• Title/Summary/Keyword: fundamental variables

Search Result 473, Processing Time 0.034 seconds

Preparation of Active Cu/ZnO-based Catalysts for Methanol Synthesis (메탄올 생산용 고활성 Cu/ZnO 촉매 합성방법)

  • Jeong, Cheonwoo;Suh, Young-Woong
    • Applied Chemistry for Engineering
    • /
    • v.27 no.6
    • /
    • pp.555-564
    • /
    • 2016
  • In recent years, methanol has attracted much attention since it can be cleanly manufactured by the combined use of atmospheric $CO_2$ recycling and water splitting via renewable energy. For the concept of "methanol economy", an active methanol synthesis catalyst should be prepared in a sophisticated manner rather than by empirical optimization approach. Even though Cu/ZnO-based catalysts prepared by coprecipitation are well known and have been extensively investigated even for a century, fundamental understanding on the precipitation chemistry and catalyst nanostructure has recently been achieved due to complexity of the necessary preparation steps such as precipitation, ageing, filtering, washing, drying, calcination and reduction. Herein we review the recent reports regarding the effects of various synthesis variables in each step on the physicochemical properties of materials in precursor, calcined and reduced states. The relationship between these characteristics and the catalytic performance will also be discussed because many variables in each step strongly influence the final catalytic activity, called "chemical memory". All discussion focuses on how to prepare a highly active Cu/ZnO-based catalyst for methanol synthesis. Furthermore, the preparation strategy we deliver here would be utilized for designing other coprecipitation-derived supported metal or metal oxide catalysts.

Model Development of Spray Dryer Absorber FGD Process (Spray Dryer Absorber 배연탈황공정의 모델 개발)

  • Jang, Sun-Hee;Oh, Eui-Kyung;Lee, Hyung-Keun;Kim, Sun-Geon
    • Clean Technology
    • /
    • v.2 no.1
    • /
    • pp.80-95
    • /
    • 1996
  • A mathematical model has been developed for simulating the spray dryer absorber (SDA) used in semi-dry flue gas desulfurization process. Fundamental equations include the component mass and heat balances in both gas and droplet phases and the equation of motion for a single droplet. The model developed described the pilot-plant data much better than the existing SPRAYMOD-M model. The effect of the process variables, whose values were chosen within the operation limits of the actual pilot plants, on % $SO_2$ removal or conversion of the sorbent were calculated, and discussed in terms of $SO_2$ absorption rate, the residence time of flue gas, the velocity and drying time of droplets. Finally, the % $SO_2$ removal was calculated with two independent process variables and the results were shown on three-dimensional or two-dimensional diagrams with the lines of constant % $SO_2$ removal, so that they can be easily applied to preliminary design of the SDA.

  • PDF

Macro-Level Accident Prediction Model using Mobile Phone Data (이동통신 자료를 활용한 거시적 교통사고 예측 모형 개발)

  • Kwak, Ho-Chan;Song, Ji Young;Lee, In Mook;Lee, Jun
    • Journal of the Korean Society of Safety
    • /
    • v.33 no.4
    • /
    • pp.98-104
    • /
    • 2018
  • Macroscopic accident analyses have been conducted to incorporate transportation safety into long-term transportation planning. In macro-level accident prediction model, exposure variable(e.g. a settled population) have been used as fundamental explanatory variable under the concept that each trip will be subjected to a probable risk of accident. However, a settled population may be embedded error by exclusion of active population concept. The objective of this research study is to develop macro-level accident prediction model using floating population variable(concept of including a settled population and active population) collected from mobile phone data. The concept of accident prediction models is introduced utilizing exposure variable as explanatory variable in a generalized linear regression with assumption of a negative binomial error structure. The goodness of fit of model using floating population variable is compared with that of the each models using population and the number of household variables. Also, log transformation models are additionally developed to improve the goodness of fit. The results show that the log transformation model using floating population variable is useful for capturing the relationships between accident and exposure variable and generally perform better than the models using other existing exposure variables. The developed model using floating population variable can be used to guide transportation safety policy decision makers to allocate resources more efficiently for the regions(or zones) with higher risk and improve urban transportation safety in transportation planning step.

Wind velocity field during thunderstorms

  • Ponte, Jacinto Jr.;Riera, Jorge D.
    • Wind and Structures
    • /
    • v.10 no.3
    • /
    • pp.287-300
    • /
    • 2007
  • Wind action is a factor of fundamental importance in the structural design of light or slender constructions. Codes for structural design usually assume that the incident mean wind velocity is parallel to the ground, which constitutes a valid simplification for frequent winds caused by meteorological phenomena such as Extratropical Storms (EPS) or Tropical Storms. Wind effects due to other phenomena, such as thunderstorms, and its combination with EPS winds in so-called squall lines, are simply neglected. In this paper a model that describes the three-dimensional wind velocity field originated from a downburst in a thunderstorm (TS) is proposed. The model is based on a semi empirical representation of an axially-symmetrical flow line pattern that describes a stationary field, modulated by a function that accounts for the evolution of the wind velocity with time. The model allows the generation of a spatially and temporally variable velocity field, which also includes a fluctuating component of the velocity. All parameters employed in the model are related to meteorological variables, which are susceptible of statistical assessment. A background wind is also considered, in order to account for the translational velocity of the thunderstorm, normally due to local wind conditions. When the translation of the TS is caused by an EPS, a squall line is produced, causing the highest wind velocities associated with TS events. The resulting vertical velocity profiles were also studied and compared with existing models, such as the profiles proposed by Vicroy, et al. (1992) and Wood and Kwok (1998). The present model predicts horizontal velocity profiles that depend on the distance to the storm center, effect not considered by previous models, although the various proposals are globally compatible. The model can be applied in any region of interest, once the relevant meteorological variables are known, to simulate the excitation due to TS winds in the design of transmission lines, long-span crossings, cable-stayed bridges, towers or similar structures.

Fundamental Studies for the Automatic Control System in the Greenhouse Using Microcomputer(II) -A Development of a Controller for an Automatic Control System- (마이크로컴퓨터에 의한 시설재배의 자동화에 관한 기초연구(II) -자동화 시스템의 종합제어기 개발-)

  • 김진현;김철수
    • Journal of Biosystems Engineering
    • /
    • v.20 no.1
    • /
    • pp.73-86
    • /
    • 1995
  • The automatic control system in the greenhouse have to be developed to the direction of considering various factors the variables such as condition of the cultivation and greenhouse, the properties and types of products. Therefore, it is more important to set up variables appropriately than the problems of automatic control system itself, and the automatic control system which satisfy these problems should be simplified in the aspect of operation. In addition, even the individual automations are not perfect yet, so more studies are required for the development of comprehensive automatic system in korea. This study was carried out to automatize environment control systems for greenhouse, especially from most intensive labor requiring parts such as watering, irrigating liquefied fertilizer, spraying chemicals, mixing and ventilation system, etc. The results are summarized as follows. 1. Control type tensiometer was expected to be desirable in the automation of watering system, therefore, a new tensiometer was designed and developed through this study. 2. The chemical spraying system developed through this study was found to be excellent in the aspect of operation. 3. When pulse type water discharge meter was used in the mixing of liquefied fertilizer and chemical solution, the error of mixing were range $\pm$0.1~0.15%. 4. The water level switch of electrod type used for controlling water level was found to be affective in both control performance and operation cost. 5. The water and level control system can be omitted if each tank size are standardized in accordance with greenhouse size, therefore, the installation cost might be significantly reduced. 6. The developed general controller was excellent in hardware parts, but still remained to be improved in software parts.

  • PDF

An analytic solution for the stirling engines with saw-toothed piston motions in adiabatic cylinders (단열실린더내에서 톱날파형 피스톤운동을 하는 스터링기관에 대한 해석적인 해)

  • 유호선
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.12 no.5
    • /
    • pp.1197-1205
    • /
    • 1988
  • An analytical method to predict qualitative performance characteristics of the Stirling Engines in the preliminary design stages is investigated. Both the expansion and the compression cylinder are treated as adiabatic and piston motions are approximated as saw-toothed waves. Basic equations which were originally proposed by Finkelstein consist of mass conservation and energy balances for each adiabatic cylinder. The approximation on piston motions and physical conditions make it possible to divide an engine cycle into four fundamental processes. In each process, first, pressure can be expressed as a function of the crank angle by solving a nonlinear first order ordinary differential equation and other thermodynamic variables are determined in turn. Application of the cyclic steady condition to the whole processes can complete a cycle. Also, further analysis results in analytic expressions for cyclic work and heat transfer in terms of the engine parameters and thermodynamic variables at boundary points. The results are expected useful as a quick reference for the engine performances. Finally, the present method can be applied to the other adiabatic analyses on the Stirling Engines with piece wise linear piston motions, if mass variations are predictable.

Assessment of Historical and Future Climatic Trends in Seti-Gandaki Basin of Nepal. A study based on CMIP6 Projections

  • Bastola Shiksha;Cho Jaepil;Jung Younghun
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2023.05a
    • /
    • pp.162-162
    • /
    • 2023
  • Climate change is a complex phenomenon having its impact on diverse sectors. Temperature and precipitation are two of the most fundamental variables used to characterize climate, and changes in these variables can have significant impacts on ecosystems, agriculture, and human societies. This study evaluated the historical (1981-2010) and future (2011-2100) climatic trends in the Seti-Gandaki basin of Nepal based on 5 km resolution Multi Model Ensemble (MME) of 18 Global Climate Models (GCMs) from the Coupled Model Intercomparison Project Phase 6 (CMIP6) for SSP1-2.6, SSP2-4.5 and SSP5-85 scenarios. For this study, ERA5 reanalysis dataset is used for historical reference dataset instead of observation dataset due to a lack of good observation data in the study area. Results show that the basin has experienced continuous warming and an increased precipitation pattern in the historical period, and this rising trend is projected to be more prominent in the future. The Seti basin hosts 13 operational hydropower projects of different sizes, with 10 more planned by the government. Consequently, the findings of this study could be leveraged to design adaptation measures for existing hydropower schemes and provide a framework for policymakers to formulate climate change policies in the region. Furthermore, the methodology employed in this research could be replicated in other parts of the country to generate precise climate projections and offer guidance to policymakers in devising sustainable development plans for sectors like irrigation and hydropower.

  • PDF

Heat Transfer Depending on 3D Printing Material and Shape for Protector Development (3D 프린팅 보호대 개발을 위한 재료와 구조에 따른 열전달 평가)

  • Okkyung Lee;Soyoung Kim;Yejin Lee;Heeran Lee
    • Fashion & Textile Research Journal
    • /
    • v.25 no.4
    • /
    • pp.497-507
    • /
    • 2023
  • This study measured the effect 3D printing products comprised of different materials and shapes on heat transfer in clothing to derive fundamental data on thermal comfort among clothing comfort. The variables were three types of material (EVA foam, TPU-10%, TPU-10%+EVA), two types of shape (without holes, with holes), and two types of covers(without cover, with cover). All samples (12 types) prepared by combining these variables were placed on the hot plate set at 36℃, and the surface temperature was measured at three points for 10 minutes. The surface temperature change was dependent on the material, shape, and cover of the sample. The sample printed with TPU exhibited higher temperature transfer compared to the EVA foam sample after 10 mins. In addition, the temperature transfer was better when there were holes, and rate decreased when the sample was covered with fabric. We confirmed that material selection of the pad and thermal conductivity of the cover are extremely important in solving thermal stress to the human body caused by functional clothing with protectors. Additionally, as the protector, it is recommended to design the outer shell with a passage, such as a hole, to allow the rapid transfer of heat to the external environment.

The Net Generation Debate: Unpacking Individual Perceptions and Lived Experiences toward Technology Use in Education

  • CHOI, Hyungshin;SO, Hyo-Jeong
    • Educational Technology International
    • /
    • v.13 no.2
    • /
    • pp.257-281
    • /
    • 2012
  • This study aims to examine individual perceptions and lived experiences of the Net generation of student teachers and the previous generation of teachers about their technology use in education. The participants of this study include 106 pre-service teachers and 50 in-service teachers from one teacher education university in Korea. Employing a mixed methodology, we first empirically examined the participants' perceptions toward multiple variables related to technology use in education, namely (a) past ICT experiences in schools, (b) personal computer use, (c) constructivist belief, (d) computer efficacy, (e) attitude toward computer in education, and (f) prospective computer use. In addition, we conducted face-to-face interviews with selected participants for the in-depth investigation of their lived experiences about technology use, beliefs, and attitude. Results indicate that there are significant differences between in-service and pre-service teachers in their prior experiences with technology in schools. However, the pre-service and in-service teachers did not differ significantly in their beliefs, attitude and other technology-related variables, which may indicate the danger of generational determinism in the Net Generation debate. The analysis of interview narratives revealed two major themes about the interplay of one's agency and structural changes in the participants' lived experiences with technology use in education: (a) transition from negative past experiences to opportunities for positive computer use, and (b) attitudes formation and change through apprenticeship experiences and structural influences. In conclusion, this study suggests that the Net Generation debate should move beyond dichotomous or techno-centric thinking. There is a critical need to pay more attention to develop deeper understandings of the fundamental diversity existing within the generation itself. Implications for teacher education are also discussed.

Effects of Material Parameters and Process Conditions on the Roll-Drafting Dynamics

  • Huh, You;Kim, Jong-S.
    • Fibers and Polymers
    • /
    • v.7 no.4
    • /
    • pp.424-431
    • /
    • 2006
  • Roll drafting, a mechanical operation attenuating fiber bundles to an appropriate thickness, is an important operation unit for manufacturing staple yams. It influences not only the linear density regularity of the slivers or staple yams that are produced, but also the quality of the textile product and the efficiency of the thereafter processes. In this research, the dynamic states of the fiber bundle in the roll drafting zone were analyzed by simulation, based on the mathematical model that describes the dynamic behavior of the flowing bundle. The state variables are the linear density and velocity of the fiber bundles and we simulated the dynamics states of the bundle flow, e.g., the profiles of the linear density and velocity in the draft zone for various values of the model parameters and boundary conditions, including the initial conditions to obtain their influence on the dynamic state. Results showed that the mean velocity profile of the fiber bundle was strongly influenced by draft ratio and process speed, while the input sliver linear density has hardly affected the process dynamics. Velocity variance of individual fibers that could be supposed to be a disturbing factor in drafting was also influenced by the process speed. But the major disturbance occurred due to the velocity slope discontinuity at the front roll, which was strongly influenced by the process speed. Thickness of input sliver didn't play any important role in the process dynamics.