• Title/Summary/Keyword: garnet

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A study on Recycling of Waste Garnet Powder as a Raw Material for Clay Bricks (폐기 Garnet 미분말의 적벽돌 원료로의 再活用에 관한 硏究)

  • 황경진;김영임;김동수;김준수
    • Resources Recycling
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    • v.11 no.2
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    • pp.36-44
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    • 2002
  • The waste garnet powder as a raw material for clay bricks was studied its recycling. The physical strength of clay bricks are closely dependent both on the contents of $SiO_2$, $Al_2$$O_3$, and $Fe_2$$O_3$in clay and on the viscosity of it. Although the garnet power has very high contents of $SiO_2$, $Al_2$$O_3$, and $Fe_2$$O_3$, it could not substituted to clay because of its low viscosity. Therefore the substitution of sand with waste garnet powder was considered to influence positively on the strength of clay bricks .Mixing ratios of {clay-sand}, {sand-garnet powder}, and {clay-sand-garnet powder} based on weight were controlled in the production of clay bricks. The properties of clay bricks such as compression strength, moisture absorption, shrinkage, and specific gravity has been evaluated. It was shown that the optimal mixing combination was found to be { clay(50%)-sand(30%)-garnet powder(20%)} as a weight basis. The present study indicated possibilities to produce commercially clay bricks with the waste garnet powder. An economical benefit will be produced in viable in view of recycling waste garnet powder.

Crystal Growth of $Ca_3(Li,Nb,Ga)_5O_{12}$ Garnet Crystals

  • Yu, Young-Moon;Chani, Valery-I.;Shimamura, Kiyoshi;Fukuda, Tsuguo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.351-374
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    • 1996
  • Various types of garnet compounds were synthsized by iso-and aliovalent substitutions and sintering method. Among them, fiber shapes of garnet crystals were grown from the $Ca_3Li_xNb_{(1.5+x)}Ga_{(3.5-2x)}O_{12}$ melt where x = 0 ~ 0.5 by modified micro-pulling down method in air using Pt crucibles. The measured lattice constants as a function of solidification fraction of grown fiber crystals are about $12.54\;{\AA}$ irrespective of x. It was found that the $Ca_3Li_{0.275}Nb_{1.775}Ga_{2.95}O_{12}$ garnet melts congruently at about $1450\;^{\circ}C$ based on the purities of garnet phase and variations of lattice parameter. Transparent and bubble-free crystals of x = 0.25 and 0.275 were grown by Czochralski techniques in air using Pt crucibles. An absorption spectrum is also reported.

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Skarn Minerals of Samhwa Iron Ore Deposit (삼화 철 광상의 Skarn 광물)

  • Chi, Jeong mahn;Jang, Yoon ho;Sung, Il yeong
    • Economic and Environmental Geology
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    • v.27 no.5
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    • pp.423-440
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    • 1994
  • The Samhwa iron ore deposit, which is of typical magnetite skarn type, is located in the Samhwadong area of Donghae city, Kangwon-do, Korea. Skarn minerals are mainly composed of garnet, clinopyroxene, vesuvianite, wollastonite and small amounts of epidote and quartz. The garnets are isotropic $(Ad_{92.82{\sim}98.37})$ or anisotropic andradite $(Ad_{45.30{\sim}75.85})$ and grossular $(Gr_{86.26{\sim}24.47})$, the clinopyroxenes are ferrosalite and salite, Homogenization temperature of gas rich two phase inclusions in garnet are $368{\sim}593^{\circ}C$, and salnities of polyphase inclusions in garnet have 33.9~68.4 equ. NaCl wt. %. Garnet grain often shows composional variation from its core to rim. In other words, Fe and Al contents in garnet vary inversely, which suggest that the variation depends upon $f_{o2}$ during skarn formation.

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Elastic Properties of the $CaSiO_3$ - Garnet Phase ($CaSiO_3$- 석류석 상의 탄성 특성)

    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.201-208
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    • 2004
  • $CaSiO_3$-garnet phase was observed in the phase transformation sequences on a natural hedenbergite, (Ca, Fe)$ SiO_3$ between 14 and 24 GPa when quenched from $~1200^{\circ}C$. Bulk modulus K = 155 GPa, $V_{\Phi}$ = 6.58 km/sec and other elastic properties of the $CaSiO_3$-garnet were obtaiend on the basis of the systematics of structural analogs in varius garnet phases and relationship of $KV_{m}$ = constant and $V_{\Phi}$$M^{$\frac{1}{2}$}$ = constant. The quenchable garnet phase apears to be stabilized by the considerable amount of Mn and other cations, and shows a wide stability range. As one of the host minerals of Ca composition, $CaSiO_3$-garnet would be one of the important mineral phases in the mantle transition region.

Mossbauer Spectroscopy Studies of Garnet $Y_{2.5}La_{0.5}Fe_5O_{12}$ (Garnet $Y_{2.5}La_{0.5}Fe_5O_{12}$의 Mossbauer 분광학 연구)

  • 염영랑;김철성
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.29-34
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    • 1999
  • $Y_{2.5}La_{0.5}Fe_5O_{12}$ is fabricated by a sol-gel method and the magnetic properties of single phase garnet are investigated by using X-ray diffraction, vibrating sample magnetometer, scanning electron microscopy and M$\"{o}$ssbauer spectroscopy. The single phase powders garnet was fired at 100$0^{\circ}C$ for 8 hours. The crystal structures of samples are cubic garnet. Mossbauer spectroscopy were measured from 13 K to 750 K. M$\"{o}$ssbauer spectra show that the iron exist ferric trivalence in sample. The spin wave constants were determined $B_{3/2}=0.32{\pm}0.05,\; C_{5/2}=0.18{\pm}0.05$ and Debye temperature were determined 382 K at 24(d) site and 246 K at 16(a)-site. The saturation magnetization $M_s$ of powder is 25 emu/g. 25 emu/g.

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Petrological and geochemical study of the Precambrian granitic gneiss in the Danyang- Yecheon area (단양-예천사이에 분포하는 선캠브리아 화강암질 편마암류의 암석학적 및 지구화학적 연구)

  • Yun Hyon Soo
    • The Journal of the Petrological Society of Korea
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    • v.1 no.1
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    • pp.34-41
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    • 1992
  • The Precambrian granitic gneisses are widely distributed in the Danyang-Yecheon area, eastern part of Korea, where the Ryeongnam massif borders the Ogcheon fold belt. They are composed of migmatitic, biotite granitic, garnet-bearing and granoblastic granitic gneisses. The common joint sets of the granitic gneiss are NE and NS directions, which are probably related to the effects of Daebo orogeny and Bulgugsa disturbance, respectively. Mineral assemblages of the banded gneiss xenolith in the garnet-bearing granitic gneiss are quartz-plagioc1ase-biotite-mus-covite-orthoclase and quartz-plagioc1ase-biotite-garnet, belonging to the amphibolite facies. The granoblastic granitic gneiss is felsic, metaluminous, and granitic, and shows subalkaline trend. The garnet-biotite geothermometry of garnet-bearing granitic gneiss yields 640$^{\circ}$-708$^{\circ}C$ at pressure of 4 kb.

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Granulite facies metamorphism of the Punggi area in the Sobeaksan Gneiss Complex -Crustal evolution and environmental geology of the North Sobeagsan Massif, Korea- (풍기지역 소백산편마암복합체의 백립암상 변성작용 -북부 소백산육괴의 지각진화와 환경지질-)

  • 권용완;신의철;오창환;김형식;강지훈
    • The Journal of the Petrological Society of Korea
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    • v.8 no.3
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    • pp.183-202
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    • 1999
  • The Sobeaksan Gneiss Complex in the Punggi area is composed of mainly mignatitic gneiss, porphyroblastic gneiss, garnet granitic gneiss and biotitie granitic gneiss. Metamorphic grade increase gradually from the amphibolite facies of northwestern part to the granulite facies of southwestern part in the study area. Representative mineral assemblage in the amphibolite facies is biotite-muscovite-K-feldspar-plagioclase$\pm$garnet$\pm$epidote, needle shape or fibrous sillimanite occur in transitional zone from the amphibolite facies to the granulite facies. In the granulite facies, the garnet-Opx granulite shows garnet-orthopyroxene-biotite-plagioclase, the metabasite shows clinopyroxene-plagioclase$\pm$hornblende$\pm$orthopyroxene$\pm$garnet and the migmatitic gneiss shows garnet-biotite-sillimanite-cordierite$\pm$spinel as representative mineral assemblage. Retrograde metamorphism after the granulite facies metamorphism made corindum and andalusite in the migmatitic gneiss and the thin layer garnet between clinopyroxene and plagioclase in the metabasites. The peak P-T conditions of the migmatitic gneiss and the garnet-Opx granulite are $916^{\circ}C$/6.6 kb and $826^{\circ}C$/6.3 kb, respectively. The P-T condition of biotite and plagioclase inclusion, which indicates the progressive condition of the granulie facies, within garnet is $866^{\circ}C$/7.5 kb and that of rim composition of garnet and biotite is $726^{\circ}C$/4.6 kb, which infer the clockwise P-T path of the granulite facies metamorphism. The temperatures caculated by the rim composition of garnet and biotite in the migmatitic gneiss and garnet granitic gneiss have a wide range of $556-741^{\circ}C$, which indicate that the retrograde metamorphism after the granulite facies metamorphism has effected differently. It is difficult to determine the P-T condition of the biotite granitic gneiss because less occurrence and higher spessartine content of garnet. The P-T condition of the thin layered garnet between clinopytoxene and plagioclase in the metabasite is $635-707^{\circ}C$/4.1-5.3 kb. This texture indicates the isobaric cooling(IBC) condition of the retrogressive metamorphism. As a result, the metamorphic evolution of the Punggi area has undergone the isobaric cooling after the granulite facies metamorphism which has undergone the clockwise P-T path.

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Polymetamorphism of the Odesan Gneiss Complex in the Northeastern area of the Kyonggi Massif, Korea (경기육괴 북동부지역에 분포하는 오대산편마암복합체의 다변성작용)

  • 권용완;김형식;오창환
    • The Journal of the Petrological Society of Korea
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    • v.6 no.3
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    • pp.226-243
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    • 1997
  • The Odesan Gneiss Complex consists of mainly migmatitic gneiss and porphyroblastic gneiss with locally intercated quartzite, amphibolite, marble and leucocratic gneiss. At least two different regional metamorphisms are recognized in the study area. Metamorphic grade of the first metamorphism increases from the K-feldspar-muscovite zone(in which biotite-muscovite-plagioclase-quartz and garnet-biotite-muscovite-K-feldspar-plagioclase-quartz assemblages occur) in the east and southwestern part of the study area to the K-feldspar-garnet zone(in which garnet-biotite-K-feldspar-plagioclase-quartz, biotite-K-feldspar-plagioclase-quartz, garnet-biotite-K-feldspar-plagioclase-sillimanite-spinel-quartz assemblages occur) in the northwestern part. Kyanite is found as inclusions in plagioclase. The second metamorphism is characterised by occurrence of cordierite. The metamorphic grade of 2nd metamorphism decreases radically from the central-western part near Gaeinsan in which cordierite-garnet-sillimanite-biotite-muscovite-quartz, cordierite-garnet-spinel-sillimanite-biotite-muscovite-quartz assemblages representing the garnet-cordierite zone are observed. The garnet-cordierite zone is surrounded by the sillimanite-cordierite zone which shows cordierite-sillimanite-biotite-plagioclase, cordierite-muscovite-biotite-plagioclase and sillimanite-muscovite-biotite-plagioclase assemblages. The peak metamorphic P-T conditions of the first metamorphism calcuted from garnet-biotite-sillimanite-K-feldspar-plagioclase-spinel assemblage are 5.4~7.4 kb and $776-789^{\circ}C$. Real P-T condition of the first metamorphism might be higher than the calcuated P-T condition according to the study based on the phase equilibria. P-T conditions calcuated from the garnet-biotite in plagioclase are 12.5kb and $650^{\circ}C$ which indicate that the P-T path of the first metamorphism had passed a high pressure condition before the peak metamorphic temperature condition. The peak metamorphic P-T conditions of the second metamorphism calcuated from garnet-biotite-cordierite-spinel-quartz assemblage are $680~750^{\circ}C$ at pressures lower than 6 kb. In the Odesan Gneiss Complex, the first metamorphism of medium pressure and high temperature had occurred after the high pressure condition and fast uplift and then the second metamorphism of low pressure condition occurred after sedimentation of the Kuryong Group.

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Features of Epitaxial Garnet Films for an Atomic Traps Technique

  • Berzhansky, V.N.;Vishnevskii, V.G.;Nedviga, A.S.;Nesteruk, A.G.
    • Journal of Magnetics
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    • v.14 no.3
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    • pp.108-113
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    • 2009
  • High-coercive garnet films have certain parameters suitable for creating reconfigurable magnetic atomic chips with visible geometry. However, the inner stresses and morphological properties, namely, networks of dislocations, layering and surface relief, and dependence of coercivity on thickness must be taken into account. Select features of films important for atomic trap creation have been studied experimentally and the supposed traps concept provided.

ANALYSIS OF LPE GROWN GARNET FILM FOR FARADAY ROTATOR

  • Noh, Young-Chul;Lee, Wan-Kyu;Park, Hyun-Sik
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.810-814
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    • 1995
  • LPE growth experiment were carried out to make garnet crystal for Faraday rotator and we have evaluated the characteristics of Faraday rotator by a measurement system which is consist of electromagnet and optical components, also done Laue pattern analysis. The thickness of garnet film was $180\;\mu\textrm{m}$ and the Faraday rotation of this film was 388 deg/Cm at wavelength $1.55\;\mu\textrm{m}$, room temperature.

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