• 제목/요약/키워드: gas phase

검색결과 3,267건 처리시간 0.031초

Gas-particle Partitioning of Organochlorine Pesticides in Atmosphere (대기 중 유기염소계 살충제의 가스-입자 분배)

  • Choi, Min-Kyu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • 제23권4호
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    • pp.457-465
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    • 2007
  • This study was performed to estimate the gas-particle partitioning of organochlorine pesticides (OCPs) in atmosphere, the samples were collected by PUF high volume air sampler for two years from June, 2000 to June, 2002. The gas phase fraction of ${\alpha/\gamma}-HCH$, heptachlor epoxide, ${\alpha/\gamma}-chlordane$ and trans-nonachlor was over 90%. But the gas phase fraction of ${\beta}-HCH$, p,p'-DDE, endosulfan sulfate, p,p'-DDD and p,p'-DDT was range of 20% through 80%, which means the gas phase fraction of OCPs components described above is sensitive to temperature. The correlation between the gas phase fraction and molecular weight of each OCPs component was not found in this research. The slope of regression line between gas-particle partitioning coefficient(${\log}K_p$) and subcooled liquid vapor(${\log}{P^o}_L$), gal-particle partitioning coefficient(${\log}K_p$) and octanol-air partitioning coefficient(${\log}K_{oa}$) which show -0.54 and 0.43 was not steep. So the equilibrium state between gas and particle was not reached and in this state the particulate fraction was low.

Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (II) (수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향)

  • Kim, Byeong-Ju;Lee, Chan-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제22권4호
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    • pp.499-509
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    • 1998
  • In the absorption process of water vapor in a liquid film, the composition of the gas phase, in which a non-absorbable gas is combined with the absorbate influences the transport characteristics remarkably. In the present study, the absorption processes of water vapor into aqueous solution of lithium bromide in the presence of non-absorbable gases were investigated analytically. The continuity, momentum, energy and diffusion equations for the solution film and gas phase were formulated in integral forms and solved numerically. It was found that the mass transfer resistance in gas phase increased with the concentration of non-absorbable gas. However the primary resistance to mass transfer was in the liquid phase. As the concentration of non-absorbable gas in the absorbate increased, the liquid-vapor interfacial temperature and concentration of absorbate in solution decreased, which resulted in the reduction of absorption rate. The reduction of mass transfer rate was found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of an absorber where non-absorbable gases accumulated. At higher non-absorbable gas concentration, the decrease of absorption flux was almost linear to the volumetric concentration of non-absorbable gas.

A Study on the Mixture Formation Process of Diesel Fuel Spray in Unsteady and Evaporative Field

  • Yeom, Jeong-Kuk;Park, Jong-Sang;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • 제19권12호
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    • pp.2253-2262
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    • 2005
  • The focus of this work is placed on the analysis of the mixture formation mechanism under the evaporative diesel spray of impinging and free conditions. As an experimental parameter, ambient gas density was selected. Effects of density variation of ambient gas on liquid and vapor-phase inside structure of evaporation diesel spray were investigated. Ambient gas density was changed between ${\rho}a=5.0\;kg/m^3$ and $12.3\;kg/m^3$. In the case of impinging spray, the spray spreading to the radial direction is larger due to the decrease of drag force of ambient gas in the case of the low density than that of the high density. On the other hand, in the case of free spray, in accordance with the increase in the ambient gas density, the liquid-phase length is getting short due to the increase in drag force of ambient gas. In order to examine the homogeneity of mixture consisted of vapor-phase fuel and ambient gas in the spray, image analysis was conducted with statistical thermodynamics based on the non-dimensional entropy (S) method. In the case of application of entropy analysis to diesel spray, the entropy value always increases. The entropy of higher ambient density is higher than that of lower ambient gas density during initial injection period.

Performance improvement of wave plate mist eliminator through geometry modification (Wave plate 습분제거기의 형상 변경을 통한 성능 개선)

  • Jung-Hun, Noh;Min-Cheol, Cho;Seung-Jong, Lee
    • Particle and aerosol research
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    • 제18권4호
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    • pp.97-107
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    • 2022
  • The geometry of popular wave plate type mist eliminator for the wet flue gas desulfurization process was improved, fabricated, and experimentally evaluated. A Mist eliminator is a type of inertial particle collector which collection efficiency is proportional to the velocity of the gas phase. However, as the amount of re-entrainment is also proportional to the gas phase velocity, there is a limitation for the gas phase flow rate. Re-entrainment is one of the most important issues in a mist eliminator and is likely to occur as the input of the liquid phase and flow rate of the gas phase increase. In order to resolve this problem, the projection angle of the improved mist eliminator is set to 30° from the conventional one while maintaining the cross-section. With low flow rate conditions, the modified mist eliminator showed a similar pressure drop and overall collection efficiency. However, with conditions in which re-entrainment is obviously occurring, the modified mist eliminator showed better performance in draining droplets than the conventional one. As a result, the modified mist eliminator showed higher overall collection efficiency.

Numerical Analysis of Plume Characteristics and Liquid Circulation in Gas Injection Through a Porous Plug

  • Choi, Choeng-Ryul;Kim, Chang-Nyung
    • Journal of Mechanical Science and Technology
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    • 제14권12호
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    • pp.1365-1375
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    • 2000
  • Two phase flows have been numerically calculated to analyze plume characteristics and liquid circulation in gas injection through a porous plug. The Eulerian approach has been for formulation of both the continuous and dispersed phases. The turbulence in the liquid phase has been modeled using the standard $textsc{k}$-$\varepsilon$ turbulence model. The interphase friction coefficient has been calculated using correlations available in the literature. The turbulent dispersion of the phase has been modeled by the "dispersion Prand시 number". The predicted mean flows is compared well with the experimental data. The plume region area and the axial velocities are increased with the gas flow rate and with the decrease in the inlet area. The turbulent intensity also shows the same trend. Also, the space-averaged turbulent kinetic energy for various gas flow rates and inlet areas has been obtained. The results are of interest in the design and operation of a wide variety of materials and chemical processing operations.

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Two-phase flow and heat transfer characteristics in a submerged gas injection system (잠겨진 가스분사장치에서의 2상 유동 및 열전달 특성)

  • 최청렬;김창녕
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • 제11권6호
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    • pp.824-834
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    • 1999
  • Characteristics of two-phase flow and heat transfer were numerically investigated in a submerged gas injection system when temperature of the injected gas was different from that of the liquid. The Eulerian approach was used for both the continuous and dispersed phases. The turbulence in the liquid phase was modeled using the standard $k-\varepsilon$$\varepsilon$ turbulence model. The interphase friction and heat transfer coefficient were calculated from the correlations available in the literature. The turbulent dispersion of the phases was modeled by a "dispersion Prandtl number". In the case with heat transfer where the temperature of the injected gas is higher than the mean liquid temperature, the axial and the radial velocities are lower in comparison with the case of homogeneous temperatures. The results in the present research are of interest in the design and operation of a wide variety of material and chemical processes.

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A Study on the Concentration Characteristics of Atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) in Chongju

  • Lee, Hak-Sung;Kang, Byung-Wook;Kwon, Dong-Hyuk;Yeo, Hyun-Gu;Chun, Man-Young
    • Journal of Korean Society for Atmospheric Environment
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    • 제19권E2호
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    • pp.89-97
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    • 2003
  • Ambient polycyclic aromatic hydrocarbons (PAHs) were measured during the winter and summer of 2002 in Chongju. A filter pack and polyurethane foam (PUF) system was employed to collect simultaneously the particulate and gas phase PAHs. The samples were then analyzed using a gas chromatograph equipped with mass spectrometer detectors (GC/MSD). A total of 29 samples were collected and 11 PAH species were identified. The lower molecular weight PAH compounds (3∼4 rings) dominated the total PAH mass. The higher molecular weight PAH compounds (5∼6 rings) were less abundant. The PAHs were showed to exhibit seasonal variations. The concentrations of all com-pounds were significantly higher in winter than summer. The lower molecular weight PAHs were mostly found in the gas phase whereas the heavier ones were mainly associated with particulate phase. Vehicle emissions are likely to be the primary contributor of PAHs in Chongju. This study also demonstrated that it is necessary to perform simultaneously particulate and gas phase measurements to determine the accurate concentrations of ambient PAHs.

Study for Permanent Mold Design Technology and Porosity Defect Prediction Method by Multi-Phase Flow Numerical Simulations (다상유체해석을 통한 기포결함 예측과 금형설계기술)

  • Choi Y. S.;Cho I. S.;Hwang H. Y.;Choi J. K.;Hong J. H.
    • Transactions of Materials Processing
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    • 제14권3호
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    • pp.224-232
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    • 2005
  • The high-pressure die-casting is one of the most effective methods to produce a large amount of products in short cycle time. This process, however, has a problem that the gas porosity defect appears easily. The generation of gas porosity is known mainly due to the air entrapment during the injection stage. Most of numerical simulations for the molten metal flow pattern observations have done in the treating of one phase fluid flow but the gas-liquid interface is essentially multi- phase phenomenon. In this paper, the two-phase fluid flow numerical simulation methods have been adapted to predict the gas porosity generations in the molten metal. The accuracy and the usefulness of the new simulation module have been emphasized and verified through some comparison experiments.

A Study on the Two-Phase Flow Transition and Atomization Characteristics in Effervescent Injectors (기체주입식 분사기의 이상유동 변화와 분무특성에 관한 연구)

  • Lee, Kangyeong;Jung, Hadong;Kang, Cheolwoong;Ahn, Kyubok
    • Journal of ILASS-Korea
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    • 제27권3호
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    • pp.144-154
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    • 2022
  • Gas injection is a technique applied to improve throttling in liquid rocket engines and atomization in effervescent injectors. When a gas is injected into a liquid, it creates a two-phase flow inside the injector. The changes (bubbly flow, slug flow, annular flow, etc.) in the two-phase flow affect the injector's spray characteristics. In this study, cold-flow tests were performed by using three injectors with different orifice diameters and four aerators with different gas injection hole diameters. The experiments were done by changing the thrust ratio (liquid mass flow rate ratio) and gas-liquid mass flow rate ratio. Two-phase flow transition, breakup length, and discharge coefficient according to the injector/aerator design and flow conditions were investigated in detail.

Preparation of Novel Sorbents for Gas-phase Mercury Removal

  • Lee, Si-Hyun;Rhim, Young-Jun;Park, Young-Ok
    • Carbon letters
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    • 제3권4호
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    • pp.187-191
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    • 2002
  • In the present research, we prepared the activated carbon (AC) sorbents to remove gas-phase mercury. The mercury adsorption of virgin AC, chemically treated AC and fly ash was performed. Sulfur impregnated and sulfuric acid impregnated ACs were used as the chemically treated ACs. A simulated flue gas was made of SOx, NOx and mercury vapor in nitrogen balance. A reduced mercury adsorption capacity was obtained with the simulated gas as compared with that containing only mercury vapor in nitrogen. With the simulated gas, the sulfuric acid treated AC showed the highest performance, but it might have the problem of corrosion due to the emission of sulfuric acid. It was also found that the high sulfur impregnated AC also released a portion of sulfur at $140^{\circ}C$. Thus, it was concluded that the low sulfur impregnated AC was suitable for the treatment of flue gas in terms of stability and efficiency.

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