• Title/Summary/Keyword: gas Separation

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Synthesis and characterization of silicone-containing polyamideimide and its gas separation

  • 이용범;심진기;이영무
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.83-84
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    • 1997
  • 1. INTRODUCTION : Polyimides containing siloxane moiety(poly(imide siloxane), or polysiloxaneimide) have been synthesized because of their some merits over polyimide itseft. Polyimides have excellent thermal and mechanical properties but their poor solubility and processibility in their fullly imidized form give disadvantages in applications. Incorporation of siloxane units make it possible to increase solubility and processibility, and also impart impact resistance, low moisture uptake, low dielectric constant, thermo-oxidative resistance, good adhesion properties to substrate and etc.. Incorporation methods of siloxane groups into the polyimide was mainly copolymerization or terpolymerization between oligomeric dimethylsiloxane and aromatic dianhydride. A few methods of introducing siloxane units in functional groups of polyimide was reported. In our laboratory poly(amideimide siloxane) and poly(imide siloxane) were prepared and the study about their thermal kinetics was performed. In separation membrane area, polysiloxaneimides was utilized in pervaporation and gas separation. Polyimides in gas separation show high selectivity and very low permeability, and introduction of siloxane segments increase permeability with low decrease in selectivity. We aimed to introduce silicone segments into poly(amic acid) state and synthesize polymer partially imidized, and also show the gas separation characteristics of the synthesized polymer.

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A Study on Separation of $N_2-SO_2$ Mixed Gas by Polymer Membranes (고분자막을 이용한 $N_2-SO_2$ 혼합기체의 분리에 관한 연구)

  • 김성준;민병렬;이태희
    • Membrane Journal
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    • v.2 no.2
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    • pp.135-143
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    • 1992
  • Separation of $N_2-SO_2$ mixed gas by polymer membranes, SEPA-97(CA), TFC, and FT-30 membrane, was investigated by varying pressure and temperature. The permeability coefficients and the separation factors of mixed gases were measured, and the influence of various factors on the gas permeability characteristics and separation performance were investigated. The range of pressure was 0.1~1.0 MPa, and that of temperature was 283~303 K. The experimental results showed that the permeability coefficients and the separation factors were increased with an increase in pressure, but they were deereased with increasing temperature. Among the examined membranes, FT-30 possessed the best gas-separating characteristics.

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Preparation and characterization of $C-SiO_2$ membranes modified by oxidation and their gas separation properties

  • Han, Sang-Hoon;Kim, Youn-Kook;Park, Ho-Bum;Lee, Young-Moo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.180-183
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    • 2004
  • Gas separation membranes are now used in a wide variety of application areas as oxygen enrichment, hydrogen recovery, acid gas treatment, and natural gas dehydration etc [1]. Since polymeric membranes offer attractive properties for gas separation application, they have been variously studied [2-4].(omitted)

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Molecular Dynamics (MD) Study of Polymeric Membranes for Gas Separation (기체 분리용 고분자 분리막의 분자동력학 연구)

  • Park, Chi Hoon;Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.24 no.5
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    • pp.341-349
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    • 2014
  • Molecular dynamics (MD) computer simulation is a very useful tool to calculate the trajectory and velocity of particles (generally, atoms), and thus to analyze the various structures and kinetic properties of atoms and molecules. For gas separation membranes, MD has been widely used for structure analysis of polymers such as free volume analysis and conformation search, and for the study of gas transport behavior such as permeability and diffusivity. In this paper, general methodology how to apply MD on gas separation membranes will be described and various related researches will be introduced.

A Parametric Study for the Design of Gas-Liquid Centrifugal Separator (기체-액체 원심분리기의 설계를 위한 매개변수 연구)

  • Nagdewe, Suryakant;Lee, S.J.;Kim, H.D.;Kim, D.S.;Kwak, K.M.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.218-219
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    • 2008
  • A gas-liquid centrifugal separator is widely used in industry because of its simple geometry and little maintenance. Also, these separators have considerable advantages over filters, scrubbers or precipitators in term of compact design, low pressure drop and higher capacity. A gas-liquid centrifugal separator is a device that utilizes centrifugal force and low pressure to separate liquid from gas by density difference. Design parameters such as length of separation space, swirl vane exit angle, inlet to outlet pipe diameter ratio, models for separation efficiency and low pressure drop as a function of physical dimension are not available in literature. In present study, length of separation space (from vane to gas exit opening) has been studied using CFD. The 3-D Navier-Stokes equations are numerically solved using a fully implicit finite volume scheme. Based upon the obtained solutions, tangential velocities, centrifugal forces, vortices and total pressure losses are analyzed to find the best design parameters.

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A Numerical Analysis of Oil Separation Performance Classified by Oil Mist Diameter for Cyclone Oil Separator (실린더 헤드커버 내장형 오일분리 장치의 오일 직경별 분리효율에 관한 해석적 연구)

  • Kim, Hyung-Gu;Yoon, Yu-Bin;Park, Young-Joon;Lee, Seang-Wock;Cho, Yong-Seok
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3026-3031
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    • 2008
  • In conventional closed-loop crankcase ventilation systems, the lubrication oil had to be re-circulated to the intake manifold, in the form of oil mist mixed with the blow-by gas. This blow-by gas containing the engine lubricant oil affects on the engine problems and the exhaust emissions. A high-efficient oil separator is required to minimize consumption of engine oil and reduce harmful emissions. In the conventional oil separator of CI engines, it has good oil separation performance even though separator design is simple, due to lots of the blow-by gas. As the emission regulation becomes severe, the oil separator for SI engines is also required. But in SI engines, separator design should be optimized, due to small size of oil particles and little amount of blow-by gas. In this study, oil separation performance classified by diameter of oil mist in cylinder head cover internal model which has three cyclones and two baffle plates for SI engine is calculated with CFD methodology.

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The Effect of the Integration Methods of Gas Turbine and Air Separation Unit on IGCC Plant Performance (가스터빈과 산소분리공정의 연계 방법에 따른 IGCC 플랜트 성능영향 분석)

  • 서석빈;김종진;조상기;이윤경;안달홍
    • Journal of Energy Engineering
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    • v.8 no.4
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    • pp.533-539
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    • 1999
  • Integration methods of a Gas Turbine and a Air Separation Unit have a potential to improve plant performance and cost of IFCC. Several studies on those integrations schemes were carried out. Then some of the methods were accually in commercial plants. Thus paper reviewed the integration schemes of a Gas Turbine and a Air Separation Unit. In order to compare the plant performance of IGCC with each scheme, simulation model was developed for IGCC power cycle with Texaco Quench gasification process. The simulation results showed that the thermal efficiency of the plant was appeared to be the best when all of the air consumption required for Air Separation Unit was supplied from the Gas Turbine and the net plant power output was maximized when 75% of the total ASU an requirement was supplied from Gas Turbine.

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Performance Prediction Method of Separation Mechanism by using a Gas Generator (가스발생기를 이용한 분리 메카니즘 성능예측 기법)

  • Oh, Seok-Jin;Lee, Do-Hyung;Kim, Sang-Hwa;Kim, Ki-Un
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.199-202
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    • 2008
  • This paper presents a mathematical-physical model to predict the performance of a gas pusher used as a separation system powered by a gas generator. The empirical coefficients of heat loss and friction were determined from experiments. Based on the grain configuration of the gas generator, the analytical approach of combustion, flow and movement of a piston inside the chamber of a gas generator and a gas pusher was simulated by numerical method. The prediction method developed can be usefully applied to the design of separation mechanism systems.

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An Experimental Study on Characteristics of Temperature Separation in a Vortex Tube for Diesel Engine Exhaust Gas (Vortex Tube의 승용 디젤기관 배기가스 온도 분리특성에 관한 연구)

  • Jung, Young-Chul;Choi, Doo-Seuk;Im, Seok-Yeon;Kim, Hong-Ju;Ryu, Jeong-In
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.1
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    • pp.93-98
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    • 2010
  • An object of this study is to confirm the opening amount of the throttle valve that is begun the temperature separation of vortex tube for various engine speed and load condition in a common rail diesel engine. The vortex tube located at downstream of the exhaust manifold is a device separating the incoming exhaust gas to hot and cold stream. To find optimum separation efficiency of vortex tube, the opening amount of throttle valve has been investigated for various engine speed and load conditions. Engine speed was found that the influence of engine speed was dominant compared with that of engine load. As engine speed was increased, the throttle opening amount starting temperature separation was reduced.

Research Trend of Membrane Technology for Separation of Carbon Dioxide from Flue Gas (온실기체 분리회수를 위한 막분리기술 연구 동향)

  • 김정훈;임지원;이수복
    • Membrane Journal
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    • v.12 no.3
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    • pp.121-142
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    • 2002
  • The $CO_2$ emission is the largest contribute for the green house effect. Among the existing chemical separation processes, the membrane separation technology is(/will be) the most potential process for $CO_2$, separation from flue gas. Based on the solution-diffusion theory and physical properties of carbon dioxide/nitrogen and the permeation data in the literature, the relationships between physico-chemical structures of polymeric membrane materials and the perm-selectivities for $CO_2$/$N_2$ gases were described in detail. The progress of membrane module and process development was introduced briefly. Finally, the worldwide research activity including South Korea's for carbon dioxide separation by membrane technology were introduced through the survey of papers and technical reports published.