• Title/Summary/Keyword: gas enrichment

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Microbial Community Structure in Hexadecane- and Naphthalene-Enriched Gas Station Soil

  • Baek, Kyung-Hwa;Kim, Hee-Sik
    • Journal of Microbiology and Biotechnology
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    • v.19 no.7
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    • pp.651-657
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    • 2009
  • Shifts in the activity and diversity of microbes involved in aliphatic and aromatic hydrocarbon degradation in contaminated soil were investigated. Subsurface soil was collected from a gas station that had been abandoned since 1995 owing to ground subsidence. The total petroleum hydrocarbon content of the sample was approximately 2,100 mg/kg, and that of the soil below a gas pump was over 23,000 mg/kg. Enrichment cultures were grown in mineral medium that contained hexadecane (H) or naphthalene (N) at a concentration of 200 mg/l. In the Henrichment culture, a real-time PCR assay revealed that the 16S rRNA gene copy number increased from $1.2{\times}10^5$to $8.6{\times}10^6$with no lag phase, representing an approximately 70-fold increase. In the N-enrichment culture, the 16S rRNA copy number increased about 13-fold after 48 h, from $6.3{\times}10^4$to $8.3{\times}10^5$. Microbial communities in the enrichment cultures were studied by denaturing gradient gel electrophoresis and by analysis of 16S rRNA gene libraries. Before the addition of hydrocarbons, the gas station soil contained primarily Alpha- and Gammaproteobacteria. During growth in the H-enrichment culture, the contribution of Bacteriodetes to the microbial community increased significantly. On the other hand, during N-enrichment, the Betaproteobacteria population increased conspicuously. These results suggest that specific phylotypes of bacteria were associated with the degradation of each hydrocarbon.

The Flame Structure of Freely Porpagating CH4/O2/N2Premixed Flames on the O2Enrichment (산소부화된 자유롭게 전파하는 CH4/O2/N2예혼합화염의 화염구조)

  • Lee, Gi-Yong;Nam, Tae-Hyeong;Yu, Hyeon-Seok;Choe, Dong-Su
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.4
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    • pp.555-560
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    • 2002
  • Numerical simulations of freely propagating flames burning stoichiometric CH$_4$/O$_2$/$N_2$mixtures are performed at atmospheric pressure in order to understand the effect of the $O_2$enrichment level on CH$_4$/Air flame. A chemical kinetic mechanism is employed, the adopted scheme involving 54 gas-phase species and 632 forward reactions. The calculated flame speeds are compared with the experiments for the flames established at several $O_2$enrichment level, the results of which is in excellent agreement. As a result of the increased $O_2$enrichment level from 0.21 to 1, the mole fraction of CO in the burred gas is increased. The flame speed and the temperature in the burned gas are also increased, but the thickness of the flame is severely shrunken in the preheat region. The maximum of the calculated EINO is obtained around 0.6 and 0.7 of the $O_2$enrichment level in cases of flames for fuel-lean mixtures.

Optimization of Bio-Methane Gas Enrichment Process for City Gas Supply (도시가스용 바이오가스 메탄농축공정 최적화)

  • Ko, Sang-Wook;Lee, Kyung Jin;Moon, Myong Hwan;Baek, Ju Hong;Ko, Jae Wook
    • Journal of the Korean Institute of Gas
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    • v.21 no.4
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    • pp.76-83
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    • 2017
  • Biogas, combine with ever-increasing natural gas demand, has been on the center stage in South Korea for the early part of twenty first century in an effort to reduce the emission of global warming gases. With the passage of legal system of City Gas Business Law in 2014, the biogas has its place of production and distribution to consumers. However, it has a room for its technological improvements in terms of enrichment, by separating carbon dioxide and removing impurities efficiently. For these improvements, four different methane enrichment processes were tested in this study; membrane separation, water absorption, Chemical Absorption and Adsorption. A variety of operation scenarios were applied to the processes and the best practices were drawn out. The optimum process was selected based on case study results. Methane produced in this study showed 97% purity and 98% recovery rate, which meets the requirements of the City Gas quality standards.

Effect of Oxygen Enrichment in a Swirling Diffusion Gas Burner (선회 확산버너에서 산소부화가 연소장에 미치는 영향)

  • Lee, Yong-Hoo;Lee, Jin-Seok;Lee, Woo-Seob;Lee, Do-Hyung
    • Journal of the Korean Society of Combustion
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    • v.7 no.2
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    • pp.34-41
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    • 2002
  • To investigate the combustion characteristics of a swirling diffusion gas burner with oxygen enrichment, mean temperature, CO, $CO_2$, and HC concentrations were measured at various oxygen enrichment conditions. According to the results, the flame temperature increased and the region of high temperature was expanded with increasing oxygen concentration. The $CO_2$ concentrations increased, while the CO concentrations decreased in proportion to the increase of oxygen concentration. On the other hand, the HC concentrations were decreased and this tendency was very strong at the downstream of the combustor.

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The Flame Structure of Freely Propagating $CH_4$/$O_2$/$N_2$ Premixed Flames on Adding Oxygen (자유롭게 전파하는 $CH_4$/$O_2$/$N_2$ 예혼합화염에서 산소부화에 따른 화염구조)

  • Lee, Ki-Yong;Nam, Tae-Hyoung;You, Hyun-Seok;Choi, Dong-Soo
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.77-82
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    • 2000
  • Numerical simulations of freely propagating flames burning stoichiometric $CH_4$/$O_2$/$N_2$ mixtures are performed at atmospheric pressure in order to understand the effect of the $O_2$ enrichment level on $CH_4$/Air flame. A chemical kinetic mechanism is employed, the adopted scheme involving 54 gas-phase species and 632 forward reactions. The calculated flame. speeds are compared with the experiments for the flames established at several $O_2$ enrichment level, the results of which is in excellent agreement. As a result of the increased $O_2$ enrichment level from 0.21 to 1, the mole fraction of CO in the burned gas is increased. The flame speed and the temperature in the burned gas are also increased, but the thickness of the flame is severely shrunken in the preheat region.

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Effect of Exhaust Heat Exchanger on Catalytic Converter Temperature in an SI Engine (가솔린 엔진의 배기 열교환기가 촉매 온도에 미치는 영향에 관한 연구)

  • 이석환;배충식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.2
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    • pp.9-16
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    • 2004
  • Close-coupled catalyst (CCC) can reduce the engine cold-start emissions by utilizing the energy in the exhaust gas. However, in case the engine is operated at high engine speed and load condition, the catalytic converter may be damaged and eventually deactivated by thermal aging. Excess fuel is sometimes supplied intentionally to lower the exhaust gas temperature avoiding the thermal aging. This sacrifices the fuel economy and exhaust emissions. This paper describes the results of an exhaust heat exchanger to lower the exhaust gas temperature mainly under high load conditions. The heat exchanger was installed between the exhaust manifold and the inlet of close-coupled catalytic converter. The exhaust heat exchanger successfully decreased the exhaust gas temperature, which eliminated the requirement of fuel enrichment under high load conditions. However, the cooling of the exhaust gas through the heat exchanger may cause the deterioration of exhaust emissions at cold start due to the increment of catalyst light-off time.

The Effect of Particle Size on Ignition Characteristics of Pulverized High-Volatile Bituminous Coal

  • Kim, Hyung-Taek
    • Journal of Energy Engineering
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    • v.2 no.3
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    • pp.285-292
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    • 1993
  • A cylindrical-shape, horizontal furnace was used to investigate the effect of particle size on the pulverized coal combustion behavior. Three differently-sized fractions (5, 30, and 44 microns in average diameter) of high-volatile bituminous coal, were burned in the test furnace. Ignition characteristics of pulverized coal flame were determined through the amount of methane in the carrier gas for the self-sustaining flame. Easiest ignition occurred with the immediately-sized coal particles. Ignition of coal jet flame appeared to occur through a gas-phase homogeneous process for particles larger than 30 microns. Below this limiting size, heterogeneous process probably dominated ignition of coal flame. Oxygen concentration of combustion air was varied up to 50%, to determine the oxygen-enrichment effect on the coal ignition behavior. Oxygen enrichment of primary air assisted ignition behavior of pulverized coal flame. However, enrichment of secondary air didn't produce any effect on the ignition behavior.

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Effect of $Co_2$ Enrichment of Semihardwood Lagerstroemia indica L. Cuttings in Enclosed Propagating Frame (이산화탄소 시용에 의한 배롱나무 삽목의 발근 촉진 효과)

  • 안영희
    • Journal of the Korean Institute of Landscape Architecture
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    • v.20 no.3
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    • pp.57-63
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    • 1992
  • The present investigation was undertaken to determine if CO2 enrichment promoted rooting and subsequent growth of Lagerstroemia indica L. cuttings. Cutting were taken from the one-year-old semihardwood twigs, and rooted in enclosed propagation frame with enriched CO2 levels (500-2000ppm) regulated by a gas monitor. The base of each cutting was dippid from 500 to 4000ppm naphthalenacetic acid. Roothing was determined after 3 months. CO2 enrichment during roothing increased the rooting percentage and number of roots per cutting, but nontreated cuttings rooted in low percentages producing one or two roots. The length of new shoots and dry weight of whole cuttings in CO2 enrichment were significantly greater than those of the atmospheric controls. The organic and inorganic compounds concentraion were measured as an indication of nutritional state in whole cuttings. As a result of CO2 enrichment, carbohydrate, protein and inorganic compounds(total nitrogen, P2O5, K2O, CaO, MgO) concentration were higher than controls.

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Effects Of Oxygen Enrichment on the Structure of CH4/CHCI3/O2N2 Premixed Flames (CH4/CHCI3/O2N2 예혼합 화염 구조에서 산소부화의 효과)

  • Lee, Ki-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.7
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    • pp.893-900
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    • 2003
  • Numerical simulations of freely propagating flames burning stoichiometric C $H_4$/CHC1$_3$/ $O_2$/$N_2$ mixtures are performed at atmospheric pressure in order to understand the effect of the $O_2$ enrichment level and the CHC1$_3$/C $H_4$ molar ratio. A chemical kinetic mechanism is developed, which involves 69 gas-phase species and 379 forward and 364 backward reactions. The calculated flame speeds are compared with the experiments for the flames established at several CHC1$_3$/C $H_4$ molar ratio (R<1), the results of which is in excellent agreement. As a results of the increased $O_2$ enrichment level from 0.21 to 1, the flame speed and the temperature in the burned gas are increased. At high CHC1$_3$/C $H_4$ molar ratio two peak values appear on the $O_2$ consumption rate, which are affected by CC1$_2$$O_2$$_{-}$>C1O+CC1O and H+ $O_2$$_{-}$>O+OH.+OH.

NOx Formation Characteristics with Oxygen Enrichment in Nonpremixed Counterflow Flames (비예혼합 대향류화염에서 산소부화에 따른 NOx 생성특성)

  • Lee, Chang-Eon;Hwang, Cheol-Hong;Yoo, Byung-Hun;Han, Ji-Woong
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.17-22
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    • 2007
  • The NOx emission characteristics with oxygen enrichment in non-premixed counterflow flames were investigated numerically. To consider systematically the situation of inevitable $N_2$ contamination by air infiltration in the process of pure-oxygen combustion, the volume ratio of $O_2$ in an oxidizer was changed from 21% to 100%. As a result the NO emission index $(EI_{NO})$ has the highest value under condition of 75% oxygen enrichment. This result can be explained by the change of $N_2$ destruction rate with oxygen enrichment rather than flame temperature, flame thickness and residence time. In particular, it was found that the reaction of N+NO=$N_2+O$ has the largest contribution on NOx production in oxygen-enrichment flames.

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