• Macromolecular Research
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• 제17권10호
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• pp.729-733
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• 2009

Solution casting films of sulfonated poly[styrene-b-(ethylene-r-butylene)-b-styrene] copolymer (sSEBS)-based composite membranes that contained different amounts of organic, nanorod-shaped polyrotaxane were annealed at various temperatures for 1 h. The films' properties were characterized with respect to their use as polymer electrolyte membranes in direct methanol fuel cells (DMFCs). Different aspect ratios of polyrotaxane were prepared using the inclusion-complex reaction between $\alpha$-cyclodextrin and poly(ethylene glycol). The presence of the organic polyrotaxane inside the membrane changed the morphology during the membrane preparation and reduced the transport of methanol. The conductivity and methanol permeability of the composite membranes decreased with increasing polyrotaxane content, while the annealing temperature increased. All of the sSEBS-based, polyrotaxane composite membranes annealed at $140^{\circ}C$ showed a higher selectivity parameter, suggesting their potential usage for DMFCs.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.82.2-82.2
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• 2010

The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

• 전기화학회지
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• 제14권2호
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• pp.71-76
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• 2011

Fe-tetramethoxyphenylporphyrin on carbon black (Fe-TMPP/C) is examined and compared with carbon (C) and Pt-coated carbon (Pt/C) for oxygen reduction reaction in a two chambered microbial fuel cell (MFC). The Fe-TMPP/C is prepared by heat treatment and characterized using SEM, TEM, and XPS. The electrochemical properties of catalysts are characterized by voltammerty and single cell measurements. It is found that the power generation in the MFC with Fe-TMPP/C as the cathode is higher than that with Pt/C. The maximum power of the Fe-TMPP/C is 0.12 mW compared with 0.10 mW (Pt/C) and 0.02 mW (C). This high output with the Fe-TMPP/C indicates that MFCs are promising in further practical applications with low cost macrocycles catalysts.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1740-1745
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• 2004

A simplified resistor network model for electrical and mass transport in anode-supported planar solid oxide fuel cell (SOFC) was constructed in order to investigate the effect of interconnect rib geometry on the cell performance. For accurate potential calculation, activation and concentration over-potentials at the electrode/electrolyte interfaces were fully considered in this calculation. When contact resistance was not considered, the optimum interconnect rib length were calculated to be $0.1{\sim}0.2$ mm for 2 mm half unit cell for given operation conditions and properties. However, with realistic contact resistance, the interconnect rib length should be increased to provide larger contact area and thus to obtain better performance.

• 한국자동차공학회논문집
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• 제3권1호
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• pp.118-130
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• 1995

Fuel spray in a gasoline engine is a significant factor for the decision of engine power, pollutant emission and the design of intake manifold system. Three kinds of fuel which has other physical properties are chosen in this study, and it is observed using an image processing method that the mechanism and structure of free fuel spray with a throttle type gasoline injector, and the detailed characteristics of droplet size and velocity distributions are obtained by macro and micro-scopic measuring method respectively. It is verified that the initial breakup behaviors are depended on We like the result of Reitz's study, and also observed that the spray of octane and solvent with Re of 210~330 and 270~330 respectively are better than ethanol which has relatively high density and viscosity.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1136-1139
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• 2005

As alternative materials for bipolar plate of PEM Fuel Cells, carbon composites were fabricated by compression molding. In this study, four types of nano particles, such as Carbon nanotubes, Carbon black, GX-15 and P-15 were mixed with epoxy resin to provide electric conductivity and structural properties. By increasing pressure during molding and volume ratio of nano particles, the physical contact among particles was improved resulting in increased electric conductivity. Surface resistance test showed, P-15 particles have the highest electric conductivity.

• 한국전산유체공학회지
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• 제6권1호
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• pp.47-55
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• 2001

The transient laminar reacting flows around fuel droplet have been numerically analyzed. The physical models used in this study can account for the variable thermophysical properties and the chemistry is represent by the one-step global reaction model. The present study is focused on the vaporization and ignition characteristics, flame structure including wake flame, transition flame and envelope flame, and interaction between droplets. Special emphasis is given to the triple flame structure and flame stabilization.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2005년도 제25회 추계학술대회논문집
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• pp.323-326
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• 2005

본 연구에서는 연료 따른 End-Burning 하이브리드 추진 시스템의 연소 특성을 파악하기 위한 실험적 연구를 수행하였다. 연료로는 PMMA, PE를 사용하였으며 산화제는 기체 산소를 사용하였다. 연료의 후퇴율은 산화제 유량뿐만 아니라 연료의 열역학적 성질의 함수이다. 본 실험을 통하여 연료의 후퇴율이 산화제 유량과 물질전달계수인 B number로 표현된 경험식을 얻었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2011년도 제37회 추계학술대회논문집
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• pp.429-431
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• 2011

열역학적 계산법을 적용하여 수반응 금속연료 추진제(HRF Propellants)의 비추력과 챔버 온도들과 같은 성능특성들을 분석하였다. 금속연료로 사용한 HRF 추진제의 열분석과 연소속도 시험을 통하여 연소특성에 대한 금속연료의 영향평가를 수행하였다.

• KIEE International Transactions on Power Engineering
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• 제5A권4호
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• pp.339-343
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• 2005

Hydrogen, as a future energy source, is thought as an alternative of fossil fuel in view of environment and energy security. Hydrogen has the properties of both fuel and electricity so that it can make the energy paradigm shift in the future. Therefore, researches on hydrogen in power system area are essential and urgent due to their huge effects on current paradigm. In this paper, the visions and technical challenges of hydrogen in power system are reviewed as energy storage, dispersed generation (DG), DC generator, and combined heat and power (CHP).