• Korean journal of applied entomology
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• v.20 no.2 s.47
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• pp.103-106
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• 1981

This experiment was carried out to investigate the vertical penetration and diffusion of fumigants for soybean disinfection in jumbo silo. The results were as follows, 1. Using the methylbromide independently as a soybean fumigant, penetration and diffusing velocity of methylbromide gas which moved from the top to the bottom through the vertica1 silo was too rapidly, it was possible to find out more 60mg/l of methylbromide gas concentration at bottom of silo within 4 hours after beginning the fumigation. And it showed the tendency of reducing methylbromide gas concentration gradually over the 10 hours from tile beginning the fumigation. 2. In case of added $CO_2$ gas to the methylbromide as a carrier is much more rapid velocity of penetration and diffusion of methylbromide gas than that of methylbromide gas independently. Therefore methylbromide gas concentration at bottom of silo was detected over the 70mg/l within 1.5 hours after beginning the fumigation.. 3. On the other hand, hence the phostoxin as a soybean fumigant was less velocity of Penetration and diffusion of the gas through the vertical silo compare to methylbromide gas, the phostoxin gas concentration couldn't detect over the 10mg/1 during the whole fumigation period at the bottomside of silo. 4. Test insects (rice weevil; sitophilus oryzae. L.) inserted at bottom of silo for examine the fumigation effect were killed completly by using the methylbromide independently and added $CO_2$ gas to methylbromide, while using the phostoxin the test insects were most alive.

• Journal of the Korean Society of Safety
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• v.33 no.5
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• pp.28-34
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• 2018

Recently, various engineering approaches have been widely used in the accident investigation field to identify the cause of the accident and to predict damage by accident. Computational analysis is the most commonly used method of accident investigation technique. This technique is mainly used to identify the mechanism of the accident generation and to determine the cause when it is difficult to reproduce the situation at the time of the accident or when it is impossible to perform a reproduction experiment. In this study, The computational fluid dynamics analysis for nitrogen asphyxiation accident generated by defect of building structural between diffusion outlet and cooling tower was performed to determine the inflow path of the suffocation gas, death possibility by concentration of suffocation gas and predicted the time of death due to the accident using 3D modeling and FLACS program. We can quantify diffusion concentration of asphyxiation gas and predict mechanism of death occurrence by accident and evaluate the consequence Analysis through this study. In the future, This method can be widely used in the field of gas safety by improving the reliability and validity of the analysis.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.279-282
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• 2002

Recently, gas turbines for power generation adopt multistage DLN(Dry Low NOx) type combustion, where diffusion combustion is applied at low load and, with increase in load, the combustion mode is changed to lean premixed combustion to reduce NOx emissive concentration. However, during the mode changeover from diffusion to premixed flame, unfavorable phenomena, such as flashback, high amplitude combustion oscillations, or thermal damage of combustor parts could frequently occur. In the present study, to apply for the analysis of such unfavorable phenomena, three-dimensional CFD investigations are carried out to compare the detailed flow characteristics and temperature distribution inside the gas turbine combustor before and after combustion mode changeover. The fuel considered here is pure methane gas. A standard $k-{\varepsilon}$ turbulence model with wall function and a P-N type radiation heat transfer model, have been utilized. To analyze the complex geometric effects of combustor parts on combustion characteristics, fuel nozzles, a swirl vane f3r fuel-air mixing, and cooling air holes on the combustor liner wall, are included in this simulation.

• Journal of the Korean Electrochemical Society
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• v.10 no.4
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• pp.306-310
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• 2007

Characteristics of GDL (Gas Diffusion Layer) mainly determine the gas diffusion and water removal in a cell, thereby changing the performance and affecting durability of PEFC. To optimize the water management and understand the two phase flow in a GDL, it is important to study the behaviors of GDL micro structure under the real operating condition. In the clamped condition of cell, the GDL beneath the rib is more compressed than beneath the channel. Many researches on physical, electrochemical, mechanical behaviors of gas diffusion layer has been conducted. However, changes in surface properties under clamped condition have rarely studied. In present study, the morphology of broken connections of carbon fibers and detachment of PTFE coatings on the fibers were shown from the microscopic observations. In addition, changes in wetting properties of GDL by compression were investigated by using XPS and liquid uptake methods. The hydrophobic characteristics of GDL surface beneath the rib of the flow field plate are changed due to the deformation of micro structure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.5
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• pp.1671-1678
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• 1996

In external chemical vapor deposition processes including VAD and OVD the distribution of flame-synthesized silica particles is determined by heat and mass transfer limitations to particle formation. Combustion gas flow velocities are such that the particle diffusion time scale is longer than that of gas flow convection in the zone of particle formation. The consequence of these effects is that the particles formed tend to remain along straight smooth flow stream lines. Silica particles are formed due to oxidation and hydrolysis. In the hydrolysis, the particles are formed in diffuse bands and particle formation thus requires the diffusion of SiCl$\_$4/ toward CH$\_$4//O$\_$2/ combustion zone to react with H$\_$2/O diffusing away from these same zones on the torch face. The conversion kinetics of hydrolysis is fast compared to diffusion and the rate of conversion is thus diffusion-limited. In the language of combustion, the hydrolysis occurs as a Burke-Schumann process. In selected conditions, reaction zone shape and temperature distributions predicted by the Burke-Schumann analysis are introduced and compared with experimental data available. The calculated centerline temperatures inside the reaction zone agree well with the data, but the calculated values outside the reaction zone are a little higher than the data since the analysis does not consider diffusion in the axial direction and mixing of the combustion products with ambient air. The temperatures along the radial direction agree with the data near the centerline, but gradually diverge from the data as the distance is away from the centerline. This is caused by the convection in the radial direction, which is not considered in the analysis. Spatial distribution of silica particles are affected by convection and diffusion, resulting in a Gaussian form in the radial direction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.9
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• pp.688-698
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• 2009

Using the multi-dimensional, multi-phase, nonisothermal Polymer Electrolyte Fuel Cell (PEFC) model presented in Part I, the effects of land/channel flow-field on temperature and liquid saturation distributions inside PEFCs are investigated in Part II. The focus is placed on exploring the coupled water transport and heat transfer phenomena within the nonisothermal and two-phase zone existing in the diffusion media (DM) of PEFCs. Numerical simulations are performed varying the land and channel widths and simulation results reveal that the water profile and temperature rise inside PEFCs are considerably altered by changing the land and channel widths, which indicates that oxygen supply and heat removal from the channel to the land regions and liquid water removal from the land toward the gas channels are key factors in determining the water and temperature distributions inside PEFCs. In addition, the adverse liquid saturation gradient along the thru-plane direction is predicted near the land regions by the numerical model, which is due to the vapor-phase diffusion driven by the temperature gradient in the nonisothermal two-phase DM where water evaporates at the hotter catalyst layer, diffuses as a vapor form and then condenses on the cooler land region. Therefore, the vapor phase diffusion exacerbates DM flooding near the land region, while it alleviates DM flooding near the gas channel.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.73-84
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• 2006

Hazardous Air Pollutants (HAPs) are characterized by being relatively heavier and denser than that of ambient air due to the various reasons such as higher molecular weight, low temperature and other complicated chemical transformations (Witlox, 1994). In an effort to investigate transport and diffusion from instantaneous emission of heavy gas, Lagrangian Particle Dispersion Model (LPDM) coupled with the RAMS output was employed. Both deposition process and buoyancy term were added on the atmospheric diffusion equations of LPDM, and the locations and concentrations of dense gas particle released from instantaneous single point source (emitting initially for 10 minutes only) were analyzed. The result overall shows that adding deposition process and buoyancy terms on the diffusion equation of LPDM has very small but detectable effect on the vertical and horizontal distribution of Lagrangian particles that especially transported for a fairly long traveling time. Also the slumping of dense gas can be found to be ignored horizontally compared to the advection by the horizontal wind suggesting that it was essential to couple the Lagrangian particle dispersion model coupled with the RAMS model in order to explain the dispersion of HAPs more accurately. However, during the initial time of instantaneous emission, buoyancy term play an important role on the vertical locations of dense particles for near surface atmosphere and around source area, indicating the importance of densities of HAPs in the beginning stage or short duration for the risk assessment of HAPs or management of heavy vapors during the explosive accidents.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.68-74
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• 2021

Gas diffusion layer (GDL) compression is important parameter of polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on contact resistance, reactants transfer to electrode, water content in membrane and electrode assembly (MEA). In this study, the effect of GDL compression on fuel cell performance was investigated for commercial products, JNT20-A3. Polarization curve and electrochemical impedance spectroscopy was performed at different relative humidity and compression ratio using electrode area of 25 ㎠ unit cell. The contact resistance was reduced to 8, 30 mΩ·㎠ and membrane hydration was increased as GDL compression increase from 18.6% to 38.1% at relative humidity of 100 and 25%, respectively. It was identified through ohmic resistance change at relative humidity conditions that as GDL compression increased, water back-diffusion from cathode and electrolyte membrane hydration was increased because GDL porosity was decreased.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2366-2371
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• 2007

Spray combustion characteristics of a conducting fuel electrospray have been studied for clean combustion technology. The multiplexing system which can retain the characteristics of the cone-jet mode is inevitable for the electrospray application. Charged micro droplets can be obtained in almost uniform size during operating the electrospray in the cone-jet mode. This experiment device set up the multiplexed grooved nozzle system with the extractor. Using the grooved nozzle, the stable cone-jet mode can be achieved at the each groove in the grooved mode. This electrospray system was applied to the diffusion combustion. It is the first step to discover the diffusion combustion characteristics of the electrospray. In case of the single grooved nozzle electrospray, the diffusion flames are occurred at each jet of grooved mode and they are quite stable. The exhaust gas analysis was indicated that there is the critical point which can make very stable diffusion combustion.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.12
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• pp.979-985
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• 2007

Spray combustion characteristics of the conducting fuel electrospray has been studied for clean combustion technology. The electrospraying multiplexed system which can maintain the characteristics of the cone-jet mode is able to obtain charged micro droplets with high flow rate. In addition, they have monodisperse distribution during operating the electrospray in the cone-jet mode. The multiplexed grooved nozzle system with the extractor was applied to this experimental device set up. The stable grooved mode can be generated by the grooved nozzle and this electrospray system was applied to the diffusion combustion. It is the first step to discover the diffusion combustion characteristics of the electrospray, In case of the single grooved nozzle electrospray the diffusion flames are occurred at each Jet of grooved mode and they are quite stable. The exhaust gas analysis was indicated that there is the critical point which can make very stable diffusion combustion