• Korean Journal of Metals and Materials
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• v.46 no.7
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• pp.427-436
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• 2008

The effect of dewpoints on annealing behavior and coating characteristics such as wettability and galvannealing kinetics was studied by annealing 0.3wt%Si - 0.1~0.4wt% Mn added interstitial-free high strength steels(IF-HSS). The 0.3wt%Si-0.1wt%Mn steel exhibited good wettability with molten zinc and galvannealing kinetics after annealing when the dewpoint of $H_2-N_2$ mixed gas was above $-20^{\circ}C$. It is shown that the wettability and galvannealing kinetics are directly related to the coverage of the external(surface) oxide formed by selective oxidation during annealing. At $N_2-15%H_2$ annealing atmosphere, the increase of dewpoint results in a gradual transition from external to internal selective oxidation. The decrease of external oxidation of alloying elements with a concurrent increase of their subsurface enrichment in the substrate, showing a larger surface area that was free of oxide particles, contributed to the improved wettability and galvannealing kinetics. On the other hand, the corresponding wettability and galvannealing kinetics were deteriorated with the dewpoints below $-20^{\circ}C$. The continuous oxide layer of network and/or film type was formed on the steel surface, leading to the poor wettability and galvannealing kinetics. It causes a high contact angle between annealed surface and molten zinc and plays an interrupting role in interdiffusion of Zn and Fe during galvannealing process.

• Journal of the Korean institute of surface engineering
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• v.31 no.5
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• pp.286-296
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• 1998

Galvannealing is becomming the main stream of the coating technology applied to automobile outer and inner panels due to its low cost and easy application applied to automobile outer and inner panels due to its low cost and easy application in thick Zn coating, compared to electro galvanizing. Despite of filed up data with an experience in this field, galvannealing in thick Zn coating is getting more difficult because of the absence of Fe deposition in Zn coating. As a result, it exhibits, with different steel sheet and grain size there is a proper temperature range which is good for the tarket coating thickness of galvannealing. In case of 1,200mm wide and 0.77 mm thick extra low carbon steel with 20$mu extrm{m}$ grain size, its proper temperature range for galvannealing of one side 60g/$\textrm{m}^2$ is 470-$480^{\circ}C$.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.32 no.12
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• pp.1107-1114
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• 2008

This paper is aimed to understand the effect of different galvannealing temperatures on the frictional properties and Fe-Zn intermetallic phases of the galvannealed (GA) coatings on steel sheets. Their galvannealing treatments were conducted at 465, 505, 515 and $540^{\circ}C$ for about 10s in the additional heating furnace of an industrial continuous hot-dip galvanizing line. The mechanical and the frictional properties of the coatings were estimated using nanoindentation, nanoscratch, micro vickers hardness tests and flat friction tests, which were performed at contact pressures of 4, 20 and 80MPa. Also, the correlation between the microstructure and the frictional properties of the GA coatings were investigated by SEM observation for the cross-section of the GA coating after and before flat friction tests. The results showed that the mechanical and the frictional properties of the coatings are strongly dependent on their phase distributions and microstructure. Especially, in low contact pressure of 4MPa the frictional properties of the coatings were dependent on the surface phases and morphology, while in high contact pressure of 80MPa it was influenced by their mechanical properties based on the dominant phase distributions.

• Journal of the Korean institute of surface engineering
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• v.34 no.3
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• pp.247-257
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• 2001

In an effort to improve the dent resistance of exterior body panels at a reduced steel thickness, the bake hardenable steels added Ti or Nb with tensile strength of 35Kgf/$\textrm{mm}^2$ were investigated. The bake hardenability increased with the annealing temperature and solute carbon content. Bake hardening of 3 to 5Kgf/$\textrm{mm}^2$ was obtained in steels with a controlled solute carbon concentration range from 6 to 10ppm. The galvannealing temperature and time had little influence on the bake hardenability. The Fe-Zn alloying reaction of 35Kgf/$\textrm{mm}^2$ BH steel was remarkably retarded due to a 0.07%P addition. The optimum galvannealing temperatures of 35Kgf/$\textrm{mm}^2$ BH steel were ranged from 520 to 56$0^{\circ}C$ in view of the Fe content and powdering resistance. The cross-section and planar views of the galvannealed coatings to characterize morphology development were discussed.

• Corrosion Science and Technology
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• v.10 no.1
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• pp.30-36
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• 2011

The effect of dynamic flow or forced convection were investigated and compared on the formation of inhibition layer, galvanizing and galvannealing reactions through the hot-dip galvanizing simulator with the oscillation of specimen in zinc bath, continuous galvanizing pilot plant with zinc pumping system through the snout and continuous galvanizing operation with Dynamic $Galvanizing^{TR}$ system. The interfacial Al pick-up was not consistent between the results of simulator, pilot plant and line operation, but the morphology of inhibition layer became compact and refined by the forced convection. The growth of Fe-Zn intermetallics at the interface was inhibited by the forced convection, whereas the galvannealing rate would be a little promoted.

• Korean Journal of Metals and Materials
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• v.46 no.2
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• pp.58-64
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• 2008

Surface-void defects observed on the galvannealed(GA) steel sheets in Interstitial-free high-strengthened steels containing Si and Mn have been investigated using the combination of the FIB(Focused Ion Beam) and FE-TEM(Field Emission-Transmission Electron Microscope) techniques. The scanning ion micrographs of cross-section microstructure of defects showed that these defects were identified as craters which were formed on the projecting part of the substrate surface. Also, those craters were formed on the Si or Mn-Si oxides film through the whole interface between galvannealed coating and steel substrate. Interface enrichments and oxidations of the active alloying elements such as Si and Mn during reduction annealing process for galvanizing were found to interrupt Zn and Fe interdiffusion during galvannealing process. During galvannealing, Zn and Fe interdiffusion is preferentially started on the clean substrate surface which have no oxide layer on. And then, during galvannealing, crater is developed with consumption of molten zinc on the oxide layer.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 1999.05a
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• pp.77-78
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• 1999

• Journal of the Korean institute of surface engineering
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• v.33 no.2
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• pp.135-144
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• 2000

Hot-dip galvannealed sheet (GA) with high strength of $45kg/mm^2$ in tensile strength, has developed for automotive applications. However, for a successful application, the powdering behaviour of GA must be minimized. The powdering of galvannealed coatings was reduced as the silicon content in the steel increased. Rapid heating and rapid cooling rate during the galvannealing process improved the powdering resistance due to the suppression of not only the ξ phase, but also the $ \Gamma _1$, phase. An analysis of the Fe-Zn alloy phases and its relation to the powdering behaviour are discussed with SEM micrographs.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.6
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• pp.141-147
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• 2008

Hot-dip galvannealed sheet (GA) with high strength of 590MPa grade in tensile strength, has developed for automotive applications. However, for a successful application, the microstructure and galvannealing behavior of galvannealed TRIP steel sheets must be strictly controlled. High silicon contents steel has problems with weld-ability, zinc coating and reduction of retained austenite volume fraction after galvannealing process. The main purpose of this study is to solve the problem as indicated above.

• Corrosion Science and Technology
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• v.10 no.2
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• pp.47-51
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• 2011

Main issues in the automotive industry are the reduction of vehicle body weight for energy savings and improvement of crashworthiness for passenger safety. In order to address both these issues, there has recently been increasing application of galvannealed advance high strength steel (GA AHSS) sheets for automobiles. However, GA AHSS sheets have some surface defects such as coating bare spots due to the addition of solid-solution strengthening elements, which result in the deterioration of the galvannealing reaction. In this study, the effects of galvannealed manufacturing conditions on surface and mechanical properties, resistance spot weldability on a laboratory scale, and GA 980 MPa steel sheets produced by commercial continuous galvannealing line (CGL) were investigated.