• 대한기계학회논문집B
• /
• 제32권9호
• /
• pp.683-694
• /
• 2008

The performance and durability of Polymer Electrolyte Fuel Cells (PEFCs) are strongly influenced by the uniformity of current density, temperature, species distributions inside a cell In order to obtain uniform distributions in them, the optimal design of flowfield must be a key factor. In this paper, the numerical study of land/channel flowfield optimizations is performed, using a multi-dimensional, multi-phase, non-isothermal PEFC model. Numerical simulations reveal more uniform current density and HFR(High Frequency Resistance) distributions and thus better PEFC performance with narrower land/channel width where the less severe oxygen depletion effect near the land region and more uniform contact resistance variation along the in-plane direction are achieved. The present study elucidates detailed effects of land/channel width and assist in identifying optimal flow-field design strategies for the operation of PEFCs.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회B
• /
• pp.3114-3119
• /
• 2008

Relatively high convective flow exists in the under-rib regions of a gas diffusion layer (GDL) when serpentine flow fields are employed in a PEMFC. This under-rib convection is believed to be favorable for the performance of PEMFCs, by enabling more effective use of catalysts in the under-rib regions. From the fact that the under-rib convection in a GDL is directly proportional to the permeability of the GDL, computational fluid dynamics (CFD) simulations were performed to discover the relationship between the GDL permeability and the PEMFC performance. Single-, triple-, and quintuple-path parallel serpentine flow fields for $9\;cm^2$ active cell area were considered while changing the GDL permeability from $1{\times}10^{-12}$ to $5{\times}10^{-11}m^2$. The results showed that higher GDL permeability generally resulted in better performance of PEMFCs, but the degree of performance enhancement became smaller as the parallel path number increased. The effects of the permeability on the local variables were also discussed.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2008년도 추계학술대회B
• /
• pp.2822-2827
• /
• 2008

Among the main components of PEM fuel cell, the functions of GDL are to transport reactants from the channel to the catalyst and remove reaction products from the catalyst and transport heat from the catalyst to the channels in the flow filed plate. Permeability of GDL is known to make it possible to enhance the gas transport through GDL, devoting to get better performance. In this paper, three dimensional numerical simulation of the fuel cell by the permeability of GDL is presented by using a FLUENT modified to include the electrochemical behavior. Results show that as permeability is higher than $10^{-12}m^2$, gradients of temperature distribution, oxygen molar concentration and current density distribution in MEA were decreased. Although heat generation was increased as high permeability, MEA's temperature was lower than the low permeability of GDL. This seems because that convection was higher affects in mass and heat transfer process than diffusion as permeability of GDL is increases.

• 천문학회지
• /
• 제36권3호
• /
• pp.111-121
• /
• 2003

In order to explore the cosmic ray acceleration at the cosmological shocks, we have performed numerical simulations of one-dimensional, plane-parallel, cosmic ray (CR) modified shocks with the newly developed CRASH (Cosmic Ray Amr SHock) numerical code. Based on the hypothesis that strong Alfven waves are self-generated by streaming CRs, the Bohm diffusion model for CRs is adopted. The code includes a plasma-physics-based 'injection' model that transfers a small proportion of the thermal proton flux through the shock into low energy CRs for acceleration there. We found that, for strong accretion shocks with Mach numbers greater than 10, CRs can absorb most of shock kinetic energy and the accretion shock speed is reduced up to $20\%$, compared to pure gas dynamic shocks. Although the amount of kinetic energy passed through accretion shocks is small, since they propagate into the low density intergalactic medium, they might possibly provide acceleration sites for ultra-high energy cosmic rays of $E\ll10^{18}eV$. For internal/merger shocks with Mach numbers less than 3, however, the energy transfer to CRs is only about $10-20\%$ and so nonlinear feedback due to the CR pressure is insignificant. Considering that intracluster medium (ICM) can be shocked repeatedly, however, the CRs generated by these weak shocks could be sufficient to explain the observed non-thermal signatures from clusters of galaxies.

• 영재교육연구
• /
• 제19권1호
• /
• pp.187-205
• /
• 2009

이 연구의 목적은 과학자의 사고과정을 반영한 모델링 탐구를 적용한 후 모델링에 대한 학생들의 인식을 알아보는 것이다. 기체의 확산, 이온의 전도도, 이온의 이동에 대한 모델링 모듈을 과학고등학교 1학년 학생들을 대상으로 적용하였다. 모델링 모듈에 대한 학생들의 인식을 알아보기 위하여 인터뷰, 실험보고서, 대화 내용을 분석하였다. 학생들은 모델링 탐구가 과학자의 연구과정을 경험할 수 있는 활동이며, 모델링 탐구는 '생각의 근육'을 키우는 활동, '새로운 시각'과 '다양한 표현'이 필요한 활동, '실험 디자인' 과정이 포함된 활동으로 인식하고 있었다. 그러므로 앞으로 다양한 모델링 모듈의 개발이 필요하다.

• 한국수소및신에너지학회논문집
• /
• 제23권5호
• /
• pp.476-483
• /
• 2012

Proper water management is crucial for the efficient operation of polymer electrolyte membrane (PEM) fuel cell. Especially, for automotive applications, A novel water management that can avoid both membrane dry-out and flooding is a very important task to achieve good performance and efficiency of PEM fuel cells. The aim of this study is to investigate the liquid water behavior on the gas diffusion layer (GDL) surface and in the cathode flow channel of a PEM unit fuel cell under flooding conditions. For this purpose, a transparent unit fuel cell is devised and fabricated by modifying the conventional PEM fuel cell design. The results of water droplet behavior under flooding conditions are mainly presented. The water distributions in the cathode flow channels with cell operating voltage are also compared and analyzed. Through this work, it is expected that the data obtained from this fundamental study can be effectively used to establish the basic water management strategy in terms of water removal from the flow channels in a PEM fuel cell stack.

• 한국수소및신에너지학회논문집
• /
• 제24권1호
• /
• pp.70-75
• /
• 2013

It has fabricated membrane electrode assemblies (MEA) for proton exchange membrane fuel cell by hot-pressing method. The hot-pressing was used for the fabrication of MEA which is composed of commercial platinum electrode on carbon paper. The performance of MEA was studied with different fabrication conditions of temperature, pressure and torque. As the temperature increased, the performance of MEA was increased. and started to decrease l after arrived at the maximum performance of MEA. This is related with good contact between electrode and polymer electrolyte membrane at high temperature and microstructural change at much higher temperature. Similarly, as the pressure increased, the performance of the MEA increased up to highest values and start to decrease. According to the our results, the maximal performance of the MEA was at the temperature of $140^{\circ}C$ and the pressure of $1.5{\times}10^3$ kPa. The optimal torque to assemble the single stack was 3.2 N m.

• 한국수소및신에너지학회논문집
• /
• 제30권6호
• /
• pp.499-504
• /
• 2019

Due to the rapid spread and low minimum ignition energy of hydrogen, rupture is highly likely to cause fire, explosion and major accidents. The self-ignition of high-pressure hydrogen is highly likely to ignite immediately when it leaks from an open space, resulting in jet fire. Results of the diffusion and leakage simulation show that jet effect occurs from the leakage source to a certain distance. And at the end of location, the vapor cloud explosion can be occurred due to the formation of hydrogen vapor clouds by built-up. In the result, it is important that depending on the time of ignition, a jet fire or a vapor cloud explosion may occur. Therefore, it is necessary to take into account jet effect by location of leakage source and establish a damage minimizing plan for the possible jet fire or vapor cloud explosion. And it is required to any kind of measurements such as an interlock system to prevent hydrogen leakage or minimize the amount of leakage when detecting leakage of gas.

• 한국세라믹학회지
• /
• 제29권8호
• /
• pp.587-592
• /
• 1992

Sheets of SiC-SiC whisker maxed matrix were prepared from the mixed slurry of SiC whisker and SiC matrix by the rolling method. With the increase of SiC whisker, the pore size, the porosity and the phosphoric acid absorbency of the matrix were increased, while the bubble pressure was decreased. The activation energy for the transfer of H+ ion was decreased with the increase of mixing ratio of SiC whisker to the SiC matrix from the measurement of hydrogen ion conductivity. The activation energy was evaluated as 0.25 eV when the mixing ratio of SiC whisker to the SiC matrix was 1 : 2 and the activation energy was 0.16 eV for the 2 : 1 matrix. It means that SiC whisker matrix contributes to attain a better microstructure for the diffusion of hydrogen ion. From the measurement of single cell performance of matrix with various mixing ratio, it is concluded that if SiC-SiC whisker maxed matrix has a sufficient bubble pressure to prevent the crossover of H2 gas, the current density of a fuel cell is increased with the increase of acid absorbency of the matrix. Current density was improved from 140 mA/$\textrm{cm}^2$ for 0.25 mm thickness of matrix to 170 mA/$\textrm{cm}^2$ for the 0.20 mm one at 700 mV.

• 조명전기설비학회논문지
• /
• 제22권8호
• /
• pp.104-108
• /
• 2008

플라즈마 현상의 정량적 이해를 위해서는 원자나 분자기체가 가지고 있는 정확한 전자충돌단면적과 그 전자수송 계수의 값을 필요로 한다. 본 연구에서 사용하고 있는 Kr과 Xe 원자기체는 PDP와 무전각램프 등 다양한 산업 응용분야에 이용되고 있다. 따라서 2항 근사 볼츠만 해석에 의해 기체압력 1[torr]의 조건에 $0.001{\sim}500$[Td]의 광범위한 E/N에서 순수 Kr과 Xe 원자기체의 전자이동속도 W, 종 횡축확산계수 $ND_L$과 $ND_T$, 전리계수 $\alpha$/N의 전자수송 계수를 계산하고 물성 해석하였다.