• Title/Summary/Keyword: gap conductance

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Conductance of a Single Molecule Junction Formed with Ni, Au, and Ag Electrodes

  • Kim, Taekyeong
    • Journal of the Korean Chemical Society
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    • v.58 no.6
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    • pp.513-516
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    • 2014
  • We measure the conductance of a 4,4'-diaminobiphenyl formed with Ni electrodes using a scanning tunneling microscope-based break-junction technique. For comparison, we use Au or Ag electrodes to form a metal-molecular junction. For molecules that conduct through the highest occupied molecular orbital, junctions formed with Ni show similar conductance as Au and are more conductive than those formed with Ag, consistent with the higher work function for Ni or Au. Furthermore, we observe that the measured molecular junction length that is formed with the Ni or Au electrodes was shorter than that formed with the Ag electrodes. These observations are attributed to a larger gap distance of the Ni or Au electrodes compared to that of the Ag electrodes after the metal contact ruptures. Since our work allows us to measure the conductance of a molecule formed with various electrodes, it should be relevant to molecular electronics with versatile materials.

Experimental Study on Manufacturing of Insulation Vacuum Glazing and Measurement of the Thermal Conductance (단열 진공유리의 제작 및 열전달계수 측정에 관한 실험적 연구)

  • Lee Bo-Hwa;Yoon Il-Seob;Kwak Ho-Sang;Song Tae-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.8 s.251
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    • pp.772-779
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    • 2006
  • Window is a critical component in the design of energy-efficient buildings. To minimize the heat loss, insulation performance of the glazing has to be improved. Manufacturing of vacuum glazing has been motivated by the possibility of making windows of very good thermal insulation properties for such applications. It is made by maintaining vacuum in the gap between two glass panes. Pillars are placed between them to withstand the atmospheric pressure. Edge covers are applied to reduce conduction through the edge. Accurate measurements have been made of the radiative heat transfer, the pillar conduction and the gas conduction using a guarded hot plate apparatus. Vacuum glazing is found to have low thermal conductance roughly below $1W/m^2K$. Among the heat transfer modes of residual gas conduction, conduction through support pillar and the radiative heat transfer between the glass panes, the last one is the most dominant to the overall thermal conductance. Vacuum glazing using very low emittance AI-coated glass has an overall thermal conductance of about $0.7W/m^2K$.

The JFNK method for the PWR's transient simulation considering neutronics, thermal hydraulics and mechanics

  • He, Qingming;Zhang, Yijun;Liu, Zhouyu;Cao, Liangzhi;Wu, Hongchun
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.258-270
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    • 2020
  • A new task of using the Jacobian-Free-Newton-Krylov (JFNK) method for the PWR core transient simulations involving neutronics, thermal hydraulics and mechanics is conducted. For the transient scenario of PWR, normally the Picard iteration of the coupled coarse-mesh nodal equations and parallel channel TH equations is performed to get the transient solution. In order to solve the coupled equations faster and more stable, the Newton Krylov (NK) method based on the explicit matrix was studied. However, the NK method is hard to be extended to the cases with more physics phenomenon coupled, thus the JFNK based iteration scheme is developed for the nodal method and parallel-channel TH method. The local gap conductance is sensitive to the gap width and will influence the temperature distribution in the fuel rod significantly. To further consider the local gap conductance during the transient scenario, a 1D mechanics model is coupled into the JFNK scheme to account for the fuel thermal expansion effect. To improve the efficiency, the physics-based precondition and scaling technique are developed for the JFNK iteration. Numerical tests show good convergence behavior of the iterations and demonstrate the influence of the fuel thermal expansion effect during the rod ejection problems.

손상 핵연료의 온도 및 산소대 금속 비율의 변화 모형 연구

  • 서영하;박광헌;호광일
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05c
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    • pp.329-334
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    • 1996
  • 손상 핵연료의 온도 및 산소대 금속 비율의 변화모형을 연구하였다. 열역학적 분석과 산화과정에 대한 분석을 통해 손상핵연료에서의 핵연료 온도와 핵연료내 O/U값 변화를 기술함으로써 결함발생에 의한 핵연료내 냉각수 침투는 Gap conductance를 떨어뜨리고 소결체 산화에 따른 O/U값 증가로 열전달특성의 저하를 가져와 핵연료의 온도를 상승시킨다는 결과를 얻어냈다.

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Enhancement of Response Speed in a-Ge:H Thin Film Semiconductor (수소화된 박막 비정질 Ge 반도체의 전기적 응답속도 향상 방안)

  • 최규남
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.261-264
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    • 1995
  • The response speed enhancement in picosecond photoconductor made from RF planar magnetron sputtered hydrogenated amorphous germanium thin film is discussed. Pulsed laser annealing technique was used to fabricate the highly conductive ohmic contacts and to remove the shallow deflects in the deposited photoconductive film using the different laser powers. Measured V-I curve showed -5 times bigger conductance in photoconductive gap than the one used by the conventional vacuum annealing method using strip heater.

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Andreev reflection in the c-axis transport of $Bi_2$$Sr_2$Ca$Cu_2$$O_{8+x}$ single crystals near $T_c$

  • Chang, Hyun-Sik;Lee, Hu-Jong
    • Progress in Superconductivity
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    • v.3 no.2
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    • pp.140-145
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    • 2002
  • An enhancement of the c-axis differential conductance around the zero-bias voltage near the superconducting transition temperature $T_{c}$ has been observed in $Au/Bi_2$$Sr_2$$CaCu_2$$O_{8+x}$ junctions. We attribute such an enhancement to the Andreev reflection (AR) between the surface Cu-O bilayer with suppressed superconductivity and the next superconducting Cu-O bilayer. The continuous evolution of the differential conductance, from gap like depression to an AR-like peak structure, around the zero-bias voltage points to weakening of the barrier strength of the nonsuperconducting layer between adjacent Cu-O bilayers as temperature approaches $T_{c}$ from below. The peak structure disappeared just below the bulk $T_{c}$ value of underdoped Bi2212 single crystals, whereas it survived up to ~1 K above $T_{c}$ in Junctions prepared on slightly overdosed crystals. According to a recently proposed theoretical consideration, a wider temperature range of the AR a bone $T_{c}$ is expected in the underdoped regime when phase-incoherent preformed pairs emerge in the pseudogap state. Our result is in contradiction to the preformed pair scenario. scenario.o.

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3D Finite Element Simulation of Pellet-Cladding Mechanical Interaction (3차원 유한요소를 이용한 핵연료와 피복관 기계적 거동 해석)

  • Seo, Sang Kyu;Lee, Sung Uk;Lee, Eun Ho;Yang, Dong Yol;Kim, Hyo Chan;Yang, Yong Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.5
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    • pp.437-447
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    • 2016
  • In a nuclear power plant, the fuel assembly, which is composed of fuel rods, burns, and the high temperature can generate power. The fuel rod consists of pellets and a cladding that covers the pellets. It is important to understand the pellet-cladding mechanical interaction with regard to nuclear safety. This paper proposes simulation of the PCMI. The gap between the pellets and the cladding, and the contact pressure are very important for conducting thermal analysis. Since the gap conductance is not known, it has to be determined by a suitable method. This paper suggests a solution. In this study, finite element (FE) contact analysis is conducted considering thermal expansion of the pellets. As the contact causes plastic deformation, this aspect is considered in the analysis. A 3D FE module is developed to analyze the PCMI using FORTRAN 90. The plastic deformation due to the contact between the pellets and the cladding is the major physical phenomenon. The simple analytical solution of a cylinder is proposed and compared with the fuel rod performance code results.

Electrical Characteristics of $Nb/Al-AlO_x/Nb$ Tunnel Junction fabricated with $I_c$ Values in the Range of $28 A/cm^2~ 940 A/cm^2$ ($28 A/cm^2~ 940 A/cm^2$의 임계전류밀도 범위로 제작된 $Nb/Al-AlO_x/Nb$ 터널접합의 전기적 특성)

  • 홍현권;김규태;박세일;김구현;남두우
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.4-7
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    • 2002
  • Samples of $Nb/Al-AlO_x/Nb$ tunnel junction with the size of $50 ${\mu}{\textrm}{m}$ {\times} 50 ${\mu}{\textrm}{m}$$ were fabricated by using self-aligning and reactive ion etching technique In the high quality samples, the $V_m$ value (the product of the critical current and subgap resistance measured at 2 mV) was 34 mV at the critical current density of $J_c: 500 A/cm^2 and the V_g$ value (the gap voltage) was 2.8 mV. For the higher $J_c$ sample, voltage fluctuation at the gap voltage was observed. The $V_m and J_c$ values for this sample were 8 mV and 900 A/cm$^2$, respectively. Also, the relationship between critical current density $J_c$ and specific normal conductance $G_s$ of the junctions with $J_c$ in the range of 28 A/cm$^2$~940 A/cm$^2$was investigated.

Temperature and Heat Split Evaluation of Annular Fuel (이중냉각핵연료 온도 및 열유속 분리 평가)

  • Yang, Yong-Sik;Chun, Tae-Hyun;Shin, Chang-Hwan;Song, Kun-Woo
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2236-2241
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    • 2008
  • The surface heat flux of nuclear fuel rod is the most important factor which can affect safety of reactor and fuel. If fuel rod surface heat flux exceeds the CHF(${\underline{C}}ritical$ ${\underline{H}}eat$ ${\underline{F}}lux$), fuel can be damaged. In case of double cooled annular fuel, which is under developing, contains two coolant channels. Therefore, a generated heat in the fuel pellet can move to inner or outer channel and heat flow direction is decided by both sides heat resistance which varied by dimension and material property change which caused by temperature and irradiation. The new program(called DUO) was developed. For the calculation of surface heat flux, a both sides convection by inner/outer coolant, s gap temperature jump and conduction in the fuel are modeled. Especially, temperature and time dependent fuel dimension and material property change are considered during the iteration. A sample calculation result shows that the DUO program has sufficient performance for annular fuel thermal hydraulics design.

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Enthalpy Rise for Pressure Loss of Spacer Grids of Dual Coolant Fuel (이중냉각연료에서 지지격자의 압력손실에 대한 엔탈피 증가)

  • Chun, Kun-Ho;Chun, Tae-Hyun;Shin, Chang-Hwan
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3473-3478
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    • 2007
  • A dual side cooling annular fuel having internal and external coolant channels has many advantages basically due to low fuel temperature and high DNBR margin, which can make a significant increase of core power density possible. So recently a 12x12 square annular fuel array was proposed for the fuel assembly to be reloaded without structural interference with operating reactors of OPR-1000s. Even through the inherent potential of the annular fuel on the high power density, it may be seriously eroded in the case of a severe unbalanced mass flux split to the internal and external channels in standpoint of DNB. Mass flux split is determined pressure drop characteristics between inner and outer channels. The spacer grids binding fuel array influence greatly the pressure drop in outer channels and the mass flux split. As an important factor of DNB behavior, the enthalpy differences at both channel exits were evaluated using the mass flux splits.

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