• Title/Summary/Keyword: functional coating

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Fabrication of the Functional Coatings of a Tubular Solid Oxide Fuel by Plasma Spray Processes. (플라즈마 용사법을 이용한 원통형 고체산화물 연료전지의 요소피막 제조)

  • 주원태;홍상희
    • Journal of the Korean institute of surface engineering
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    • v.30 no.5
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    • pp.333-346
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    • 1997
  • Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

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Printability of Thermally and Chemically Stable Silica-Titanium Dioxide Composite Coating Layer (실리카-이산화티탄 복합 코팅층의 열적, 화학적 안정성 및 인쇄적성 평가)

  • Kim, Hye Jin;Han, Kyu Sung;Hwang, Kwang Taek;Nahm, Sahn;Kim, Jin Ho
    • Korean Journal of Materials Research
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    • v.29 no.10
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    • pp.631-638
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    • 2019
  • As automation systems become more common, there is growing interest in functional labeling systems using organic and inorganic hybrid materials. Especially, the demand for thermally and chemically stable labeling paper that can be used in a high temperature environment above $300^{\circ}C$ and a strong acid and base atmosphere is increasing. In this study, a composite coating solution for the development of labeling paper with excellent thermal and chemical stability is prepared by mixing a silica inorganic binder and titanium dioxide. The silica inorganic binder is synthesized using a sol-gel process and mixed with titanium dioxide to improve whiteness at high-temperature. Adhesion between the polyimide substrate and the coating layer is secured and the surface properties of the coating layer, including the thermal and chemical stability, are investigated in detail. The effects of the coating solution dispersion on the surface properties of the coating layer are also analyzed. Finally, it is confirmed that the developed functional labeling paper showed excellent printability.

Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets

  • Jo, Du-Hwan;Kwon, Moonjae;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.15-19
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    • 2012
  • Both electrogalvanized and hot-dip galvanized steel sheets have been finally produced via organic-inorganic surface coating process on the zinc surface to enhance corrosion resistance and afford additional functional properties. Recently, POSCO has been developed a variety of chromate-free coated steels that are widely used in household, construction and automotive applications. New organic-inorganic hybrid coating solutions as chromate alternatives are comprised of surface modified silicate with silane coupling agent and inorganic corrosion inhibitors as an aqueous formulation. In this paper we have prepared new type of hybrid coatings and evaluated quality performances such as corrosion resistance, spot weldability, thermal tolerance, and paint adhesion property etc. The electrogalvanized steels with these coating solutions exhibit good anti-corrosion property compared to those of chromate coated steels. Detailed components composition of coating solutions and experimental results suggest that strong binding between organic-inorganic hybrid coating layer and zinc surface plays a key role in the advanced quality performances.

A study on the mechanical properties of TiN/DLC based functionally graded coatings

  • Song, Young-Sik;Kim, J.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2003.10a
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    • pp.59-59
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    • 2003
  • In recent, various functional coatings on artificial tooth implants have been conducted to enhance the bonding strength between implants and bones. Despite of these efforts, some previous reports argued that an adhesion strength between titanium implant and the final coatings like hydroxyapatite(HA) is weaker than the strength between coating and bone. In order to increase the adhesion force between the final coating and implant surface, TiN/DLC based functionally graded coating, which has higher mechanical strength than the titanium implant, was applied as a middle layer between titanium implant and final coating. Particularly we finally coated a biocompatible hydroxyapatite film on the DLC layer and examined the mechanical properties. As a result, TiN/DLC based functionally graded coating showed the higher adhesion strength compared with hydroxyapatite single layer coating on the titanium implant.

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InP/ZnSe/ZnS: A Novel Multishell System for InP Quantum Dots for Improved Luminescence Efficiency and Its application in a Light-Emitting Device

  • Ippen, Christian;Greco, Tonino;Wedel, Armin
    • Journal of Information Display
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    • v.13 no.2
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    • pp.91-95
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    • 2012
  • Indium phosphide (InP) quantum dots (QDs) are considered alternatives to Cd-containing QDs for application in light-emitting devices. The multishell coating with ZnSe/ZnS was shown to improve the photoluminescence quantum yield (QY) of InP QDs more strongly than the conventional ZnS shell coating. Structural proof for this system was provided by X-ray diffraction and transmission electron microscopy. QY values in the range of 50-70% along with peak widths of 45-50 nm can be routinely achieved, making the optical performance of InP/ZnSe/ZnS QDs comparable to that of Cd-based QDs. The fabrication of a working electroluminescent light-emitting device employing the reported material demonstrated the feasibility of the desired application.

A Study on the Analysis of Fabric Trend Terms and Finishing - Women's Wear Fabrics for Spring/Summer Seasons for 10 Years(1995~2004) - (소재 트렌드를 표현하는 소재 가공 분석 - 10년간(1995~2004) 봄.여름용 여성복 소재를 중심으로 -)

  • Kim, Dong-Woon;Park, Chung-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.2 s.161
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    • pp.217-224
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    • 2007
  • This paper investigated spring/summer fabric trends of women's and analyzed the correlation between the fabric trends and finishing for 10 years (1995 S/S-2004 S/S). Fabric trend terms were selected from 5 fashion journals and were grouped by hierarchical cluster analysis using SPSS 12.0 statistical package. Also, finishing terms were selected and analyzed by frequency. The results showed that 13 representative fabric trend terms were clean, functional, lustrous, compact, rubbery, comfortable, chic, romantic, decorative, natural, fluid, textured, and ethnic trend. In terms of fabric finishing, 12 representative finishing were selected such as coating, calendaring, wrinkle finishing, decorative finishing, quilting, and washing. Finally, in respect of the analysis of fabric trends and finishing, washing and embroidery were used to represent ethnic trends and textured fabric was closely correlated wrinkle and decorative finishing. Fluid fabrics were expressed via wrinkle and coating and washing and wrinkle were used for natural feeling. Decorative fabric was expressed by embroidery and coating and decorative finishing were frequently used to show romantic and chic fabric. Also comfortable fabrics were correlated with easy care and rubbery, compact, lustrous, and clean fabrics were correlated with coating.

Development of Pigment Coated Paper Recognizable With UV Light (자외선 램프로 식별 가능한 안료코팅용지 개발)

  • Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.76-81
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    • 2011
  • This study was carried out in order to develop a speciality functional coated paper, which can be recognized under a ultraviolet lamp. The special fluorescent whitening agent (FWA) which absorbs ultraviolet light (397~410 nm) and emits it as yellowish light (570~500nm) was used. The special FWA was applied in a coating color in two ways: (1) direct application to a coating color as a FWA; (2) application on pigment surface, drying it and application it as a fluorescence whitening pigments (colored pigments). The effects of the special FWA on coating color properties were tested and the distribution of colored pigments in coated paper was evaluated under a ultraviolet lamp. The results showed that the colored pigments didn't affect on coating color properties. Experimental results showed the possibility of producing a security coated paper using the special FWA. To produce a speciality functional paper, it was found to be proper to apply the special FWA in the form of colored pigment.

Aerosol Deposition and Its Potential Use for Bioactive Ceramic Coatings

  • Hahn, Byung-Dong;Park, Dong-Soo;Lee, Jeong-Min;Choi, Jong-Jin;Ryu, Jung-Ho;Yoon, Woon-Ha;Lee, Byoung-Kuk;Choi, Joon-Hwan;Kim, Hyoun-Ee
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.41.1-41.1
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    • 2009
  • Aerosol Deposition (AD) is anovel way to fabricate bioactive ceramic coatings in biomedical implants and prostheses applications. In the present work, silicon-substituted hydroxyapatite (HA) coatings on commercially pure titanium were prepared by aerosol deposition using Si-HA powders. The incorporation of silicon in the HA lattice is known to improve the bioactivity of the HA, makingsilicon-substitute HA an attractive alternative to pure HA in biomedical applications. Si-HA powders with the chemical formula $Ca_{10}(PO_4)_6-x(SiO_4)x(OH)_2-x$, having silicon contents up to x=0.5 (1.4 wt%), were synthesized by solid-state reaction of $Ca_2P_2O_7$, $CaCO_3$, and $SiO_2$. The Si-HA powders were characterized by X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF), and Fourier transform infrared spectroscopy(FT-IR). The corresponding coatings were also analyzed by XRD, scanning electron microscopy (SEM), and electron probe microanalyzer (EPMA). The results revealed that a single-phase Si-HA was obtained without any secondary phases such as $\alpha$- or $\beta$-tricalcium phosphate (TCP) for both the powders and the coatings.The Si-HA coating was about $5\;{\mu}m$ thick, had a densemicrostructure with no cracks or pores. In addition, the proliferation and alkaline phosphatase (ALP) activity of MC3T3-E1 preosteoblast cells grown on the Si-HA coatings were significantly higher than those on the bare Ti and pure HA coating. These results revealed the stimulatory effects induced by siliconsubstitution on the cellular response to the HA coating.

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One-Step β-Li2SnO3 Coating on High-nickel Layered Oxides via Thermal Phase Segregation for Li-ion Batteries

  • Seongmin Kim;Hanseul Kim;Sung Wook Doo;Hee-Jae Jeon;In Hye Kim;Hyun-seung Kim;Youngjin Kim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.293-300
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    • 2023
  • The global energy storage markets have gravitated to high-energy-density and low cost of lithium-ion batteries (LIBs) as the predominant system for energy storage such as electric vehicles (EVs). High-Ni layered oxides are considered promising next-generation cathode materials for LIBs owing to their significant advantages in terms of high energy density. However, the practical application of high-Ni cathodes remains challenging, because of their structural and surface instability. Although extensive studies have been conducted to mitigate these inherent instabilities, a two-step process involving the synthesis of the cathode and a dry/wet coating is essential. This study evaluates a one-step β-Li2SnO3 layer coating on the surface of LiNi0.8Co0.2O2 (NC82) via the thermal segregation of Sn owing to the solubility limit with respect to the synthesis temperature. The doping, segregation, and phase transition of Sn were systematically revealed by structural analyses. Moreover, surface-engineered 5 mol% Sn-coated LiNi0.8Co0.2O2 (NC82_Sn5%) exhibited superior capacity retention compared to bare NC82 owing to the stable surface coating layer. Thus, the developed one-step coating method is suitable for improving the properties of high-Ni layered oxide cathode materials for application in LIBs.

A QCM-based Sensor System for Detecting NO2 and SO2 (QCM기반 NO2와 SO2 감지용 센서시스템)

  • Hwang, Min-Jin;Shim, Wang Geun;Moon, Hee
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.285-291
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    • 2013
  • The effects of sensing materials, coating methods, diluent gases, and temperature have been studied in detail to make a quartz crystal microbalance based adsorption sensor system for detecting gases. In particular, sensor elements for detecting $NO_2$ and $SO_2$, that are known as major air pollutants, have been prepared by coating two different polymers, polypyrrole and poly(3,4-ethylenedioxythiophene). The sensor elements prepared in this work have high sensitivity and selectivity for $NO_2$ and $SO_2$ at ppm level concentrations. It was proven that the sensing characteristics and response rate of the sensing elements are highly dependent on the coating method and the loading mass of sensing materials.