• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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• pp.569-572
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• 2003

Titanium dioxide ($TiO_2$) nanoparticles were prepared by the oxidation of titanium tetrachloride ($TiCl_4$) in a diffusion flame reactor. The average diameter of particles was 15 to 30 nm and mass fraction of anatase ranged from $40\;to\;80\%$. Effects of particle size and phase composition of those $TiO_2$ nanoparticles on photocatalytic properties such as decomposition of methylene blue and bacteria gas were investigated. The degree of decomposition of methylene blue by the $TiO_2$ nanoparticles under the illumination of the black light was directly proportional to the anantase mass fraction, but inversely to the particle size. The decomposition of bacteria by the $TiO_2$ nanoparticles under the illumination of the fluorescent light showed the same trend as in the case of the methylene blue.

• Bulletin of the Korean Chemical Society
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• 제24권5호
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• pp.610-612
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• 2003

Octanethiol ($CH_3(CH_2)_7SH$) based self-assembled monolayer on Cu(111) in ultra-high vacuum has been examined using x-ray photoelectron spectroscopy (XPS), temperature programmed desorption (TPD), intergrated desorption mass spectrometry (IDMS), and contact angle analysis. The results show that the octanethiolate monolayers similar to those on gold are formed on Cu(111). The monolayers are stable up to temperatures of about 480 K. Above 495 K the monolayers decompose via the γ-hydrogen elimination mechanism to yield 1-octene in the gas phase. The thiolate head groups on the copper surface change to Cu₂S following the decomposition of hydrocarbon fragments in the monolayers at about 605 K.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2008년도 추계학술대회 논문집
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• pp.406-415
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• 2008

Recently, the amount of thermosetting plastic wastes have increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy composites, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that recovers carbon fibers from carbon fiber reinforced epoxy composites for train body was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

• 청정기술
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• 제22권3호
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• pp.190-195
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• 2016

회전식 소각공정은 고에너지 물질의 폐기처리를 위해 현재 상용화 되고 있는 기술로 열풍을 이용하여 대상물질을 열분해하는 공정이며 TNT, RDX 및 Composition B를 통한 열분해 공정의 사전연구가 진행되었다. 본 연구의 대상물질은 나이트로셀룰로스(nitrocellulose, NC)와 나이트로글리세린(nitroglycerine, NG)의 혼합물인 더블베이스 추진제(M8)로 선정하였다. M8 추진제의 열분해 반응은 응축상 반응(condensed phase reaction, CPR)과 기체상 반응(gas phase reactions, GPRs)로 구성되어 있다. CPR의 경우 흡열반응으로 4가지 화합물을 생성하며, GPRs의 경우 59개의 가스화합물 및 365개의 흡열·발열 반응으로 구성되어 있다. 본 연구는 gPROMS 소프트웨어를 이용하여 관형반응기의 수학적 모델링을 완성하였으며, 운전온도 및 유속 변화에 따른 케이스스터디를 진행하였다. 상대적으로 낮은 유속 및 높은 공정온도는 반응기의 내부온도(Case3: 953 K, Case6: 1300 K)를 상승 시켰으며, CO₂와 H₂O 몰농도 값 상승을 통해 완전연소율이 증가하는 것을 확인할 수 있었다. 본 연구 내열형 소각로 설계, 운전조건을 도출하는데 있어 기초 자료로 활용될 수 있을 것으로 사료된다.

• 한국연소학회지
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• 제22권2호
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• pp.1-8
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• 2017

To evaluate the combustion instability of a gas turbine combustor, the DMD technique was applied. The mode frequency results for each fuel composition were compared with FFT(Fast Fourier Transform) results. The damping coefficient, which is a quantitative parameter for combustion instability, was evaluated for 5 experimental cases. The flame transfer function (FTF) was calculated in the most unstable test case. In deriving the FTF, gain and phase were calculated using DMD technique. As a result of the analysis of the OH radical perturbation of the DMD, the heat release fluctuation was the highest at 100 Hz, at which the highest value of gain is observed. The frequency of FFT and FTF were different. In order to clarify the reason for this, FTF for various resonance frequencies was performed and it shows that the pattern of gain was similar to FFT.

• Bulletin of the Korean Chemical Society
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• 제24권6호
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• pp.853-858
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• 2003

The reaction mechanism of the pyrolysis of sulphonyl oximes ($CH_3-C_6H_4-S(O)_2O-N=C(H)-C_6H_4Y$), in the gas phase is studied theoretically at HF/3-21G, ONIOM (B3LYP/6-31G**:HF/3-21G) and ONIOM (MP2/6- 31G**:HF/3-21G) levels. All the calculations show that the thermal decomposition of sulphonyl oximes is a concerted asynchronous process via a six-membered cyclic transition state. The activation energies (Ea) predicted by ONIOM (B3LYP/6-31G**: HF/3-21G) method are in good agreement with the experimental results for a series of tosyl arenecarboxaldoximes. Five para substituents, Y = $OCH_3$, $CH_3$, H, Cl, and $NO_2$, are employed to investigate the substituent effect on the elimination reaction. Linear Hammett correlations are obtained in all calculations in contrast to the experimental finding.

• Bulletin of the Korean Chemical Society
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• 제12권1호
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• pp.97-101
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• 1991

Gas-phase pyrolyses of carbonate esters, ${\alpha}$- and ${\beta}$-hydroxy esters and ${\beta}$-hydroxy ketones have been studied theoretically by the AM1 MO method. Carbonate esters were found to decompose by two types of processes; in the reaction pathway involving an intermediate, the decomposition of the intermediate was rate-limiting, but direct pyrolyses were also possible via a six-membered cyclic transition state in which the methoxy oxygen attacks a hydrogen atom on the ${\beta}$-carbon. The hydroxy esters and ketones were found to decompose in a concerted process involving a six-membered cyclic transition state. Successive methylation on the ${\alpha}$- and ${\gamma}$-carbon led to an increase in the reactivity in agreement with experiments.

• Bulletin of the Korean Chemical Society
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• 제12권5호
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• pp.560-564
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• 1991

The gas-phase pyrolysis reactions of iminoethers (Ⅱ), 2-alkoxypyridines (Ⅲ), 2-N-alkylated pyridones (Ⅳ) and N-alkylated acetamides (Ⅴ) have been studied MO theoretically with the AM1 method. The decomposition of these compounds proceeds by a concerted retro-ene process through a six-membered cyclic transition state. The reactivity decreases in the order (Ⅱ) > (Ⅲ) > (Ⅳ) > (Ⅴ), with a greater reactivity for the imine series, (Ⅱ) and (Ⅲ), compared to the amide series, (Ⅳ) and (Ⅴ), and a difference in basicity between the N and O atoms. Within a given series, however, the reactivity is dictated mainly by the aromaticity in the transition state. The reactivity order with respect to side alkyl chain of a species was found to increase as the steric crowding effect increases. The AM1 reactivity in this work agree well with the experimental results.

• 한국수산과학회지
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• 제50권6호
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• pp.837-840
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• 2017

We developed a method to rapidly evaluate the freshness of fish using a sensor gas chromatography (SGC) system. Mackerel Scomber japonicus was stored at $4^{\circ}C$ for 12 days to create an environment similar to the natural decomposition process. Trimethylamine (TMA) content in mackerel muscle was measured at 3-day intervals using a spectrophotometer. The gas-phase concentration of TMA in whole mackerel was also determined using an SGC system. The muscle TMA content increased over time during storage, as did the gas-phase concentration of TMA. Therefore, this study demonstrated that an SGC system can be used to rapidly measure the gas-phase concentration of TMA in fish during processing.

• 공업화학
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• 제7권6호
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• pp.1027-1033
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• 1996

쌍극자물질에 전자파를 조사하면 그 파동의 변화에 따라 분자가 진동하며, 이웃 분자와 마찰을 일으켜 물질 내부로부터 가열되는 독특한 현상을 보인다. 따라서 고체인 전자파흡수제에 흡착시킨 쌍극자 기체를 microwave energy로 쉽게 파괴할 수 있다. 연소기기 배출가스에서 산성가스 제거공정 개발을 위하여 이 방법에 의한 산성가스 분해실험을 실시하였다. Calcined char는 전자파흡수제 및 가스 흡착제로서의 역할을 하는데, NO와 $SO_2$를 함유한 표준가스를 char bed내로 통과시키면서 microwave를 조사하였다. Microwave가 조사되고 있는 20 gram의 char bed를 통과하는 동안 95% 이상의 NO와 70% 이상의 $SO_2$가 환경적으로 무해한 단체원소로 분해되었으며, 분해된 원소 중 산소기는 char의 기공내에서 탄소와 반응하여 $CO_2$를 형성하며 char의 기공도 및 표면적 증대효과를 가져왔다. 일반적인 상업적 연소공정에서 처럼 이보다 낮은 농도에서는 거의 완전한 분해가 가능하리라 보여지며, 대기오염 방지에 좋은 방법이 되리라 믿어진다.