• Title/Summary/Keyword: gas using environment

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Seasonal Variation of Nitrate in the Greater Seoul Area Using a Photochemical Box Model and a Gas/Aerosol Equilibrium Model (광화학 상자모델과 기체/입자 평형모델을 이용한 서울ㆍ수도권의 계절별 질산염 농도 변화)

  • Lee S.;Ghim Y. S;Kim Y. P;Kim J. Y
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.729-738
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    • 2004
  • Seasonal variation of major inorganic ions in the greater Seoul area was estimated using a photochemical box model and a gas/aerosol equilibrium model with emphasis on semi -volatile nitrate. Pollutant emission was determined by season by comparing the predicted concentration with the measurement one obtained for a year from the late 1996. The results showed that particulate nitrate was the highest in summer but about 40% of total nitrate was present in the gas phase. This was due to volatilization at high temperature since ammonia was sufficient to neutralize all nitrate regardless of season. As relative humidity in summer was higher than the deliquescence point, particulate ion concentration with water was two times higher than that in other season. So called ‘NOx disbenefit’ indicating increase in particulate ion concentration with decrease in NOx emission was evident especially in winter.

Optimal LNG Procurement Policy in a Spot Market Using Dynamic Programming (동적 계획법을 이용한 LNG 현물시장에서의 포트폴리오 구성방법)

  • Ryu, Jong-Hyun
    • Journal of Korean Institute of Industrial Engineers
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    • v.41 no.3
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    • pp.259-266
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    • 2015
  • Among many energy resources, natural gas has recently received a remarkable amount of attention, particularly from the electrical generation industry. This is in part due to increasing shale gas production, providing an environment-friendly fossil fuel, and high risk of nuclear power. Because South Korea, the world's second largest LNG importing nation after Japan, has no international natural gas pipelines and relies on imports in the form of LNG, the natural gas has been traditionally procured by long term LNG contracts at relatively high price. Thus, there is a need of developing an Asian LNG trading hub, where LNG can be traded at more competitive spot prices. In a natural gas spot market, the amount of natural gas to be bought should be carefully determined considering a limited storage capacity and future pricing dynamics. In this work, the problem to find the optimal amount of natural gas in a spot market is formulated as a Markov decision process (MDP) in risk neutral environment and the optimal base stock policy which depends on a stage and price is established. Taking into account price and demand uncertainties, the basestock target levels are simply approximated from dynamic programming. The simulation results show that the basestock policy can be one of effective ways for procurement of LNG in a spot market.

CF4 Treatment Characteristics using an Elongated Arc Reactor (신장 아크 반응기를 이용한 CF4 처리특성)

  • Kim, Kwan-Tae;Lee, Dae-Hoon;Lee, Jae-Ok;Cha, Min-Suk;Song, Young-Hoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.85-93
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    • 2010
  • $CF_4$ removal characteristics were investigated using an elongated arc reactor. The advantage of the elongated arc reactor includes direct use of treated gas as plasma operating gas and the enhancement of the removal reaction by using a thermo-chemistry and a plasma induced chemistry at the same time. Geometrical configurations, such as the length of the reactor and the shape of a throat, were tested to get an optimized removal efficiency with low power consumption. As results, over 95% of $CF_4$ removal was obtained with 300 lpm of total flowrate for various $CF_4$ concentration (0.1~1%). Corresponding specific energy density (SED), which means required electrical energy to treat the unit volume of treated gas, is about 3.5 kJ/L, The present technique can be applied to real applications by satisfying three major concerns, those are the high flowrate of treated gas, high removal efficiency (> 95%), and low power consumption (< 10 kJ/L).

폐기물 매립지 토양에서의 PCBs 분석법

  • Lee Jeong-Hwa;Jeon Chi-Wan;Jeong Yeong-Uk
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.199-201
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    • 2005
  • This paper describes a simple procedure for the quantitative analysis of 7 PCBs (polychlorinated biphenyls) in soils on the waste reclaimed land, The procedure involved sample clean up using silicagel column, acetonitrile partition and sulfuric acid procedures. The instrumental technique is applied GC/PDD(gas chromatography/pulsed discharge detector) and GC/ECD(gas chromatography/electron capture detector). Concentration of $sub-{\mu}g/g$ level was attainable with 20g soils on the waste reclaimed land.

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Investigation of Elemental Mercury Oxidation on Commercial SCR Catalysts in Flue Gas of Fossil Fired Power Plant (상용 SCR 촉매상에서 화력발전소 배기가스 중 원소수은의 산화반응연구)

  • Lee, Seung-Min;Lee, Jung-Bin
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.3
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    • pp.245-252
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    • 2010
  • For the purpose of evaluating to remove elemental mercury using SCR (Selective Catalytic Reduction) catalysts, the result of the concentration variation of elemental mercury in lab experiment and field measurement was compared. The effect of the elemental mercury oxidation on commercial catalysts was studied in simulated gas. Three species of SCR catalyst, $V_2O_5-TiO_2$ type, were selected. The elemental mercury reduced 30% without HCl gas in SCR operating condition. But the width of reduction increased 60% at 20 ppm HCl gas. According to the result of field measurement, reduction rate of elemental mercury at SCR outlet showed 60%. The total mercury concentration decreased about 20%. The results were similar to the lab test. The results of chemical analysis of test sample showed increase of mercury concentration but surface change was not observed.

Removal of Hydrogen Sulfide Using Porous Ceramic Biofilter Inoculated with Sulfur Oxidizing Bacteria (황산화 균주가 부착된 다공성 세라믹 biofilter를 이용한 $H_2S$ 제거)

  • 박상진;조경숙
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.649-655
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    • 1999
  • Biofiltration of polluted gas streams contained $H_2S$ was studied. The experiments were performed in a laboratory-scale reactor with a porous ceramic media inoculated with sulfur oxidizing bacterium, TAS which was isolated from activiated sludge. The concentration of $H_2S$ in the inlet gas varied from 109 to 3,841 ppm, at the various space velocities(SV) of 50 $h^{-1}$ to 250 $h^{-1}$. Various tests have been conducted to evaluate the effects of such parameters as pH, concentration of sulfate ion and retention time on the pressure drop and maximum elimination capacity. The removal efficiency of $H_2S$ decreased as the $H_2S$ concentration or gas velocity increased in the inlet gas. Pressure drop was insignificant in this system. The maximum elimination capacity could reach up to 16.35g-S/kg-dry packing material/day.

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Adsorption properties of magnesium oxide matrix using anthracite and vermiculite (안트라사이트와 버미큘라이트를 혼입한 산화마그네슘 경화체의 흡착특성)

  • Kim, Dae-Yeon;Pyeon, Su-Jeong;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.224-225
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    • 2018
  • Modern people are more interested in the indoor environment as they spend more time indoors than in the past. Among the air pollutants in the indoor air, ladon gas is a colorless, tasteless, odorless, inert gas produced by nuclear decomposition of naturally occurring uranium in rocks and soils. It has been proven that ladon gas is introduced into the room through cracks on the floor of the building or basement wall, and it causes various diseases such as lung cancer when exposed to radon during human breathing. The US Environmental Protection Agency (EPA) specifies 4pCi / L as a necessary measure for radon, and the Korea Environmental Protection Agency has implemented comprehensive indoor radon management measures since 2007. Therefore, in this study, we intend to adsorb and reduce radon in indoor air pollutants.

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A Study on Off-Gas Treatment of an Air Stripping Tower Using a Plasma Reactor

  • Lim, Gye-Gyu;Yoo, Ho-Sik
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.E
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    • pp.382-389
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    • 1993
  • An evaluation of a plasma reactor was conducted to investigate its potential as a feasible and economical off-gas control technology for an air stripping tower (AST). The plasma reactor was powered by an alternating current with frequencies up to 1000Hz. The study showed that over 90% conversion of gas-phase trichloroethylene (TCE) can be achieved. An optimum frequency for the laternating current existed for maximum power input. The optimum frequency was dependent on the reactor geometry and the primary voltage applied. for a fixed geometry, a plasma reactor has a limited capacity for flow rate. Even though it is a feasible process to control off-gases, further investigations should be conducted to develop a more economic process.

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Removal of Non-volatile Contaminant from Aquifer using Surfactant-enhanced Ozone Sparging (오존과 계면활성제를 이용한 대수층 내 비휘발성 물질 제거)

  • Yang, Su-Kyeong;Shin, Seung-Yeop;Kim, Heon-Ki
    • Journal of Soil and Groundwater Environment
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    • v.15 no.6
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    • pp.37-45
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    • 2010
  • Surfactant-enhanced ozone sparging (SEOS), an advanced version of SEAS (surfactant-enhance air sparging) was introduced in this study for the first time for removal of non-volatile contaminant from aquifer. The advantages of implementing SEAS, enhanced air saturation and expanded zone of sparging influence, are combined with the oxidative potential of ozone gas. Experiments conducted in this study were tow fold; 1-dimensional column experiments for the changes in the gas saturation and contaminant removal during sparging, and 2-dimensional box model experiment for the changes in the size of zone of influence and contaminant removal. An anionic surfactant (SDBS, sodium dodecylbenzene sulfonate) was used to control surface tension of water. Fluorescein sodium salt was used as a representative of watersoluble contaminants, for its fluorescence which is easy to detect when it disappears due to oxidative degradation. Three different gases (air, high-concentration ozone gas, and low-concentration ozone gas) were used for the sparging of 1-D column experiment, while two gases (air and low-concentration ozone gas) were used for 2-D box model experiment. When SEOS was performed for the column and box model, the air saturation and the zone of influence were improved significantly compared to air sparging without surface tension suppression, resulted in effective removal of the contaminant. Based on the experiments observations conducted in this study, SEOS was found to maintain the advantages of SEAS with further capability of oxidative degradation of non-volatile contaminants.