• Title/Summary/Keyword: fuel dilution

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Determination of Uranium Isotopes in Spent Nuclear Fuels by Isotope Dilution Mass Spectrometry (동위원소희석 질량분석법을 이용한 사용후핵연료 중 우라늄 동위원소 정량)

  • Kim, Jung Suk;Jeon, Young Shin;Son, Se Chul;Park, Soon Dal;Kim, Jong Goo;Kim, Won Ho
    • Analytical Science and Technology
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    • v.16 no.6
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    • pp.450-457
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    • 2003
  • The determination of uranium and its isotopes in spent nuclear fuels by isotope dilution mass spectrometry (IDMS) has been studied. The spent fuel samples were dissolved in 8 M $HNO_3$ or its mixture with 14 M $HNO_3-0.05M$ HF. The dissolved solutions were filterred on membrane filter with $1.2{\mu}m$ pore size. The uraniums in the spiked and unspiked sample solutions were quantitatively adsorbed by anion exchange resin, AG 1X8 and eluted with 0.1 M HCl. The contents of uranium and its isotopes ($^{234}U$, $^{235}U$, $^{236}U$$^{238}U$) in the spent fuel samples were determined by isotope dilution mass spectrometric method using $^{233}U$ as spike. The spike reference solution was standarized by reverse isotope dilution mass spectrometry (R-IDMS) using natural and depleted uranium. The results from IDMS were in average relative difference of 0.34% when compared with those by the potentiometric titration method.

The Effect of N2 Dilution on the Flame Stabilization in a Non-Premixed Turbulent H2 Jet with Coaxial Air (질소 희석이 수소 난류확산화염의 화염안정성에 미치는 영향)

  • Oh, Jeong-Seog;Yoon, Young-Bin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.7
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    • pp.477-485
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    • 2009
  • The study of nitrogen dilution effect on the flame stability was experimentally investigated in a non-premixed turbulent lifted hydrogen jet with coaxial air. Hydrogen gas was used as a fuel and coaxial air was used to make flame liftoff. Each of hydrogen and air were injected through axisymetric inner and outer nozzles ($d_F=3.65\;mm$ and $d_A=14.1\;mm$). And both fuel jet and coaxial air velocity were fixed as $u_F=200\;m/s$ and $u_A=16\;m/s$, while the mole fraction of nitrogen diluents gas was varied from 0.0 to 0.2 with 0.1 step. For the analysis of flame structure and the flame stabilization mechanism, the simultaneous measurement of PIV/OH PLIF laser diagnostics had been performed. The stabilization point was selected in the most upstream region of the flame base and defined as the point where the turbulent flame propagation velocity was equal to the axial component of local flow velocity. We found that the turbulent flame propagation velocity increased with the decrease of nitrogen mole fraction. We concluded that the turbulent flame propagation velocity was expressed as a function of turbulent intensity and axial strain rate, even though nitrogen diluents mole fraction was changed.

Effects of Fuel Nozzle Diameter in the Behavior of Laminar Lifted Flame (노즐 직경 변화가 층류부상화염 거동에 미치는 영향)

  • Kim, Tae-Kwon;Um, Hyen-Soo;Kim, Kyung-Ho;Ha, Ji-Soo;Park, Jeong
    • Journal of the Korean Institute of Gas
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    • v.12 no.2
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    • pp.77-84
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    • 2008
  • Experimental study was conducted to clarify the importance of buoyancy effects in laminar lifted flames which have been well understood by cold jet similarity theory. To evaluate buoyancy effects, lifted flame behaviors were systematically observed in methane and propane lifted flames diluted with He as changing the fuel nozzle diameter from 0.1 to 6 mm. Important physical parameters such as fuel strength, flame stretch and flame curvature, which were derived through simple physical scaling laws, were estimated. It is experimentally proven that buoyancy effects are important in relatively large fuel nozzle diameter and large fuel dilution with He. The results of Chen et al., which displayed the existence of stably lifted flames for 0.5

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Heterogeneous Ignition of $H_2/O_2/CO_2$ Mixture Over Platinum Catalyst (수소/산소/이산화탄소 혼합기의 백금촉매반응특성 : 비균일 반응의 점화 온도)

  • Nam, Chang-Ho;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.90-96
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    • 2001
  • Catalytic ignition of $H_2/O_2/CO_2$ mixtures over platinum catalyst is experimentally investigated by using microcalorimetry. For comparison, $N_2$ and Ar is also used as diluent gas. The gas mixture flows toward platinum foil heated by electric current at atmosphere pressure and ambient temperature. The ignition temperature range 350-445K according to the fuel ratio, dilution ratio and diluent gas. It increases as the fuel ratio and dilution ratio increase. $H_2/O_2$ mixture with $CO_2$ ignites at higher temperature than with other diluents by 30-50K. Several experimental evidences show the inhibition effects of $CO_2$ in $H_2-O_2$ heterogeneous reaction is considerable

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Experimental Study of Diluted Engine Oil Characteristics by Diesel Fuel (경유가 혼입된 엔진오일의 특성에 관한 실험적 연구)

  • Kim Han Goo;Park Tae Sik;Kim Chung Kyun
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.233-236
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    • 2004
  • An experimental study was conducted to evaluate characteristic variation of diluted engine oil by diesel fuel and its effects on engine components. Especially, engine oil was made to have $15\%$ fuel content. To predict existing diesel fuel content in engine oil after test was used the viscosity calibration curve. About $54\%$ percent of diesel fuel in diluted engine oil was distillated by various paths related to reciprocating motion of piston and the rest diesel fuel plays an important role for decreasing engine oil viscosity. Test results show that lowered engine ell viscosity by diesel fuel dilution become a reason of increasing engine elements wear, Therefore, this caused the quantity of blow-by gas to increase and main gallery pressure to decrease.

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Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel (저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구)

  • Kim, Yong-Chul;Lee, Chan
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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Effect of $CO_2$ dilution on Combustion Instabilities in dual premixed flame (이중 예혼합화염에서 $CO_2$ 희석이 연소불안정에 미치는 영향)

  • Lee, Kang-Yeop;Kim, Hyung-Mo;Park, Poo-Min;Hwang, O-Sik;Yang, Soo-Seok;Ko, Young-Sung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.763-768
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    • 2011
  • The effects of $CO_2$-dilution on combustion instability were studied in order to apply biogas in a dual lean premixed gas turbine combustor on a real-scale dual lean premixed burner head which is originally developed for Natural Gas fuel. Combustion instability is reduced by $CO_2$ dilution effect according to the result of dynamic pressure signal and phase-resolved $OH^*$ images. The reason for this is that dilution of $CO_2$ reduces heat release perturbation and increases flame volume due to reduction of the flame speed and expansion of flame surface.

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Flammability Limit and Flame Instability of Nitrogen-Diluted LPG Fuel (질소로 희석된 LPG 연료의 가연한계와 화염 안정성)

  • Ahn, Taekook;Nam, Younwoo;Lee, Kyung-Woo;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.319-321
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    • 2012
  • The flammability limit and the flame instability of nitrogen-diluted LPG fuel was experimentally studied on a co-flow flame configuration. The combustion reaction of nitrogen-diluted hydrocarbon with air could be interpreted as the equivalent reaction of pure fuel with nitrogen-diluted air. Nitrogen-diluted LPG with nitrogen up to 90 % of nitrogen mole fraction in fuel, which is close to the flammability limit, could form a co-flow flame. Various parameters such as laminar or turbulent flame, the existence of diffusion flame with pure fuel, air temperature could affect the limit of flame formation.

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Soot Generation System Utilizing High-Temperature Furnace (고온로를 이용한 매연발생장치)

  • Cho, Sanghwan;Park, Sunho;Nam, Younwoo;Choi, Yoo youl;Lee, Wonnam
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.55-58
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    • 2013
  • A new soot particle generation system has been developed and tested. The soot generation system consists of two sections, a fuel supply and a soot production. In the fuel supply module, either liquid fuel precisely controlled by a syringe pump is mixed with preheated carrier gas and rapidly evaporated or gaseous fuel controlled by a MFC is diluted with dilution gas. The soot production module contains a heater that can raise the gas/fuel temperature up to $1400^{\circ}C$. The physical and chemical properties of produced soot particles depend on the type and concentration of fuel, the residence time, and temperature in the soot production section. The soot generation system will be utilized to produce well-defined soot particles for soot studies such as the evaluation of experimental sampling and analysis processes for the quantitative assessment of PM and BC from ships and the adverse health effects on pulmonary and cardiovascular systems of human body.

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A Study on Enhancement of Combustion Performance by Dilution of Hydrogen in Heavy-Duty Hydrogen Engine (수소기관의 수소연료의 희석에 의한 역화억제효과에 관한 연구)

  • KIM, S.Y.;KIM, Y.Y.;Kim, Y.T.;LEE, JONG T.
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.4
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    • pp.348-354
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    • 2004
  • Hydrogen gas has several merits such as lower ignition energy, wide flammability and shorter quenching distance. It leads to high thermal efficiency but backfire occurrence. In this study, feasibility of expansion of BFL(Back-Fire Limit) equivalence ratio and combustion characteristics by a dilution of hydrogen fuel are experimently examined by using experimental heavy duty single cylinder hydrogen fueled engine. As results, it is found that BFL equivalence ratio is expanded to rich range and torque is increased.