• Transactions of the Korean hydrogen and new energy society
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• v.30 no.2
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• pp.111-118
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• 2019

Greenhouse gas emissions have a profound effect on global warming. Various environmental regulations have been introduced to reduce the emissions. The largest amount of greenhouse gases, including carbon dioxide, is produced in the steel industry. To decrease carbon dioxide emission, hydrogen-based iron oxide reduction, which can replace carbon-based reduction has received a great attention. Iron production generates various by-product gases, such as cokes oven gas (COG), blast furnace gas (BFG), and Linz-Donawitz gas (LDG). In particular, COG, due to its high concentrations of hydrogen and methane, can be reformed to become a major source of hydrogen for reducing iron oxide. Nevertheless, continuous COG cannot be supplied under actual operation condition of steel industry. To solve this problem, this study proposed to use two alternative COG-based fuel mixtures; one with natural gas and the other with biogas. Reforming study on two types of mixed gas were carried out to evaluate catalyst performance under a variety of operating conditions. In addition, methane conversion and product composition were investigated both theoretically and experimentally.

• Journal of the Korean Institute of Gas
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• v.24 no.5
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• pp.65-73
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• 2020

To reduce the hydrogen production cost through the utilizing the oxygen and improving the capacity factor of water electrolysis used to energy storage of renewable energy, the hybrid hydrogen production process which has dual operating concept of using the water electrolysis as energy storage and oxygen production process for biomass gasification was proposed. Moreover, Techno-economic analysis on this system was quantitatively performed.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.5
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• pp.397-403
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• 2009

The catalysis of carbon black was investigated for the production of hydrogen by the catalytic decomposition of propane-butane mixture gas in this study. The thermal and the catalytic decompositions of hydrocarbons were performed at the temperature range of 500 - $1100^{\circ}C$, respectively. The conversions of hydrocarbons and the mole traction of hydrogen increased with increasing the reaction temperature and the conversion of hydrocarbons in the catalytic decomposition process was approximately liked with that obtained by the thermal decomposition. However, the mole traction of hydrogen produced in the catalytic decomposition process was higher than that obtained from the thermal decomposition. Therefore, it was concluded that the catalysis for the decomposition of hydrocarbons is occurred over carbon black used as catalyst. The mole traction of hydrogen produced by the catalytic decomposition of hydrocarbons also increased with increasing the mole ratio of $C_3H_8/C_4H_{10}$ in propane and butane mixture gas at $700^{\circ}C$. Therefore, it was concluded that the catalytic decomposition of the high propane mixture gas is more effectively for the production of hydrogen.

• Korean Journal of Food Science and Technology
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• v.26 no.3
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• pp.195-198
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• 1994

A bubble counter was designed and fabricated for the measurement of gas production rate on the basis of number of bubbles produced from yeast fermentor. The sensor was consisted of bubble forming device and electronic signal processing circuitry. The bubble forming device was built with bubble collector and liquid cell to form uniform size of bubble. Bubbles were counted by pulses formed by photo-interrupter circuitry having 8-bit binary latch counter. The gas production rate curves on the basis of bubble counted showed a good agreement to that of growth curves obtained by the optical measurement method. The sensor was succesfully applied to monitoring of the nutrient utilization test with glucose and galactose media.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2850-2855
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• 2008

Very High Temperature Reactor (VHTR) has been selected as a high energy heat source for a nuclear hydrogen generation. The VHTR heat is transferred to a thermo-chemical hydrogen production process through an intermediate loop. Both Process Heat Exchanger and sulfuric acid evaporator provide the coupled components between the VHTR intermediate loop and hydrogen production module. A small scaled Compact Nuclear Hydrogen Coupled Components test loop is developed to simulate the VHTR intermediate loop and hydrogen production module. Main objective of the loop is to screening the candidates of NHDD (Nuclear Hydrogen Development and Demonstration) coupled components. The operating condition of the gas loop is a temperature up to $950^{\circ}C$ and a pressure up to 6.0MPa. The thermal and fluid dynamic design of the loop is dependent on the structures that enclose the gas flow, especially primary side that has fast gas velocity. We designed and constructed a small scale sulfuric acid experimental system which can simulate a part of the hydrogen production module also.

• Environmental and Resource Economics Review
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• v.31 no.4
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• pp.597-617
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• 2022

In this study, consumption-based greenhouse gas emissions from 1990 to 2021 are calculated by the industry sector, and greenhouse gas emissions transferred due to trade between countries are compared to analyze what implications Korea has. As a result, production-based and consumption-based emissions in the United States, Germany, the EU, and the OECD are gradually decreasing. Production-based emission in Korea is larger than consumption-based emissions because Korean economic structure is import-oriented. However, unlike other developed countries, Korea cannot trade energy by land, so it can be said that it is reasonable to establish a greenhouse gas reduction plan considering Korea's unique characteristics.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.4
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• pp.362-370
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• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.3
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• pp.128-134
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• 2016

An analysis of the main factors and its degree of impact on power production is performed against the landfill gas power plant in S landfill site. The number of normal operation (50 MWh & 24 hr) days was 70.9% to the total number of operation days from 2007 to 2014, and the percentage of the actual power production was 79.3% of 3,428,400 MW which is the theoretical maximum estimation. The ratio of factors that accounted for the efficiency of power production are: 44.0% of repairing of the defect and regular servicing, 37.4% of cut-down operation due to hydrogen sulfide, and 18.6% of air pre-heater washing, respectively. Yet, considering that the cut-down operation due to hydrogen sulfide was carried out for only two years, the high concentration of hydrogen sulfide was the most influential factors on landfill gas power production. The long-term power production was analyzed as 35.9 MWh in 2018, and the constant drop is anticipated, resulting in 16.6 MWh by 2028, and under 8.4 MWh in 2038.

• Journal of the Korean Institute of Gas
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• v.17 no.2
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• pp.59-69
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• 2013

This study presents development of the ANN simulator for well placement of infill drilling in gas fields. The input data of the ANN simulator includes the production time, well location, all inter well distances, boundary inter well distance, infill well position, productivity potential, functional links, reservoir pressure. The output data includes the bottomhole pressure in addition to the production rate. Thus, it is possible to calculate the productivity and bottomhole pressure during production period simultaneously, and it is expected that this model could replace conventional simulators. Training for the 20 well placement scenarios was conducted. As a result, it was found that accuracy of ANN simulator was high as the coefficient of correlation for production rate was 0.99 and the bottomhole pressure 0.98 respectively. From the resultes, the validity of the ANN simulator has been verified. The term, which could produce Maximum Daily Quantity (MDQ) at the gas field and the productivity according to the well location was analyzed. As a result, the MDQ could be maintained for a short time in scenario C-1, which has the three infill wells nearby aquifer boundary, and a long time in scenario A-1. In conclusion, it was found that scenario A maintained the MDQ up to 21% more than those of scenarios B and C which include parameters that might affect the productivity. Thus, the production rate can be maximized by selecting the location of production wells in comprehensive consideration of parameters that may affect the productivity. Also, because the developed ANN simulator could calculate both production rate and bottomhole pressure, respectively, it could be used as the forward simulator in a various inverse model.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.1
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• pp.131-138
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• 2006

In this study, the optimum condition of pH was investigated on the hydrogen gas production under anaerobic fermentation process. The results of the experiment showed that the optimum condition was observed at pH 6, resulting in 1175.87 mL/L of hydrogen gas production rate and 22.51% theoretical hydrogen conversion ratio. Hydrogen gas production rate and theoretical hydrogen conversion ratio were 901.77 mL/L and 17.48 % respectively at pH 5. At pH 7 and 8, the production rate of hydrogen gas was little low as 82.15 mL/L. Among the organic acids from the sucrose fermentation, propionate was observed as the dominant acid at pH 7 and 8 but butyrate was the dominant at pH 5 and 6.