• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.425.1-425.1
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• 2014

Thermal transport in nanomaterials is not only scientifically interesting but also technological important for various future electronic, bio, and energy device applications. Among the various computation approaches to investigate lattice thermal transport phenomena in nanoscale, the atomistic nonequilibrium Green's function approach based on first-principles density functional theory calculations appeared as a promising method given the continued miniaturization of devices and the difficulty of developing classical force constants for novel nanoscale interfaces. Among the nanometerials, carbon atomic chains, namely the cumulene (all-doulble bonds, ${\cdots}C=C=C=C{\cdots}$) and polyyne (alternation of single and triple bonds, ${\cdots}C{\equiv}C-C{\equiv}C{\cdots}$) can be considered as the extream cases of interconnction materials for nanodevices. After the discovery and realization of carbon atomic chains, their electronic transport properties have been widely studied. For the thermal transport properties, however, there have been few literatures for this simple linear chain system. In this work, we first report on the development of a non-equilibrium Green's function theory-based computational tool for atomistic thermal transport calculations of nanojunctions. Using the developed tool, we investigated phonon dispersion and transmission properties of polyethylene (${\cdots}CH2-CH2-CH2-CH2{\cdots}$) and polyene (${\cdots}CH-CH-CH-CH{\cdots}$) structures as well as the cumulene and polyyne. The resulting phonon dispersion from polyethylene and polyene showed agreement with previous results. Compared to the cumulene, the gap was found near the ${\Gamma}$ point of the phonon dispersion of polyyne as the prediction of Peierls distortion, and this feature was reflected in the phonon transmission of polyyne. We also investigated the range of interatomic force interactions with increase in the size of the simulation system to check the convergence criteria. Compared to polyethylene and polyene, polyyne and cumulene showed spatially long-ranged force interactions. This is reflected on the differences in phonon transport caused by the delicate differences in electronic structure.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.195-195
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• 2012

Recently, graphene based solution-gated field-effect transistors (SGFETs) have been received a great attention in biochemical sensing applications. Graphene and reduced graphene oxide (RGO) possess various advantages such as high sensitivity, low detection limit, label-free electrical detection, and ease of fabrication due to their 2D nature and large sensing area compared to 1D nanomaterials- based nanobiosensors. Therefore, graphene or RGO -based SGFET is a good potential candidate for sensitive detection of protons (H+ ions) which can be applied as the transducer in various enzymatic or cell-based biosensing applications. However, reports on detection of H+ ions using graphene or RGO based SGFETs have been still limited. According to recent reports, clean graphene grown by CVD or exfoliation is electrochemically insensitive to changes of H+ concentration in solution because its surface does not have terminal functional groups that can sense the chemical potential change induced by varying surface charges of H+ on CVD graphene surface. In this work, we used RGO -SGFETs having oxygen-containing functional groups such as hydroxyl (OH) groups that effectively interact with H+ ions for expectation of increasing pH sensitivity. Additionally, we also investigate RGO based SGFETs for bio-sensing applications. Hydroloytic enzymes were introduced for sensing of biomolecular interaction on the surface of RGO -SGFET in which enzyme and substrate are acetylcholinesterase (AchE) and acetylcholine (Ach), respectively. The increase in H+ generated through enzymatic reaction of hydrolysis of Ach by AchE immobilized on RGO channel in SGFET could be monitored by the change in the drain-source current (Ids).

• 한국건설순환자원학회논문집
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• 제9권1호
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• pp.13-19
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• 2021

현대인들은 지속적인 산업 발전으로 인해 실내 활동 시간이 증가하고 있다. 실내 활동 시간이 늘어남에 따라 실내 공기질에 대한 관심이 또한 높아지고 있지만 현대 건축물들은 기능성을 위해 폐쇄적인 형태를 지니고 있는 실정이다. 실내 대기 오염의 주요 원인은 화학적 원인인 포름알데히드와 생물학적 원인인 곰팡이가 대표적이다. 이러한 문제점을 해결하기 위해 천연물질을 통한 실내 공기질 개선에 대한 연구가 활발하게 이루어지고 있다. 그 중 천연물질인 피톤치드는 포름알데히드와 곰팡이를 효과적으로 감소시키는 것으로 알려져 있다. 또한, 다공성 구조를 가진 숯은 오염물질에 대한 높은 흡수율을 지니고 있다. 본 연구에서는 실내공기질 오염의 주된 원인인 포름알데히드와 곰팡이를 제거하기 위해 피톤치드와 숯을 혼입하여 기능성 시멘트 경화체를 제작하고 이를 통한 실내 공기질 개선에 대한 연구를 진행하였으며, 실험 결과 피톤치드와 숯을 혼입한 기능성 시멘트 경화체는 포름알데히드와 곰팡이를 저감시키고 실내 공기질을 효과적으로 개선하는 것을 알 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제29권1호
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• pp.139-147
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• 2008

New PPV derivatives which contain electron-withdrawing CF3F4phenyl group, poly[2-(2-ethylhexyloxy)-5-(2,3,5,6-tetrafluoro-4-trifluoromethylphenyl)-1,4-phenylenevinylene] (CF3F4P-PPV), and poly[2-(4-(2-etylhexyloxy)-phenyl)-5-(2,3,5,6-tetrafluoro-4-trifluoromethylphenyl)-1,4-phenylenevinylene] (P-CF3F4P-PPV), have been synthesized by GILCH polymerization. As the result of the introduction of the electron-withdrawing CF3F4phenyl group to the phenyl backbone, the LUMO and HOMO energy levels of CF3F4P-PPV (3.14, 5.50 eV) and P-CF3F4P-PPV (3.07, 5.60 eV) were reduced. The PL emission spectra in solid thin film are more red-shifted over 50 nm and increased fwhm (full width at half maximum) than solution conditions by raising aggregation among polymer backbone due to electron withdrawing effect of 2,3,5,6-tetrafluoro-4-trifluoromethylphenyl group. The EL emission maxima of CF3F4P-PPV and P-CF3F4P-PPV appear at around 530-543 nm. The current density-voltage-luminescence (J-V-L) characteristics of ITO/PEDOT/polymer/Al devices of CF3F4P-PPV and P-CF3F4P-PPV show that turn-on voltages are around 12.5 and 7.0 V, and the maximum brightness are about 82 and 598 cd/m2, respectively. The maximum EL efficiency of P-CF3F4P-PPV (0.51 cd/A) was higher than that of CF3F4P-PPV (0.025 cd/A).

• 공업화학
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• 제17권2호
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• pp.177-182
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• 2006

본 연구는 층상 실리케이트의 한 종류인 MMT (Montmorillonite) 표면의 금속이온을 이온 교환반응에 의해 다양한 구조를 가지고 있는 방향족 암모늄염으로 치환함으로써 내열성이 우수한 친유기성 MMT의 제조 및 이를 이용한 폴리이미드(polyimide) 나노복합재의 특성에 관한 것이다. 도입된 개질제의 구조는 내열성 및 반응성을 고려하여 아민기 및 서로 다른 종류의 알킬기가 도입된 방향족 아민을 설계하였으며, 이를 효과적으로 합성하였다. 합성된 개질제와 MMT와의 이온교환반응을 통하여 표면이 유기화된 친유기성 MMT를 제조하였다. 합성된 친유기성 MMT의 XRD 분석으로부터 층간 거리가 최대 $3.3{\AA}$ 증가된 것을 확인할 수 있었으며, 초기 열분해 온도는 $275^{\circ}C$로서 우수한 내열성을 나타내었다. 폴리아믹산과 제조된 친유기성 MMT와의 복합화를 통하여 폴리아믹산 나노복합용액을 제조하였으며, 이를 탈수 고리화하여 폴리이미드/친유기성 MMT 나노복합필름을 제조하였다. WAXD를 통하여 친유기성 MMT의 분산도를 파악하였으며 또한 친유기성 MMT의 함량에 따른 폴리이미드 나노복합필름의 기계적 특성 변화를 연구하였다.

• 항공우주산업기술동향
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• 제6권1호
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• pp.90-98
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• 2008

나노기술(NT, Nanotechnology)은 분자 및 원자 수준에서 물질을 제작 및 가공할 수 있는 초극미세기술을 의미하며, 재료, 물리, 전자 등의 기존의 기술 분야들을 융합하여 새로운 기술 영역을 구축하는 학제간 연구(Interdisciplinary)가 필요한 분야이다. 국내에서는 탄소나노튜브가 향후 반도체를 견인할 10대 신성장동력 미래기술로 선정되어 활발한 연구가 이루어지고 있다. 나노기술이 미소과학 분야라면 우주기술(ST, Space Technology)는 거대 복합과학 분야를 대표하는 기술로서 기계, 재료, 전자, 통신 등의 기술을 활용하는 시스템 기술이다. 우리나라의 우주개발은 선진국 보다 비록40년 가량 늦었지만 15년 남짓한 기간에 기술자립화 단계로 나아가는 비약적인 성과를 보여주고 있다. 전남 고흥에 나로우주센터가 완공되면 우리 땅에서, 우리 위성을, 우리 발사체로 발사할 수 있게 된다. 나노기술분야는 나노재료, 나노전자, 나노제조 등 매우 광범위하므로 우주기술 개발을 위한 제한된 자원의 견지에서, 비용 대비 성능이 가장 우수하게 평가되는 나노 기술적 구성요소들에 집중하는 것이 필요하다. 본 논문에서는 미국 NASA에서 수행중인 나노기술 개발현황과 유럽의 9차 나노포럼에서 보고한 우주항공분야의 나노기술을 기초로, 현재 우주항공선진국에서 수행중인 개발 현황을 정리하였다. 성능 나노기술의 도움으로 이전에는 불가능하였던 우주 기술이 현실로 다가오고 있는바, 우주개발의 경쟁력을 얻기 위해서는 나노기술을 접목해야만 한다는 것을 알 수 있다. 우리나라는 국가우주개발중장기계획에 따라 2025년 달탐사 착륙선을 개발할 계획이므로, 나노기술을 적극적으로 활용하여 선진국수준의 기술을 확보해야 할 것이다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2010년도 제3회 국제학회
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• pp.40-40
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• 2010

Studies on attractive color changing property of dye chromophore and fluorophore have been greatly enjoyed in the related industrial and research fields such as optoelectronics, chemosensor, biosensor and so on. The optical property based on D-$\Pi$-A intramolecular charge transfer (ICT) system of chromophore molecules can be utilized as suitable sensing probes for checking media polarity and determining colorimetric chemosensing effect, especially heavy metal detection. These finding are obtained by absorption and emission properties. In this work, donor-acceptor D-$\Pi$-A type fluorescent dyes were designed and synthesized with the corresponding donor and acceptor groups. The selected donor moieties might be provided prominent amorphous properties which are very useful in designing and synthesizing functional polymers and in fabricating devices. Another reasons to choose are commercial availabilities in high purity and low price. Donor-bridge-acceptor (D-A) type dyes can produce impressive optical-physical properties, yielding them potentially suitable for applications in the synthesis of small functional organic molecules. Small organic functional molecules have unique advantages, such as better solubility, amorphous character, and represent an area of research which needs to be explored and developed. Currently, their applications in metalorganic compounds is rapidly expanding and becoming widespread in self-assembly processes, photoluminescence applications, chiral organocatalysts, and ingrafts with nanomaterials. Colloidal nanoparticles have received great attentions in recent years. The photophysical properties of nanoparticles, particularly in terms of brightness, photostability, emission color purity and broad adsorption range, are very attractive functions in many applications. To our knowledge background, colloidal nanoparticles have been enjoyed their applications in bio-probe research fields. This research interest can be raised by the advantages of the materials such as high photoluminescence quantum yields, sharp emission band, long-term photostability and broad excitation spectra. In recent, the uses of nanoparticles being embedded in a polymer matrix and binded on polymer surface have been explored and their properties such as photo-activation and strong photoluminescence have been proposed. The prepared chromophores and nanoparticles were investigated with absorption and emission properties, solvatochromic behaviors, pH induced color switching effects, chemosensing effects and HOMO/LUMO energy potentials with computer simulation. In addition, synthesized fluorophore dyes and particles were applied onto PE/Aramid fiber fluorescing colorations. And the related details were then discussed.

• 한국재료학회지
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• 제20권10호
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• pp.513-517
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• 2010

There have been many efforts to modify and improve the properties of functional thin films by hybridization with nano-sized materials. For the fabrication of electronic circuits, micro-patterning is a commonly used process. For photochemical metal-organic deposition, photoresist and dry etching are not necessary for microscale patterning. We obtained direct-patternable $SnO_2$ thin films using a photosensitive solution containing Ag nanoparticles and/or multi-wall carbon nanotubes (MWNTs). The optical transmittance of direct-patternable $SnO_2$ thin films decreased with introduction of nanomaterials due to optical absorption and optical scattering by Ag nanoparticles and MWNTs, respectively. The crystallinity of the $SnO_2$ thin films was not much affected by an incorporation of Ag nanoparticles and MWNTs. In the case of mixed incorporation with Ag nanoparticles and MWNTs, the sheet resistance of $SnO_2$ thin films decreased relative to incorporation of either single component. Valence band spectral analyses of the nano-hybridized $SnO_2$ thin films showed a relation between band structural change and electrical resistance. Direct-patterning of $SnO_2$ hybrid films with a line-width of 30 ${\mu}m$ was successfully performed without photoresist or dry etching. These results suggest that a micro-patterned system can be simply fabricated, and the electrical properties of $SnO_2$ films can be improved by incorporating Ag nanoparticles and MWNTs.

• Restorative Dentistry and Endodontics
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• 제45권4호
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• pp.54.1-54.16
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• 2020

Objectives: This study aimed to synthesize nanocrystals (NCs) of zinc oxide (ZnO) and calcium ion (Ca²⁺)-doped ZnO with different percentages of calcium oxide (CaO), to evaluate cytotoxicity and to assess the effects of the most promising NCs on cytotoxicity depending on lipopolysaccharide (LPS) stimulation. Materials and Methods: Nanomaterials were synthesized (ZnO and ZnO:xCa, x = 0.7; 1.0; 5.0; 9.0) and characterized using X-ray diffractometry, scanning electron microscopy, and methylene blue degradation. SAOS-2 and RAW 264.7 were treated with NCs, and evaluated for viability using the MTT assay. NCs with lower cytotoxicity were maintained in contact with LPS-stimulated (+LPS) and nonstimulated (-LPS) human dental pulp cells (hDPCs). Cell viability, nitric oxide (NO), and reactive oxygen species (ROS) production were evaluated. Cells kept in culture medium or LPS served as negative and positive controls, respectively. One-way analysis of variance and the Dunnett test (α = 0.05) were used for statistical testing. Results: ZnO:0.7Ca and ZnO:1.0Ca at 10 ㎍/mL were not cytotoxic to SAOS-2 and RAW 264.7. +LPS and -LPS hDPCs treated with ZnO, ZnO:0.7Ca, and ZnO:1.0Ca presented similar NO production to negative control (p > 0.05) and lower production compared to positive control (p < 0.05). All NCs showed reduced ROS production compared with the positive control group both in +LPS and -LPS cells (p < 0.05). Conclusions: NCs were successfully synthesized. ZnO, ZnO:0.7Ca and ZnO:1.0Ca presented the highest percentages of cell viability, decreased ROS and NO production in +LPS cells, and maintenance of NO production at basal levels.

• 마이크로전자및패키징학회지
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• 제30권2호
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• pp.1-12
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• 2023

전 세계적 모바일 스마트 기기 혁명은 사람이 접하는 모든 공간에서 독립된 형태의 전기회로를 요구하고 있으며, 전자기기간 연결된 사물인터넷의 구현은 사용자 측면에서 운용이 쉽고 지속 가능한 디지털 생태계 인프라 구축에서 매우 중요한 위치를 차지하고 있다. 이러한 기술은 자동차 전장품, 가정용 가전제품 및 웨어러블 기기의 생산 기술 발전으로 이어지고 있으며, 특히 최근 소개된 인몰드 전자기기(in-mold electronics, IME)는 기존의 대량 공정의 장점을 극대화할 수 있는 기술로 대두되고 있다. 이 기술은 평평한 2차원 기판에 기능성 잉크를 인쇄하고, 3차원 형상으로 열/사출 성형하여 경량화 및 저비용으로 장치를 생산해내는 경제성 강점을 이유로 산업적인 가치를 평가받고 있다. 본 논문에서는 인몰드 전자 장치의 제조기술 및 응용 측면에 대한 가장 최신의 국내외 연구 그룹에서 제안된 기술 개발을 소개하고자 한다. 신체 표면상에서 독립된 형태의 바이오센서 전자소자의 운용을 위한 생체 모사 기술, 에너지 소자, 생체신호 모니터링 센서들을 인몰드 기술로 구현하는 기술 및 장치 구성은, 4차 산업혁명과 함께 성장 중인 유연인쇄전자 기술과 융합되어 회로 기판 제조기술의 혁신을 가져올 것으로 기대된다.