• Title/Summary/Keyword: gamma particle

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Preparation of γ-oryzanol-loaded pectin micro and nanocapsules and their characteristics according to particle size (감마오리자놀 함유 칼슘-펙틴 미세 및 나노캡슐의 제조와 입자 크기에 따른 캡슐특성)

  • Lee, Seul;Kim, Eun Suh;Lee, Ji-Soo;Lee, Hyeon Gyu
    • Korean Journal of Food Science and Technology
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    • v.49 no.1
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    • pp.110-116
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    • 2017
  • ${\gamma}-Oryzanol-loaded$ calcium-pectin micro- and nanocapsules were prepared by ionic gelation to improve oxidation stability and the effect of particle size on capsule properties was investigated. The physical properties were influenced by preparation conditions such as concentrations of pectin, $CaCl_2$, ${\gamma}-oryzanol$, and hardening time. Particle sizes of micro- and nanocapsules that showed the maximum encapsulation efficiency and sustained release were $2.27{\pm}0.02mm$ and $347.7{\pm}58.1nm$, respectively. Microcapsules showed higher encapsulation efficiency ($50.73{\pm}1.98%$) than nanocapsules ($17.70{\pm}2.04%$), while nanocapsules showed more sustained release and higher stability than microcapsules. Release of ${\gamma}-oryzanol$ from both microand nanocapsules, which was low in gastric environments and promoted in intestinal environments, showed suitable characteristics for oral administration. Furthermore, antioxidant activity of ${\gamma}-oryzanol$ against autoxidation of linoleic acid was prolonged by both micro- and nanoencapsulation in a ferric thiocyanate test. Therefore, micro- and nanoencapsulation using pectin can be effective for improving biodelivery, stability, and antioxidant activity of ${\gamma}-oryzanol$.

Simulation of the Determination of NaCl Concentration in Concrete samples by the Neutron induced Prompt Gamma-ray Method

  • Kim, Hyeon-Soo
    • Journal of Environmental Science International
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    • v.13 no.2
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    • pp.175-180
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    • 2004
  • A prompt gamma-ray neutron activation (PGNA) system was simulated by the Monte Carlo N-Particle transport code (MCNP-4A) to estimate the level at which the scattered photon fluence rate, the absolute efficiency of the HPGe-detector, the volume of the concrete sample and the $^{35}$ /Cl(n, ${\gamma}$) reaction rate in this sample contribute to the count rate in the NaCl concentration measurement. The n- ${\gamma}$ fluence rates at the ST-2 beam tube exit of the HANARO reactor were used as input data, and the GAMMA-X type HPGe detector was modeled to tally 1.1649 MeV ${\gamma}$ -rays emitted from the $^{35}$ Cl(n, ${\gamma}$) reaction in the concrete sample. For three cylindrical concrete samples of 13.8, 46.8 and 157.1 ㎤ volumes, respectively, the relations between the NaCl weight fractions of 0.1, 1, 2 and 5 % in each of the concrete samples and the 1.1 649 MeV pulses created in the HPGe detector model were studied. As a result, it was found that the count rate at the same NaCl concentration nearly depends on the volume of the samples in a simulated condition of the same NaCl concentration samples, and that the linearities of the NaCl concentration calibration curves were reasonable in the narrow range of the NaCl weight fraction.

Optimization of Rod-shaped γ-LiAlO2 Particle Reinforced MCFC Matrices by Aqueous Tape Casting (수계 테이프 케스팅 법에 의한 봉상 γ-LiAlO2 입자 강화 MCFC 매트릭스 제조 공정의 최적화)

  • Choi, Hyun-Jong;Shin, Mi-Young;Hyun, Sang-Hoon;Lim, Hee-Chun
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.282-287
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    • 2009
  • Rod-shaped particle reinforced $LiAlO_2$ matrices for MCFC were fabricated by an aqueous tape-casting technique. The hydrolysis reaction and agglomeration of $\gamma-LiAlO_2$ particles in aqueous slurries were inhibited by additions of $LiOH{\cdot}H_2O$ and glycerin to the aqueous $\gamma-LiAlO_2$ slurry. The tape-casting, performed using the aqueous slurry containing protein albumin, was fast and led to an effective drying at casting temperature range of $60{\sim}65^{\circ}C$. The strength of the particle reinforced matrix was improved about 4 times compared to that of matrix without reinforcement. Pore size distribution ($0.1{\sim}0.4{\mu}m$) and porosity ($50{\sim}60%$) of the reinforced matrices were determined to be appropriate for the MCFC matrix. The aqueous tape casting process is not only environmental-friendly but also efficient for fabricating MCFC matrices compared to non-aqueous tape casting.

Effect of palm oil on the basic geotechnical properties of kaolin

  • Sriraam, Anirudh Subramanya;Raghunandan, Mavinakere Eshwaraiah;Ti, Tey Beng;Kodikara, Jayantha
    • Geomechanics and Engineering
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    • v.18 no.2
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    • pp.179-188
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    • 2019
  • This paper presents an experimental study to evaluate the effect of palm oil on the selected basic physical-chemical and geotechnical properties of kaolin. The experimental findings are further compared with literature outcomes investigating similar properties of fine grained soils subjected to contamination by different types of oils. To this end, palm oil was mixed with oven dried kaolin samples-aiding oil's interaction (coating) with dry particles first, in anticipation to emphasize the effect of oil on the properties of kaolin, which would be difficult to achieve otherwise. Oil content was limited to 40% by dry weight of kaolin, supplemented at intervals of 10% from clean kaolin samples. Observations highlight physical particle-to-particle bonding resulting in the formation of pseudo-silt sized clusters due to palm oil's interaction as evinced in the particle size distribution and SEM micrographs. These clusters, aided by water repellency property of the oil coating the kaolin particles, was analyzed to show notable variations in kaolin's consistency-measured as liquid and plastic limits. Furthermore, results from compaction tests indicates contribution of oil's viscosity on the compaction behavior of kaolin - showing decrease in the maximum dry unit weight (${\gamma}_{d,max}$) and optimum moisture content ($w_{opt}$) values with increasing oil contents, while their decrease rates were directly and inversely proportional in ${\gamma}_{d,max}$ and $w_{opt}$ values with oil contents respectively. Comparative study in similar terms, also validates this lower and higher decrease rates in ${\gamma}_{d,max}$ and $w_{opt}$ values of the fine grained soils respectively, when subjected to contamination by oil with higher viscosity.

Ultrastructural Studies of Encystment in Allomyces macrogynus

  • Kim, Jung-Soeup;Youn, Hyun-Joo;Cho, Chung-Won
    • Journal of Microbiology
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    • v.34 no.3
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    • pp.220-224
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    • 1996
  • Ultrastructural organization of encysting zoospores of Allomyces macrogynus was examined using the methods of cryofixation and freeze substitution. During enxcystment, obvious changes were observed at the surface of the plasma membrane and in the structure of gamma particles. Many multivesicular bodies associated with the plasma membrane were observed at early stages of encystment. After induction of encystment, vesicles were found within the gamma particles. These vesicles appeared to leave gamma particles after forming multivesicular bodies. This study suggests that the cell wall formation during encystment is mediated by the fusion of multivesicular bodies with the plasma membrane.

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Gamma ray interactions based optimization algorithm: Application in radioisotope identification

  • Ghalehasadi, Aydin;Ashrafi, Saleh;Alizadeh, Davood;Meric, Niyazi
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3772-3783
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    • 2021
  • This work proposes a new efficient meta-heuristic optimization algorithm called Gamma Ray Interactions Based Optimization (GRIBO). The algorithm mimics different energy loss processes of a gamma-ray photon during its passage through a matter. The proposed novel algorithm has been applied to search for the global minima of 30 standard benchmark functions. The paper also considers solving real optimization problem in the field of nuclear engineering, radioisotope identification. The results are compared with those obtained by the Particle Swarm Optimization, Genetic Algorithm, Gravitational Search Algorithm and Grey Wolf Optimizer algorithms. The comparisons indicate that the GRIBO algorithm is able to provide very competitive results compared to other well-known meta-heuristics.

Synthesis of Silica Nanoparticles Having the Controlled Size and their Application for the Preparation of Polymeric Composites (크기가 제어된 실리카 나노입자 합성과 제조된 입자의 고분자계 복합재 응용)

  • Kim, Jong-Woung;Kim, Chang-Keun
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.75-79
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    • 2006
  • Silica nanoparticles for polymeric dental restorative composites were prepared by Stober method, and then the effects of surface treatment of silica particles with Lmethacrylofpropyltrimethofsilane $(\gamma-MPS)$ on the dispersity of the silica particles in the organic matrix was investigated. Particles having various average size were prepared by using controlled amounts of tetraethylorthosilicate(TEOS), water, and catalyst and by changing solvent used for reaction. The site of particles prepared by using methanol as solvent was smaller than that prepared by using ethanol as solvent. In addition, the size of particles was increased by decreasing amounts of water and by increasing amounts of TEOS and catalyst. Hydrophobic silica nanoparticles was prepared by reacting hydrophilic nanoparticles with $\gamma-MPS$ to improve interfacial properties with organic matrix. Amounts of $\gamma-MPS$ per unit mass of the particles was increased by decreasing particle size. even though the amount of $\gamma-MPS$ per specific surface area were nearly the same regardless of the particle size. The dispersity of the silica particles in the organic matrix was improved when the surface treated silica particles were used for preparing the polymeric dental restorative composites.

Particle Characteristics of Flame-Synthesized γ-Al2O3 Nanoparticles (화염법으로 제조된 감마-Al2O3 나노입자의 화염조건에 따른 입자특성 연구)

  • Lee, Gyo-Woo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.5
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    • pp.509-515
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    • 2012
  • In this study, ${\gamma}-Al_2O_3$ nanoparticles were synthesized by using coflow hydrogen diffusion flames. The synthesis conditions were varied with using several oxygen concentrations in the oxidizing air. The particle characteristics of the flame-synthesized $Al_2O_3$ nanoparticles were determined by examining the crystalline structure, shape, and specific surface area of the nanoparticles. The measured maximum centerline temperature of the flames ranged from 1507.8 K to 1998.7 K. The morphology and crystal structure of the $Al_2O_3$ nanoparticles were determined from SEM images and XRD analyses, respectively. The particle sizes were calculated from measured BET specific surface areas and ranged from 25 nm to 52 nm. From XRD analyses, it was inferred that a large number of the synthesized nanoparticles were ${\gamma}-Al_2O_3$ nanoparticles including ${\theta}-Al_2O_3$ nanoparticles.

Analysis of Inter-Particle Distance Distribution in a Diamond Sawing Blade

  • Lee, Hyun-Woo;Kim, Yong-Seog
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2003.10a
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    • pp.62-63
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    • 2003
  • The inter-particle distance between diamonds on the segment surface of sawing blade predicted theoretically and measured experimentally followed a Gamma or Weibull function, rather than a normal distribution function. These results suggest that random dispersion of diamond particles in the segment may not be an efficient way of improving cutting efficiency of the blade.

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Effect of $\alpha-Al_2O_3$ Seeds and Alumina Sol on $\alpha$-Alumina Powder Derived from $\gamma-Al_2O_3$ ($\gamma$-알루미나부터 $\alpha$-알루미나 분말 제조에 있어 Seeding과 알루미나 졸이 미치는 영향)

  • 임경란;장진욱;임창섭;홍국선
    • Journal of the Korean Ceramic Society
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    • v.32 no.4
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    • pp.482-488
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    • 1995
  • The phase transformation temperature from $\theta$- to $\alpha$-alumina was lowered from 1214$^{\circ}C$ to 114$0^{\circ}C$ in DSC by treating ${\gamma}$-alumina obtained by calcination of boehmite at $700^{\circ}C$ for 2hrswith $\alpha$-Al2O3 seeds (d50=0.36${\mu}{\textrm}{m}$) and 3wt% of the alumina sol. $\alpha$-Al2O3 seeds seemed to lower to the transformation temperature and the alumina sol suppressed the high temperature agglormeration. The effect was increased as the amount of the sol was increased, which was supported by TEM and particle size distribution. For an example, spherical ${\gamma}$-alumina powder with d50=0.54${\mu}{\textrm}{m}$ was prepared by treating the ${\gamma}$-alumina with 9 wt% of the alumina sol and 3wt% of the $\alpha$-Al2O3. It sintered to 99% of the theoretical density at 150$0^{\circ}C$ for 2hrs. and it had relatively homogeneous microstructure with 2~3${\mu}{\textrm}{m}$ sized grains.

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