyo-Jin;Park, Tae-Jun;Lee, Jae-Gu;Kim, Jae-Ho;An, Dal-Hong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.5
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    • pp.1735-1742
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    • 1996
  • An entrained flow gasifier simulating the cold mode was tested to estimate its performance for coal gasification and flow characteristics with a developed high speed impinging jet nozzle. The burner was designed for high temperature and high pressure(HTHP) conditions, especially for IGCC(Integrated Coal Gasification Combined Cycle). In order to get proper size of droplets for high viscous liquid such as coal slurry, atomization was achieved by impacting slurry with high speed (over 150m/sec) secondary gas (oxygen/or air)/ Formed water droplets were ranged between 100.mu.m to 20.mu.m in their sizes. The flow characteristics in the gasifier was well understood in mixing between fuel and oxidizer. Both external and internal recirculation zones were closely investigated through experimentation with visualization and numerical solutions from FLUENT CODE.

A Numerical Study of Autoignition in a Confined Cylindrical Spray Combustor (밀폐된 원통형 분무 연소기내의 자연발화 현상에 관한 수치적 연구)

  • Choi, Ji Hun;Baek, Seung Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.6
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    • pp.778-787
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    • 1999
  • In this study, the autoignition process of liquid fuel, injected into hot and stagnant air in a 2-D axisymmetric confined cylindrical combustor, has been investigated. Eulerian-Lagrangian scheme was adopted to analyze the two-phase flow and combustion. The unsteady conservation equations were used to solve the transition of the gas field. Interactions between two phases were accounted by using the particle source in cell (PSI-Cell) model, which was used for detailed consideration of the finite rates of transports between phases. And infinite conduction model was adopted for the vaporization of droplets. The results have shown that the process of the autoignition consists of heating up of droplets, vaporization, mixing and ignition. The ignition criteria could be determined by the temporal variations of temperature, reaction rate and species mass fraction. And the effects of various parameters on ignition phenomena are examined. These have shown that the increasing the reaction rate and/or the vaporization rate can reduce the ignition delay time.

AC Electrical and Mechanical Properties of Epoxy-Nano-Microsilica Mixed Composites for Eco-Friendly GIS Spacer (친환경 GIS Spacer용, 에폭시-나노-마이크로실리카 혼합 콤포지트의 교류 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.9
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    • pp.1181-1188
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    • 2018
  • In order to develop new insulating materials for GIS Spacer using environmentally friendly insulating gas, three kinds of dispersed liquid nano composites of solid epoxy /nano layered silicate filled material were prepared. And the epoxy/nano/micro silica composite was prepared by mixing epoxy/nano 3 phr dispersion/4 kinds of filler contents(40,50,60, 70wt%). The electrical insulation breakdown strengths of the nano and nano/micro mixed composites were evaluated by using 8 kinds of samples including the original epoxy. The mechanical tensile strength of the epoxy / nano / micro silica composite were evaluated, also. The TEM was measured to evaluate the internal structure of nano/micro composites. As a result, it was confirmed that the layered silicate nano particles was exfoliated through the process of inserting epoxy resin between silicate layers and the layers. In addition, dispersion of nano / micro silica resulted in improvement of electrical insulation breakdown strength with increase of filling amount of dense tissue with nanoparticles inserted between microparticles. In addition, the tensile strength showed a similar tendency, and as the content of microsilica filler increased, the mechanical improvement was further increased.

The Recovery of Carbon Fiber from Carbon Fiber Reinforced Epoxy Composites for Train Body (철도차량용 폐 복합소재에서의 탄소섬유 회수)

  • Lee, Suk-Ho;Lee, Cheul-Kyu;Kim, Yong-Ki;Kim, Jung-Seok;Ju, Chang-Sik
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.406-415
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    • 2008
  • Recently, the amount of thermosetting plastic wastes have increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy composites, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that recovers carbon fibers from carbon fiber reinforced epoxy composites for train body was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

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Solid Phases in Polyphase Inclusions from North Ore Deposits, Dunjeon Gold Mine (둔전금광산 북광상에서 산출되는 다상포유물내의 고상)

  • Park, Hee-In;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.24 no.1
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    • pp.1-8
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    • 1991
  • North ore deposits of the Dunjeon gold mine is disseminated-stockworks deposits emplaced in Ordovician Dongjeom quartzite. Six types of fluid inclusions are recongnized in the stage I quartz. Among them polyphase inclusions(type-IV-A, B) are predominent in the lower part of stage I quartz crystals whereas liquid and gas inclusions(type I, II) are abundant in the upper part of the same quartz crystals. Liquid $CO_2$-bearing inclusions(type III-A, B)occur as pseudosecondary inclusions. Solid phases in polyphase inclusions are identified by using scanning electron microscopy combined with energy dispersive x-ray spectroscopy. The solid phases are as follows; halite, sylvite, hydrophyllite, quartz, muscovite, calcite, ankerite, K-Mg-Fe-Al-Si mineral, Ca-Fe-Si mineral, Mg-Al-Si mineral, two kinds of Fe-mineral and Cu-Fe mineral. Results of freezing and heating experiments of fluid inclusions and identification of daughter minerals in polyphase inclusions in the stage I quartz reveal that ore fluids were high saline system NaCl-KCl-$CaCl_2$-$H_2O$ in the earier stage and then evolved to rather simple system NaCl-$H_2O$ in the later stage, and temporally fluid mixing occured with system $CO_2$-$H_2O$. Homogenization temperatures and salinity of fluid inclusions in the stage I range from 290 to $454^{\circ}C$ and from 0.2 to 54.2 wt. % equivalent to NaCl.

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Study on the Stability Test of Impinging(FOOF) Injector on $GN_2$ Purge Cold Flow Test (질소분사 음향시험을 통한 충돌형(FOOF) 분사기의 안정성 평가에 관한 연구)

  • Yoo Doc-Koon;Lee Kwang-Jin;Seo Seong-Hyeon;Han Young-Min;Choi Hwan-Seok;Seol Woo-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.135-140
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    • 2006
  • In the experimental study of $N_2$ purge cold flow test of impinging(FOOF) injector for determining of instability region, the whistling sound which has a specific frequency is generated. The frequency of whistling is proportional to the gas flow velocity in part of the oxidizer orifice and due to the coupling of the vibrating gas column and the natural frequency of pipe-orifice shape, the discontinuous jumping phenomena arises. The whistling phenomena have no effect on the combustion instability. Compared the damping factor of 1T1L mode with the hot fire test, the instability region of $N_2$ purge cold flow test is very much like that. It means that flow instability by impinging or mixing of jet is the main reason of combustion instability of impinging injector(FOOF) in the hot firing test.

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A Study on the Optimization of Fuel Metering for the Lean Combustion System in a Gasoline Engine (I) (가솔린 자동차의 희박연소시스템 적용을 위한 연료공급 최적화에 관한 연구 (I) - 가솔린 인젝터의 연료분열특성에 관한 연구 -)

  • Yoon, S.J.;Cho, D.J.;Pang, D.Y.
    • Journal of ILASS-Korea
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    • v.3 no.3
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    • pp.33-41
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    • 1998
  • In recently, a study on the lean combustion is investigated intensively, because it is expected that this method may decrease the harmful exhaust gas and improve fuel economy in gasoline engine. The problems of lean combustion system in gasoline engine are ignition difficulty, misfire and instability of combustion. The investigation on the optimization of fuel metering and the control of mixing gas flow may be critical to improve the performance of lean combustion. In the fuel injection gasoline engine, the formation of mixture influences strongly on the engine performance such that the importance of fuel metering system becomes apparent. First of all, a study on the fuel breakup characteristics of gasoline fuel injector was carried out in this paper. Fuel injectors are pintle and 4hole-2spray type. The purpose of this study is to clarify the atomization mechanism of spray injected into atomosphere field through electronic controlled-fuel injectors, and to analyze spray characteristics such as drop size distribution and mean drop diameter produced at fuel injector. In this paper, the spray development is observed by taking photograps using 80mm still-camera system, and drop sizes are measured by PMAS. From these experiment, spray pattern injected from gasoline fuel injectors was investigated clearly. Also, it was found that SMD and drop size distribution of injected fuel spray from gasoline fuel injectors.

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Study on the Generation of Chemically Active Species Using Gas-liquid Mixing Plasma Discharging System (기-액 혼합 플라즈마 방전 시스템에서 화학적 활성종의 생성)

  • Kim, DongSeog;Park, YoungSeek
    • Journal of Korean Society on Water Environment
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    • v.30 no.4
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    • pp.394-402
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    • 2014
  • High-voltage dielectric discharges are an emerging technique in environmental pollutant degradation, which are characterized by the production of hydroxyl radicals as the primary degradation species. The initiation and propagation of the electrical discharges depends on several physical, chemical, and electrical parameters such as 1st and 2nd voltage of power, gas supply, conductivity and pH. These parameters also influence the physical and chemical characteristics of the discharges, including the production of reactive species such as OH, $H_2O_2$ and $O_3$. The experimental results showed that the optimum 1st voltage and oxygen flow rate for RNO (N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical) degradation were 160 V (2nd voltage of is 15 kV) and 4 L/min, respectively. As the 2nd voltage (4 kV to 15 kV) was increase, RNO degradation was increased and, generated $H_2O_2$ and $O_3$ concentration were increased. The conductivity of the solution was not influencing the RNO degradation, $H_2O_2$ and $O_3$ generation. The pH effect on RNO degradation was not high. However, the lower pH and the conductivity, the higher $H_2O_2$ and $O_3$ generation were observed.